The role of atropisomers on the photo-reactivity and fatigue of diarylethene-based metal–organic frameworks

Walton, Ian M.; Cox, Jordan M.; Benson, Cassidy A.; Patel, Dinesh (Dan) G.; Chen, Yu-Sheng; Benedict, Jason B.

doi:10.1039/C5NJ01718A

Title: The role of atropisomers on the photo-reactivity and fatigue of diarylethene-based metal–organic frameworks

Journal Article · Mon Sep 21 00:00:00 EDT 2015 · New Journal of Chemistry

DOI:https://doi.org/10.1039/C5NJ01718A· OSTI ID:1236855

Walton, Ian M. ^[1]; Cox, Jordan M. ^[1]; Benson, Cassidy A. ^[1]; Patel, Dinesh (Dan) G. ^[2]; Chen, Yu-Sheng ^[3]; Benedict, Jason B. ^[1]

State Univ. of New York (SUNY), Buffalo, NY (United States)
Pennsylvania State Univ., Hazleton, PA (United States)
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources (CARS)

Photo-responsive metal–organic frameworks (MOFs) are one example of light controlled smart materials for use in advanced sensors, data storage, actuators and molecular switches. In this paper we show the design, synthesis and characterization of a photo-responsive linker that is subsequently reacted to yield MOF single crystals. The photo-responsive properties of the resulting UBMOF-2 arise from the photo-induced cyclization of the diarylethene moiety designed into the linker. Computational modeling to assess the relative energies of linker atropisomers reveals a large energetic barrier preventing facile interconversion between key species. The role of this barrier on the observed photo-induced fatigue provides useful insight into the development of advanced photo-responsive nanoporous materials.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: NSF/CHE-1346572; AC02-06CH11357

OSTI ID:: 1236855

Journal Information:: New Journal of Chemistry, Vol. 40, Issue 1; ISSN 1144-0546

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 51 works

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Title: The role of atropisomers on the photo-reactivity and fatigue of diarylethene-based metal–organic frameworks

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