Equilibrium, metastability, and hysteresis in a model spin-crossover material with nearest-neighbor antiferromagnetic-like and long-range ferromagnetic-like interactions

Rikvold, Per Arne; Brown, Gregory; Miyashita, Seiji; Omand, Conor; Nishino, Masamichi

doi:10.1103/PhysRevB.93.064109

Title: Equilibrium, metastability, and hysteresis in a model spin-crossover material with nearest-neighbor antiferromagnetic-like and long-range ferromagnetic-like interactions

Journal Article · Tue Feb 16 00:00:00 EST 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.93.064109· OSTI ID:1412068

Rikvold, Per Arne ^[1]; Brown, Gregory ^[2]; Miyashita, Seiji ^[3]; Omand, Conor ^[4]; Nishino, Masamichi ^[5]

Florida State Univ., Tallahassee, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
The Univ. of Tokyo, Tokyo (Japan); CREST, Saitama (Japan)
The Univ. of Tokyo, Tokyo (Japan); Univ. of British Columbia, Vancouver, BC (Canada)
National Institute for Materials Science, Ibaraki (Japan)

Phase diagrams and hysteresis loops were obtained by Monte Carlo simulations and a mean- field method for a simplified model of a spin-crossovermaterialwith a two-step transition between the high-spin and low-spin states. This model is a mapping onto a square-lattice S = 1/2 Ising model with antiferromagnetic nearest-neighbor and ferromagnetic Husimi-Temperley ( equivalent-neighbor) long-range interactions. Phase diagrams obtained by the two methods for weak and strong long-range interactions are found to be similar. However, for intermediate-strength long-range interactions, the Monte Carlo simulations show that tricritical points decompose into pairs of critical end points and mean-field critical points surrounded by horn-shaped regions of metastability. Hysteresis loops along paths traversing the horn regions are strongly reminiscent of thermal two-step transition loops with hysteresis, recently observed experimentally in several spin-crossover materials. As a result, we believe analogous phenomena should be observable in experiments and simulations for many systems that exhibit competition between local antiferromagnetic-like interactions and long-range ferromagnetic-like interactions caused by elastic distortions.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1412068

Alternate ID(s):: OSTI ID: 1238095

Journal Information:: Physical Review B, Vol. 93, Issue 6; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 16 works

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Cooperative Phenomena in Spin Crossover Systems Nesterov, Alexander I.; Orlov, Yuri S.; Ovchinnikov, Sergey G. arXiv https://doi.org/10.48550/arxiv.1611.10009	text	January 2016

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