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Title: Nitrogen Atom Transfer From High Valent Iron Nitrides

This report describes the synthesis and reactions of high valent iron nitrides. Organonitrogen compounds such as aziridines are useful species for organic synthesis, but there are few efficient methods for their synthesis. Using iron nitrides to catalytically access these species may allow for their synthesis in an energy-and atom-efficient manner. We have developed a new ligand framework to achieve these goals as well as providing a method for inducing previously unknown reactivity.
Authors:
 [1] ;  [2]
  1. New Mexico State Univ., Las Cruces, NM (United States)
  2. Indiana Univ., Bloomington, IN (United States)
Publication Date:
OSTI Identifier:
1236964
Report Number(s):
DOE-NMSU--15996
DOE Contract Number:
FG02-08ER15996
Resource Type:
Technical Report
Research Org:
New Mexico State University, Las Cruces, NM (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY iron nitrides; catalysis; aziridines