skip to main content

SciTech ConnectSciTech Connect

Title: A versatile synthetic route for the preparation of titanium metal-organic frameworks

Exploitation of new titanium metal–organic frameworks (Ti-MOFs) with high crystallinity has been attracting great attention due to their vast application potential in photocatalysis. Herein a versatile synthetic strategy, namely, High Valence Metathesis and Oxidation (HVMO), is developed to synthesize a series of Ti-MOFs with predesigned topologies and structures. The crystallinity of these Ti-MOFs was well maintained throughout, as confirmed by powder X-ray diffraction and gas adsorption measurements. Significantly, there were only a few examples of Ti-MOFs, not to mention a general synthetic strategy for various kinds of Ti-MOFs in the literature. This contribution also illustrates the intriguing potential of Ti-MOF platforms in photocatalysis.
Authors:
; ; ; ; ; ; ; ;  [1]
  1. TAM
Publication Date:
OSTI Identifier:
1236869
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chemical Science (Online); Journal Volume: 7; Journal Issue: (2) ; 2016
Publisher:
Royal Society of Chemistry
Research Org:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Org:
DOE - BASIC ENERGY SCIENCES
Country of Publication:
United States
Language:
ENGLISH