Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres
Abstract
Thermally triggered autonomic shutdown of a Lithium-ion (Li-ion) battery is demonstrated using polydopamine (PDA)-coated polyethylene microspheres applied onto a battery anode. The microspheres are dispersed in a buffered 10 mM dopamine salt solution and the pH is raised to initiate the polymerization and coat the microspheres. Coated microspheres are then mixed with an aqueous binder, applied onto a battery anode surface, dried, and incorporated into Li-ion coin cells. FTIR and Raman spectroscopy are used to verify the presence of the polydopamine on the surface of the microspheres. Scanning electron microscopy is used to examine microsphere surface morphology and resulting anode coating quality. Charge and discharge capacity, as well as impedance, are measured for Li-ion coin cells as a function of microsphere content. Autonomous shutdown is achieved by applying 1.7 mg cm–2 of PDA-coated microspheres to the electrode. Furthermore, the PDA coating significantly reduces the mass of microspheres for effective shutdown compared to our prior work with uncoated microspheres.
- Authors:
-
- Univ. of Illinois Urbana-Champaign, Urbana, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1238061
- Alternate Identifier(s):
- OSTI ID: 1556593
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 269; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Li-ion batteries; thermal shutdown; polyethylene microspheres; polydopamine coating
Citation Formats
Baginska, Marta, Blaiszik, Benjamin J., Rajh, Tijana, Sottos, Nancy R., and White, Scott R. Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres. United States: N. p., 2014.
Web. doi:10.1016/j.jpowsour.2014.07.048.
Baginska, Marta, Blaiszik, Benjamin J., Rajh, Tijana, Sottos, Nancy R., & White, Scott R. Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres. United States. https://doi.org/10.1016/j.jpowsour.2014.07.048
Baginska, Marta, Blaiszik, Benjamin J., Rajh, Tijana, Sottos, Nancy R., and White, Scott R. 2014.
"Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres". United States. https://doi.org/10.1016/j.jpowsour.2014.07.048. https://www.osti.gov/servlets/purl/1238061.
@article{osti_1238061,
title = {Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres},
author = {Baginska, Marta and Blaiszik, Benjamin J. and Rajh, Tijana and Sottos, Nancy R. and White, Scott R.},
abstractNote = {Thermally triggered autonomic shutdown of a Lithium-ion (Li-ion) battery is demonstrated using polydopamine (PDA)-coated polyethylene microspheres applied onto a battery anode. The microspheres are dispersed in a buffered 10 mM dopamine salt solution and the pH is raised to initiate the polymerization and coat the microspheres. Coated microspheres are then mixed with an aqueous binder, applied onto a battery anode surface, dried, and incorporated into Li-ion coin cells. FTIR and Raman spectroscopy are used to verify the presence of the polydopamine on the surface of the microspheres. Scanning electron microscopy is used to examine microsphere surface morphology and resulting anode coating quality. Charge and discharge capacity, as well as impedance, are measured for Li-ion coin cells as a function of microsphere content. Autonomous shutdown is achieved by applying 1.7 mg cm–2 of PDA-coated microspheres to the electrode. Furthermore, the PDA coating significantly reduces the mass of microspheres for effective shutdown compared to our prior work with uncoated microspheres.},
doi = {10.1016/j.jpowsour.2014.07.048},
url = {https://www.osti.gov/biblio/1238061},
journal = {Journal of Power Sources},
issn = {0378-7753},
number = C,
volume = 269,
place = {United States},
year = {Thu Jul 17 00:00:00 EDT 2014},
month = {Thu Jul 17 00:00:00 EDT 2014}
}
Web of Science
Works referenced in this record:
Safety mechanisms in lithium-ion batteries
journal, April 2006
- Balakrishnan, P. G.; Ramesh, R.; Prem Kumar, T.
- Journal of Power Sources, Vol. 155, Issue 2
Characterization of thermal cut-off mechanisms in prismatic lithium-ion batteries
journal, October 2001
- Venugopal, Ganesh
- Journal of Power Sources, Vol. 101, Issue 2
Battery Separators
journal, October 2004
- Arora, Pankaj; Zhang, Zhengming (John)
- Chemical Reviews, Vol. 104, Issue 10
Separator technologies for lithium-ion batteries
journal, December 2010
- Huang, Xiaosong
- Journal of Solid State Electrochemistry, Vol. 15, Issue 4
Effects of separator breakdown on abuse response of 18650 Li-ion cells
journal, December 2007
- Roth, E. P.; Doughty, D. H.; Pile, D. L.
- Journal of Power Sources, Vol. 174, Issue 2
Enhancement of Meltdown Temperature of the Polyethylene Lithium-Ion Battery Separator via Surface Coating with Polymers Having High Thermal Resistance
journal, May 2009
- Chung, Y. S.; Yoo, S. H.; Kim, C. K.
- Industrial & Engineering Chemistry Research, Vol. 48, Issue 9
Lithium Ion Batteries: Autonomic Shutdown of Lithium-Ion Batteries Using Thermoresponsive Microspheres (Adv. Energy Mater. 5/2012)
journal, May 2012
- Baginska, Marta; Blaiszik, Benjamin J.; Merriman, Ryan J.
- Advanced Energy Materials, Vol. 2, Issue 5
Mussel-Inspired Polydopamine-Treated Polyethylene Separators for High-Power Li-Ion Batteries
journal, May 2011
- Ryou, Myung-Hyun; Lee, Yong Min; Park, Jung-Ki
- Advanced Materials, Vol. 23, Issue 27
Polyethylene characterization by FTIR
journal, January 2002
- Gulmine, J. V.; Janissek, P. R.; Heise, H. M.
- Polymer Testing, Vol. 21, Issue 5
Electrochemical growth of flowerlike gold nanoparticles on polydopamine modified ITO glass for SERS application
journal, February 2010
- Ye, Weichun; Wang, Daoai; Zhang, Hong
- Electrochimica Acta, Vol. 55, Issue 6
Works referencing / citing this record:
Lithium Ferrites@Polydopamine Core-Shell Nanoparticles as a New Robust Negative Electrode for Advanced Asymmetric Supercapacitors
journal, May 2018
- Mao, Zuxing; Han, Yi; Liu, Si
- Particle & Particle Systems Characterization, Vol. 35, Issue 7
Novel Core-Shell PS- co -PBA@SiO 2 Nanoparticles Coated on PP Separator as “Thermal Shutdown Switch” for High Safety Lithium-Ion Batteries
journal, August 2017
- Liao, Haiyang; Zhang, Haiyan; Qin, Gai
- Macromolecular Materials and Engineering, Vol. 302, Issue 11
Elucidating structure–function relationships governing the interfacial response of human mesenchymal stem cells to polydopamine coatings
journal, January 2020
- Steeves, Alexander J.; Variola, Fabio
- Journal of Materials Chemistry B, Vol. 8, Issue 2
Smart Materials and Design toward Safe and Durable Lithium Ion Batteries
journal, May 2019
- Wen, Lei; Liang, Ji; Chen, Jing
- Small Methods, Vol. 3, Issue 11