Catalysis applications of size-selected cluster deposition
Abstract
In this Perspective, we review recent studies of size-selected cluster deposition for catalysis applications performed at the U.S. DOE National Laboratories, with emphasis on work at Argonne National Laboratory (ANL) and Brookhaven National Laboratory (BNL). The focus is on the preparation of model supported catalysts in which the number of atoms in the deposited clusters is precisely controlled using a combination of gas-phase cluster ion sources, mass spectrometry, and soft-landing techniques. This approach is particularly effective for investigations of small nanoclusters, 0.5-2 nm (<200 atoms), where the rapid evolution of the atomic and electronic structure makes it essential to have precise control over cluster size. Cluster deposition allows for independent control of cluster size, coverage, and stoichiometry (e.g., the metal-to-oxygen ratio in an oxide cluster) and can be used to deposit on any substrate without constraints of nucleation and growth. Examples are presented for metal, metal oxide, and metal sulfide cluster deposition on a variety of supports (metals, oxides, carbon/diamond) where the reactivity, cluster-support electronic interactions, and cluster stability and morphology are investigated. Both UHV and in situ/operando studies are presented that also make use of surface-sensitive X-ray characterization tools from synchrotron radiation facilities. Novel applications of cluster deposition tomore »
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Argonne National Lab. (ANL), Argonne, IL (United States). Nanoscience and Technology Division; Univ. of Chicago, IL (United States). Inst. for Molecular Engineering; Yale Univ., New Haven, CT (United States). Dept. of Chemical and Environmental Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1236817
- Grant/Contract Number:
- AC02-06CH11357; SC0012704
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 12; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; cluster deposition; heterogeneous catalysis; metal oxide; molybdenum sulfide; size-selected; transition metal; work function
Citation Formats
Vajda, Stefan, and White, Michael G. Catalysis applications of size-selected cluster deposition. United States: N. p., 2015.
Web. doi:10.1021/acscatal.5b01816.
Vajda, Stefan, & White, Michael G. Catalysis applications of size-selected cluster deposition. United States. https://doi.org/10.1021/acscatal.5b01816
Vajda, Stefan, and White, Michael G. 2015.
"Catalysis applications of size-selected cluster deposition". United States. https://doi.org/10.1021/acscatal.5b01816. https://www.osti.gov/servlets/purl/1236817.
@article{osti_1236817,
title = {Catalysis applications of size-selected cluster deposition},
author = {Vajda, Stefan and White, Michael G.},
abstractNote = {In this Perspective, we review recent studies of size-selected cluster deposition for catalysis applications performed at the U.S. DOE National Laboratories, with emphasis on work at Argonne National Laboratory (ANL) and Brookhaven National Laboratory (BNL). The focus is on the preparation of model supported catalysts in which the number of atoms in the deposited clusters is precisely controlled using a combination of gas-phase cluster ion sources, mass spectrometry, and soft-landing techniques. This approach is particularly effective for investigations of small nanoclusters, 0.5-2 nm (<200 atoms), where the rapid evolution of the atomic and electronic structure makes it essential to have precise control over cluster size. Cluster deposition allows for independent control of cluster size, coverage, and stoichiometry (e.g., the metal-to-oxygen ratio in an oxide cluster) and can be used to deposit on any substrate without constraints of nucleation and growth. Examples are presented for metal, metal oxide, and metal sulfide cluster deposition on a variety of supports (metals, oxides, carbon/diamond) where the reactivity, cluster-support electronic interactions, and cluster stability and morphology are investigated. Both UHV and in situ/operando studies are presented that also make use of surface-sensitive X-ray characterization tools from synchrotron radiation facilities. Novel applications of cluster deposition to electrochemistry and batteries are also presented. This review also highlights the application of modern ab initio electronic structure calculations (density functional theory), which can essentially model the exact experimental system used in the laboratory (i.e., cluster and support) to provide insight on atomic and electronic structure, reaction energetics, and mechanisms. As amply demonstrated in this review, the powerful combination of atomically precise cluster deposition and theory is able to address fundamental aspects of size-effects, cluster-support interactions, and reaction mechanisms of cluster materials that are central to how catalysts function. Lastly, the insight gained from such studies can be used to further the development of novel nanostructured catalysts with high activity and selectivity.},
doi = {10.1021/acscatal.5b01816},
url = {https://www.osti.gov/biblio/1236817},
journal = {ACS Catalysis},
issn = {2155-5435},
number = 12,
volume = 5,
place = {United States},
year = {Fri Oct 23 00:00:00 EDT 2015},
month = {Fri Oct 23 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
The Impact of Nanoscience on Heterogeneous Catalysis
journal, March 2003
- Bell, A. T.
- Science, Vol. 299, Issue 5613
Colloid Science of Metal Nanoparticle Catalysts in 2D and 3D Structures. Challenges of Nucleation, Growth, Composition, Particle Shape, Size Control and Their Influence on Activity and Selectivity
journal, June 2008
- Somorjai, Gabor A.; Park, Jeong Y.
- Topics in Catalysis, Vol. 49, Issue 3-4
Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects
journal, April 2010
- Cuenya, Beatriz Roldan
- Thin Solid Films, Vol. 518, Issue 12
Nanostructured materials for applications in heterogeneous catalysis
journal, January 2013
- Zaera, Francisco
- Chem. Soc. Rev., Vol. 42, Issue 7
When Gold Is Not Noble: Nanoscale Gold Catalysts
journal, December 1999
- Sanchez, A.; Abbet, S.; Heiz, U.
- The Journal of Physical Chemistry A, Vol. 103, Issue 48
Advances in the catalysis of Au nanoparticles
journal, December 2001
- Haruta, Masatake; Daté, Masakazu
- Applied Catalysis A: General, Vol. 222, Issue 1-2
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003
- Fu, Q.
- Science, Vol. 301, Issue 5635
Surface chemistry of catalysis by gold
journal, March 2004
- Meyer, R.; Lemire, C.; Shaikhutdinov, Sh. K.
- Gold Bulletin, Vol. 37, Issue 1-2
Supported gold nanoparticles as catalysts for organic reactions
journal, January 2008
- Corma, Avelino; Garcia, Hermenegildo
- Chemical Society Reviews, Vol. 37, Issue 9
Nanoclusters deposited on surfaces
journal, October 2001
- Binns, C.
- Surface Science Reports, Vol. 44, Issue 1-2
Nanoassembled model catalysts
journal, May 2000
- Heiz, Ueli; Schneider, Wolf-Dieter
- Journal of Physics D: Applied Physics, Vol. 33, Issue 11
Fundamental aspects of catalysis on supported metal clusters
journal, January 2004
- Heiz, U.; Bullock, E. L.
- Journal of Materials Chemistry, Vol. 14, Issue 4
Atomically precise cluster catalysis towards quantum controlled catalysts
journal, December 2014
- Watanabe, Yoshihide
- Science and Technology of Advanced Materials, Vol. 15, Issue 6
Catalysis by Supported Size-Selected Clusters
book, September 2009
- Meyer, Randall; Lei, Yu; Lee, Sungsik
- Model Systems in Catalysis
Influence and Removal of Capping Ligands on Catalytic Colloidal Nanoparticles
journal, July 2014
- Huang, Weixin; Hua, Qing; Cao, Tian
- Catalysis Letters, Vol. 144, Issue 8
Efficient Removal of Organic Ligands from Supported Nanocrystals by Fast Thermal Annealing Enables Catalytic Studies on Well-Defined Active Phases
journal, May 2015
- Cargnello, Matteo; Chen, Chen; Diroll, Benjamin T.
- Journal of the American Chemical Society, Vol. 137, Issue 21
Removal and Utilization of Capping Agents in Nanocatalysis
journal, September 2013
- Niu, Zhiqiang; Li, Yadong
- Chemistry of Materials, Vol. 26, Issue 1
Surface studies of supported model catalysts
journal, January 1998
- Henry, Claude R.
- Surface Science Reports, Vol. 31, Issue 7-8
Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties
journal, January 1997
- Campbell, Charles T.
- Surface Science Reports, Vol. 27, Issue 1-3
Oxide ultra-thin films on metals: new materials for the design of supported metal catalysts
journal, January 2008
- Freund, Hans-Joachim; Pacchioni, Gianfranco
- Chemical Society Reviews, Vol. 37, Issue 10
Metal deposits on well-ordered oxide films
journal, August 1999
- Bäumer, Marcus; Freund, Hans-Joachim
- Progress in Surface Science, Vol. 61, Issue 7-8
Surface Dipoles and Electron Transfer at the Metal Oxide–Metal Interface: A 2PPE Study of Size-Selected Metal Oxide Clusters Supported on Cu(111)
journal, June 2014
- Yang, Yixiong; Zhou, Jia; Nakayama, Miki
- The Journal of Physical Chemistry C, Vol. 118, Issue 25
Influence of Cluster–Support Interactions on Reactivity of Size-Selected Nb x O y Clusters
journal, April 2015
- Nakayama, Miki; Xue, Meng; An, Wei
- The Journal of Physical Chemistry C, Vol. 119, Issue 26
A phase-space-compressing, mass-selecting beamline for hyperthermal, focused ion beam deposition
journal, December 1998
- Boyd, Kevin J.; Łapicki, Adam; Aizawa, Masato
- Review of Scientific Instruments, Vol. 69, Issue 12
A new type of cluster and cluster ion source
journal, March 1991
- Haberland, H.; Karrais, M.; Mall, M.
- Zeitschrift f�r Physik D Atoms, Molecules and Clusters, Vol. 20, Issue 1-4
Thin films from energetic cluster impact: A feasibility study
journal, September 1992
- Haberland, Hellmut; Karrais, Martin; Mall, Martin
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 10, Issue 5
Reactivity of the <mml:math altimg="si14.gif" display="inline" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">M</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">S</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> (M=Mo, W) cluster with CO and NH3 in the gas-phase: An experimental and DFT study
journal, September 2005
- Lightstone, James M.; Patterson, Melissa J.; White, Michael G.
- Chemical Physics Letters, Vol. 413, Issue 4-6
Structure of Molybdenum and Tungsten Sulfide M x S y + Clusters: Experiment and DFT Calculations
journal, November 2008
- Patterson, Melissa J.; Lightstone, James M.; White, Michael G.
- The Journal of Physical Chemistry A, Vol. 112, Issue 47
Gas-Phase Reactivity of the Ti 8 C 12 + Met-car with Triatomic Sulfur-Containing Molecules: CS 2 , SCO, and SO 2
journal, March 2006
- Lightstone, James M.; Patterson, Melissa J.; Liu, Ping
- The Journal of Physical Chemistry A, Vol. 110, Issue 10
Reactivity of supported platinum nanoclusters studied by in situ GISAXS: clusters stability under hydrogen
journal, October 2006
- Winans, Randall E.; Vajda, Stefan; Ballentine, Gregory E.
- Topics in Catalysis, Vol. 39, Issue 3-4
Gas Phase Chemical Reactions of Transition Metal Clusters
journal, March 1984
- Riley, S. J.; Parks, E. K.; Pobo, L. G.
- Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 88, Issue 3
Supported gold clusters and cluster-based nanomaterials: characterization, stability and growth studies by in situ GISAXS under vacuum conditions and in the presence of hydrogen
journal, October 2006
- Vajda, Stefan; Winans, Randall E.; Elam, Jeffrey W.
- Topics in Catalysis, Vol. 39, Issue 3-4
Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument
journal, May 2014
- Yin, C.; Tyo, E.; Kuchta, K.
- The Journal of Chemical Physics, Vol. 140, Issue 17, Article No. 174201
Catalysis by clusters with precise numbers of atoms
journal, July 2015
- Tyo, Eric C.; Vajda, Stefan
- Nature Nanotechnology, Vol. 10, Issue 7
Simultaneous measurement of X-ray small angle scattering, absorption and reactivity: A continuous flow catalysis reactor
journal, September 2011
- Lee, Sungsik; Lee, Byeongdu; Seifert, Soenke
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1
Effect of the size-selective silver clusters on lithium peroxide morphology in lithium–oxygen batteries
journal, September 2014
- Lu, Jun; Cheng, Lei; Lau, Kah Chun
- Nature Communications, Vol. 5, Article No. 4895
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane
journal, February 2009
- Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P.
- Nature Materials, Vol. 8, Issue 3
Cleavage of the C–O–C bond on size-selected subnanometer cobalt catalysts and on ALD-cobalt coated nanoporous membranes
journal, February 2011
- Deng, Weiling; Lee, Sungsik; Libera, Joseph A.
- Applied Catalysis A: General, Vol. 393, Issue 1-2
Size- and Support-Dependent Evolution of the Oxidation State and Structure by Oxidation of Subnanometer Cobalt Clusters
journal, May 2014
- Yin, Chunrong; Zheng, Fan; Lee, Sungsik
- The Journal of Physical Chemistry A, Vol. 118, Issue 37
Oxidation and reduction of size-selected subnanometer Pd clusters on Al 2 O 3 surface
journal, June 2013
- Mao, Bao-Hua; Chang, Rui; Lee, Sungsik
- The Journal of Chemical Physics, Vol. 138, Issue 21
A near ambient pressure XPS study of subnanometer silver clusters on Al 2 O 3 and TiO 2 ultrathin film supports
journal, January 2014
- Mao, Bao-Hua; Chang, Rui; Shi, Lei
- Phys. Chem. Chem. Phys., Vol. 16, Issue 48
Reaction Mechanism for Direct Propylene Epoxidation by Alumina-Supported Silver Aggregates: The Role of the Particle/Support Interface
journal, December 2013
- Cheng, Lei; Yin, Chunrong; Mehmood, Faisal
- ACS Catalysis, Vol. 4, Issue 1
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
Electronic structure of deposited monosized metal-clusters
journal, March 1991
- Cox, D. M.; Eberhardt, W.; Fayet, P.
- Zeitschrift f�r Physik D Atoms, Molecules and Clusters, Vol. 20, Issue 1-4
Tuning the oxidation of carbon monoxide using nanoassembled model catalysts
journal, December 2000
- Heiz, U.; Sanchez, A.; Abbet, S.
- Chemical Physics, Vol. 262, Issue 1
Low-Temperature Cluster Catalysis
journal, March 2004
- Judai, Ken; Abbet, Stéphane; Wörz, Anke S.
- Journal of the American Chemical Society, Vol. 126, Issue 9
Support-dependent Performance of Size-selected Subnanometer Cobalt Cluster-based Catalysts in the Dehydrogenation of Cyclohexene
journal, August 2012
- Lee, Sungsik; Di Vece, Marcel; Lee, Byeongdu
- ChemCatChem, Vol. 4, Issue 10
Oxidative dehydrogenation of cyclohexene on size selected subnanometer cobalt clusters: improved catalytic performance via evolution of cluster-assembled nanostructures
journal, January 2012
- Lee, Sungsik; Vece, Marcel Di; Lee, Byeongdu
- Physical Chemistry Chemical Physics, Vol. 14, Issue 26
Fischer–Tropsch Synthesis at a Low Pressure on Subnanometer Cobalt Oxide Clusters: The Effect of Cluster Size and Support on Activity and Selectivity
journal, January 2015
- Lee, Sungsik; Lee, Byeongdu; Seifert, Sönke
- The Journal of Physical Chemistry C, Vol. 119, Issue 20
Size-selected, supported clusters: the interaction of carbon monoxide with nickel clusters
journal, December 1998
- Heiz, U.
- Applied Physics A: Materials Science & Processing, Vol. 67, Issue 6
Sintering, oxidation, and chemical properties of size-selected nickel clusters on TiO2(110)
journal, September 2002
- Aizawa, Masato; Lee, Sungsik; Anderson, Scott L.
- The Journal of Chemical Physics, Vol. 117, Issue 10
Carbon Dioxide Conversion to Methanol over Size-Selected Cu 4 Clusters at Low Pressures
journal, July 2015
- Liu, Cong; Yang, Bing; Tyo, Eric
- Journal of the American Chemical Society, Vol. 137, Issue 27
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO2 Surfaces
journal, November 2009
- Kaden, W. E.; Wu, T.; Kunkel, W. A.
- Science, Vol. 326, Issue 5954
Oxidative Decomposition of Methanol on Subnanometer Palladium Clusters: The Effect of Catalyst Size and Support Composition
journal, May 2010
- Lee, Sungsik; Lee, Byeongdu; Mehmood, Faisal
- The Journal of Physical Chemistry C, Vol. 114, Issue 23
Acetylene Cyclotrimerization on Supported Size-Selected Pd n Clusters (1 ≤ n ≤ 30): One Atom Is Enough!
journal, April 2000
- Abbet, S.; Sanchez, A.; Heiz, U.
- Journal of the American Chemical Society, Vol. 122, Issue 14
Tuning the Selectivity of Acetylene Polymerization Atom by Atom
journal, February 2001
- Abbet, Stéphane; Sanchez, Antonio; Heiz, Ueli
- Journal of Catalysis, Vol. 198, Issue 1
Cluster Size-Dependent Mechanisms of the CO + NO Reaction on Small Pd n ( n ≤ 30) Clusters on Oxide Surfaces
journal, July 2003
- Wörz, Anke S.; Judai, Ken; Abbet, Stéphane
- Journal of the American Chemical Society, Vol. 125, Issue 26
Communication: Suppression of sintering of size-selected Pd clusters under realistic reaction conditions for catalysis
journal, April 2011
- Yin, Feng; Lee, Sungsik; Abdela, Ahmed
- The Journal of Chemical Physics, Vol. 134, Issue 14
Size-Selected Monodisperse Nanoclusters on Supported Graphene: Bonding, Isomerism, and Mobility
journal, October 2012
- Wang, Bo; Yoon, Bokwon; König, Michael
- Nano Letters, Vol. 12, Issue 11
Fundamental Insight into the Substrate-Dependent Ripening of Monodisperse Clusters
journal, August 2013
- Fukamori, Yves; König, Michael; Yoon, Bokwon
- ChemCatChem, Vol. 5, Issue 11
Catalytic oxidation of cyclohexane by size-selected palladium clusters pinned on graphite
journal, May 2012
- Habibpour, Vahideh; Yin, Chunrong; Kwon, Gihan
- Journal of Experimental Nanoscience, Vol. 8, Issue 7-8
Size-Dependent Subnanometer Pd Cluster (Pd 4 , Pd 6 , and Pd 17 ) Water Oxidation Electrocatalysis
journal, June 2013
- Kwon, Gihan; Ferguson, Glen A.; Heard, Christopher J.
- ACS Nano, Vol. 7, Issue 7
Initial and Final State Effects in the Ultraviolet and X-ray Photoelectron Spectroscopy (UPS and XPS) of Size-Selected Pd n Clusters Supported on TiO 2 (110)
journal, March 2015
- Roberts, F. Sloan; Anderson, Scott L.; Reber, Arthur C.
- The Journal of Physical Chemistry C, Vol. 119, Issue 11
Combined temperature-programmed reaction and in situ x-ray scattering studies of size-selected silver clusters under realistic reaction conditions in the epoxidation of propene
journal, September 2009
- Vajda, Stefan; Lee, Sungsik; Sell, Kristian
- The Journal of Chemical Physics, Vol. 131, Issue 12
Size-dependent selectivity and activity of silver nanoclusters in the partial oxidation of propylene to propylene oxide and acrolein: A joint experimental and theoretical study
journal, February 2011
- Molina, Luis M.; Lee, Sungsik; Sell, Kristian
- Catalysis Today, Vol. 160, Issue 1
The impact of size-selected Ag clusters on graphite: an STM study
journal, October 1996
- Carroll, S. J.; Weibel, P.; Issendorff, B. von
- Journal of Physics: Condensed Matter, Vol. 8, Issue 41
Immobilization of large size-selected silver clusters on graphite
journal, January 2006
- Claeyssens, F.; Pratontep, S.; Xirouchaki, C.
- Nanotechnology, Vol. 17, Issue 3
Combined TPRx, in situ GISAXS and GIXAS studies of model semiconductor-supported platinum catalysts in the hydrogenation of ethene
journal, January 2010
- Wyrzgol, Sonja A.; Schäfer, Susanne; Lee, Sungsik
- Physical Chemistry Chemical Physics, Vol. 12, Issue 21
Electronic structures of size-selected single-layered platinum clusters on silicon(111)-7×7 surface at a single cluster level by tunneling spectroscopy
journal, January 2006
- Yasumatsu, Hisato; Hayakawa, Tetsuichiro; Kondow, Tamotsu
- The Journal of Chemical Physics, Vol. 124, Issue 1
Size-selected clusters as heterogeneous model catalysts under applied reaction conditions
journal, January 2010
- Kunz, Sebastian; Hartl, Katrin; Nesselberger, Markus
- Physical Chemistry Chemical Physics, Vol. 12, Issue 35
Size-dependent catalytic activity and geometries of size-selected Pt clusters on TiO2(110) surfaces
journal, January 2011
- Watanabe, Yoshihide; Wu, Xingyang; Hirata, Hirohito
- Catalysis Science & Technology, Vol. 1, Issue 8, p. 1490-1495
Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters
journal, February 2012
- Bonanni, Simon; Aït-Mansour, Kamel; Harbich, Wolfgang
- Journal of the American Chemical Society, Vol. 134, Issue 7, p. 3445-3450
The effect of particle proximity on the oxygen reduction rate of size-selected platinum clusters
journal, July 2013
- Nesselberger, Markus; Roefzaad, Melanie; Fayçal Hamou, R.
- Nature Materials, Vol. 12, Issue 10
Strong Effects of Cluster Size and Air Exposure on Oxygen Reduction and Carbon Oxidation Electrocatalysis by Size-Selected Pt n ( n ≤ 11) on Glassy Carbon Electrodes
journal, February 2013
- Proch, Sebastian; Wirth, Mark; White, Henry S.
- Journal of the American Chemical Society, Vol. 135, Issue 8
Cluster Size Effects in the Photocatalytic Hydrogen Evolution Reaction
journal, August 2013
- Schweinberger, Florian F.; Berr, Maximilian J.; Döblinger, Markus
- Journal of the American Chemical Society, Vol. 135, Issue 36
Cluster Size Controls Branching between Water and Hydrogen Peroxide Production in Electrochemical Oxygen Reduction at Pt n /ITO
journal, January 2015
- von Weber, Alexander; Baxter, Eric T.; White, Henry S.
- The Journal of Physical Chemistry C, Vol. 119, Issue 20
Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite: Size Effect in the Sub-2 nm Regime
journal, December 2010
- Liu, Yongmei; Tsunoyama, Hironori; Akita, Tomoki
- ACS Catalysis, Vol. 1, Issue 1
Scaling Relations for Implantation of Size-Selected Au, Ag, and Si Clusters into Graphite
journal, February 2003
- Pratontep, S.; Preece, P.; Xirouchaki, C.
- Physical Review Letters, Vol. 90, Issue 5
CO Oxidation on Au n /TiO 2 Catalysts Produced by Size-Selected Cluster Deposition
journal, May 2004
- Lee, Sungsik; Fan, Chaoyang; Wu, Tianpin
- Journal of the American Chemical Society, Vol. 126, Issue 18
Cluster size effects on CO oxidation activity, adsorbate affinity, and temporal behavior of model Aun∕TiO2 catalysts
journal, September 2005
- Lee, Sungsik; Fan, Chaoyang; Wu, Tianpin
- The Journal of Chemical Physics, Vol. 123, Issue 12
Agglomeration, Sputtering, and Carbon Monoxide Adsorption Behavior for Au/Al 2 O 3 Prepared by Au n + Deposition on Al 2 O 3 /NiAl(110)
journal, June 2005
- Lee, Sungsik; Fan, Chaoyang; Wu, Tianpin
- The Journal of Physical Chemistry B, Vol. 109, Issue 22
Agglomeration, support effects, and CO adsorption on Au/TiO2(110) prepared by ion beam deposition
journal, March 2005
- Lee, Sungsik; Fan, Chaoyang; Wu, Tianpin
- Surface Science, Vol. 578, Issue 1-3
Intact Size-Selected Au n Clusters on a TiO 2 (110)-(1 × 1) Surface at Room Temperature
journal, October 2005
- Tong, Xiao; Benz, Lauren; Kemper, Paul
- Journal of the American Chemical Society, Vol. 127, Issue 39
Pinning of size-selected gold and nickel nanoclusters on graphite
journal, August 2005
- Di Vece, M.; Palomba, S.; Palmer, R. E.
- Physical Review B, Vol. 72, Issue 7
Factors in gold nanocatalysis: oxidation of CO in the non-scalable size regime
journal, June 2007
- Landman, Uzi; Yoon, Bokwon; Zhang, Chun
- Topics in Catalysis, Vol. 44, Issue 1-2
Water on Rutile TiO 2 (110) and Au/TiO 2 (110): Effects on Au Mobility and the Isotope Exchange Reaction
journal, May 2008
- Wu, Tianpin; Kaden, William E.; Anderson, Scott L.
- The Journal of Physical Chemistry C, Vol. 112, Issue 24
Selective Propene Epoxidation on Immobilized Au 6-10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity
journal, February 2009
- Lee, Sungsik; Molina, Luis M.; López, María J.
- Angewandte Chemie International Edition, Vol. 48, Issue 8
Very small “window of opportunity” for generating CO oxidation-active Au n on TiO 2
journal, January 2014
- Tang, X.; Schneider, J.; Dollinger, A.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 14
Deposition of size-selected metal clusters generated by magnetron sputtering and gas condensation: a progress review
journal, November 2003
- Xirouchaki, C.; Palmer, R. E.
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1814
Atomic Structure Control of Size-Selected Gold Nanoclusters during Formation
journal, May 2014
- Plant, Simon R.; Cao, Lu; Palmer, Richard E.
- Journal of the American Chemical Society, Vol. 136, Issue 21
Metastability of the atomic structures of size-selected gold nanoparticles
journal, January 2015
- Wells, Dawn M.; Rossi, Giulia; Ferrando, Riccardo
- Nanoscale, Vol. 7, Issue 15
Oxidative dehydrogenation of ethane and propane at short contact time
journal, November 2004
- Silberova, Bozena; Fathi, Marcus; Holmen, Anders
- Applied Catalysis A: General, Vol. 276, Issue 1-2
Advanced metal oxide (supported) catalysts: Synthesis and applications
journal, November 2014
- Lee, Dong Won; Yoo, Bok Ryul
- Journal of Industrial and Engineering Chemistry, Vol. 20, Issue 6
Catalysis Science of Bulk Mixed Oxides
journal, April 2012
- Wachs, Israel E.; Routray, Kamalakanta
- ACS Catalysis, Vol. 2, Issue 6
Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbons
journal, May 2003
- Gorte, R. J.; Vohs, J. M.
- Journal of Catalysis, Vol. 216, Issue 1-2
Olefin Metathesis by Supported Metal Oxide Catalysts
journal, June 2014
- Lwin, Soe; Wachs, Israel E.
- ACS Catalysis, Vol. 4, Issue 8
Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis
journal, August 2014
- Zhu, Junjiang; Li, Hailong; Zhong, Linyun
- ACS Catalysis, Vol. 4, Issue 9
The Physical and Chemical Properties of Ultrathin Oxide Films
journal, October 1997
- Street, S. C.; Xu, C.; Goodman, D. W.
- Annual Review of Physical Chemistry, Vol. 48, Issue 1
Interface-Confined Oxide Nanostructures for Catalytic Oxidation Reactions
journal, March 2013
- Fu, Qiang; Yang, Fan; Bao, Xinhe
- Accounts of Chemical Research, Vol. 46, Issue 8
Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies
journal, February 2010
- Rodríguez, José A.; Hrbek, Jan
- Surface Science, Vol. 604, Issue 3-4
Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction
journal, December 2007
- Rodriguez, J. A.; Ma, S.; Liu, P.
- Science, Vol. 318, Issue 5857
Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009
- Rodriguez, José A.; Graciani, Jesús; Evans, Jaime
- Angewandte Chemie International Edition, Vol. 48, Issue 43
Formation of Monodisperse (WO3)3 Clusters on TiO2(110)
journal, July 2006
- Bondarchuk, Oleksandr; Huang, Xin; Kim, Jooho
- Angewandte Chemie International Edition, Vol. 45, Issue 29
Preparation and characterization of monodispersed WO3 nanoclusters on TiO2(110)
journal, February 2007
- Kim, Jooho; Bondarchuk, Oleksandr; Kay, Bruce D.
- Catalysis Today, Vol. 120, Issue 2
Catalytic Dehydration of 2-Propanol on (WO 3 ) 3 Clusters on TiO 2 (110)
journal, April 2008
- Kim, Yu Kwon; Rousseau, Roger; Kay, Bruce D.
- Journal of the American Chemical Society, Vol. 130, Issue 15
Competitive Oxidation and Reduction of Aliphatic Alcohols over (WO 3 ) 3 Clusters
journal, May 2009
- Kim, Yu Kwon; Dohnálek, Z.; Kay, Bruce D.
- The Journal of Physical Chemistry C, Vol. 113, Issue 22
Formaldehyde Polymerization on (WO 3 ) 3 /TiO 2 (110) Model Catalyst
journal, May 2010
- Kim, Jooho; Kay, Bruce D.; Dohnálek, Zdenek
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
Polymerization of Formaldehyde and Acetaldehyde on Ordered (WO 3 ) 3 Films on Pt(111)
journal, April 2011
- Li, Zhenjun; Zhang, Zhenrong; Kay, Bruce D.
- The Journal of Physical Chemistry C, Vol. 115, Issue 19
Growth of Ordered Ultrathin Tungsten Oxide Films on Pt(111)
journal, March 2011
- Li, Zhenjun; Zhang, Zhenrong; Kim, Yu Kwon
- The Journal of Physical Chemistry C, Vol. 115, Issue 13
Structure and Bonding of Tungsten Oxide Clusters on Nanostructured Cu-O Surfaces
journal, November 2011
- Wagner, M.; Surnev, S.; Ramsey, M. G.
- The Journal of Physical Chemistry C, Vol. 115, Issue 47
Preparation, Characterization, and Catalytic Properties of Tungsten Trioxide Cyclic Trimers on FeO(111)/Pt(111)
journal, December 2011
- Li, Shao-Chun; Li, Zhenjun; Zhang, Zhenrong
- The Journal of Physical Chemistry C, Vol. 116, Issue 1
Alcohol Dehydration on Monooxo W═O and Dioxo O═W═O Species
journal, July 2012
- Li, Zhenjun; Šmíd, Břetislav; Kim, Yu Kwon
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 16
Oxidation, Reduction, and Condensation of Alcohols over (MO 3 ) 3 (M = Mo, W) Nanoclusters
journal, September 2014
- Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.
- The Journal of Physical Chemistry C, Vol. 118, Issue 39
Ethanol Conversion on Cyclic (MO 3 ) 3 (M = Mo, W) Clusters
journal, February 2014
- Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.
- The Journal of Physical Chemistry C, Vol. 118, Issue 9
Dehydration, dehydrogenation, and condensation of alcohols on supported oxide catalysts based on cyclic (WO 3 ) 3 and (MoO 3 ) 3 clusters
journal, January 2014
- Rousseau, Roger; Dixon, David A.; Kay, Bruce D.
- Chem. Soc. Rev., Vol. 43, Issue 22
Formation of TiO 2 Nanoparticles by Reactive-Layer-Assisted Deposition and Characterization by XPS and STM
journal, July 2005
- Song, Zhen; Hrbek, Jan; Osgood, Richard
- Nano Letters, Vol. 5, Issue 7
Reaction of water with Ce–Au(111) and CeOx/Au(111) surfaces: Photoemission and STM studies
journal, June 2007
- Zhao, Xueing; Ma, Shuguo; Hrbek, Jan
- Surface Science, Vol. 601, Issue 12
Using Moiré Patterning to Map Surface Reactivity versus Atom Registration: Chemisorbed Trimethyl Acetic Acid on TiO/Au(111)
journal, December 2014
- Li, Zhisheng; Potapenko, Denis V.; Osgood, Richard M.
- The Journal of Physical Chemistry C, Vol. 118, Issue 51
Formation and fragmentation of gas-phase titanium/oxygen cluster positive ions
journal, September 1990
- Yu, Wen; Freas, Royal B.
- Journal of the American Chemical Society, Vol. 112, Issue 20
Electronic structure of titanium oxide clusters: TiOy (y = 1−3) and (TiO2)n (n = 1−4)
journal, November 1997
- Wu, Hongbin; Wang, Lai‐Sheng
- The Journal of Chemical Physics, Vol. 107, Issue 20
On the Titanium Oxide Neutral Cluster Distribution in the Gas Phase: Detection through 118 nm Single-Photon and 193 nm Multiphoton Ionization
journal, January 2005
- Matsuda, Yoshiyuki; Bernstein, Elliot R.
- The Journal of Physical Chemistry A, Vol. 109, Issue 2
Reactivity of Small Mo x O y - Clusters toward Methane and Ethane
journal, February 2006
- Wyrwas, Richard B.; Yoder, Bruce L.; Maze, Joshua T.
- The Journal of Physical Chemistry A, Vol. 110, Issue 6
R H and H 2 Production in Reactions between R OH and Small Molybdenum Oxide Cluster Anions
journal, April 2014
- Waller, Sarah E.; Jarrold, Caroline C.
- The Journal of Physical Chemistry A, Vol. 118, Issue 37
Probing the Electronic Structure and Band Gap Evolution of Titanium Oxide Clusters (TiO 2 ) n - ( n = 1−10) Using Photoelectron Spectroscopy
journal, March 2007
- Zhai, Hua-Jin; Wang, Lai-Sheng
- Journal of the American Chemical Society, Vol. 129, Issue 10
Theoretical Study of the Electronic Structure and Stability of Titanium Dioxide Clusters (TiO 2 ) n with n = 1−9
journal, May 2006
- Qu, Zheng-wang; Kroes, Geert-Jan
- The Journal of Physical Chemistry B, Vol. 110, Issue 18
Infrared Spectroscopy of Niobium Oxide Cluster Cations in a Molecular Beam: Identifying the Cluster Structures
journal, March 2003
- Fielicke, André; Meijer, Gerard; von Helden, Gert
- Journal of the American Chemical Society, Vol. 125, Issue 12
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions
journal, February 2007
- Rodriguez, José A.; Liu, Ping; Hrbek, Jan
- Angewandte Chemie International Edition, Vol. 46, Issue 8
Water-gas shift activity of Cu surfaces and Cu nanoparticles supported on metal oxides
journal, May 2009
- Rodriguez, J. A.; Liu, P.; Wang, X.
- Catalysis Today, Vol. 143, Issue 1-2
The Activation of Gold and the Water–Gas Shift Reaction: Insights from Studies with Model Catalysts
journal, November 2013
- Rodriguez, José A.; Senanayake, Sanjaya D.; Stacchiola, Dario
- Accounts of Chemical Research, Vol. 47, Issue 3
High Water−Gas Shift Activity in TiO 2 (110) Supported Cu and Au Nanoparticles: Role of the Oxide and Metal Particle Size
journal, April 2009
- Rodríguez, José A.; Evans, Jaime; Graciani, Jesús
- The Journal of Physical Chemistry C, Vol. 113, Issue 17
Water-gas-shift reaction on metal nanoparticles and surfaces
journal, April 2007
- Liu, Ping; Rodriguez, José A.
- The Journal of Chemical Physics, Vol. 126, Issue 16
CO Oxidation on Inverse CeO x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O 2
journal, March 2011
- Yang, Fan; Graciani, Jesús; Evans, Jaime
- Journal of the American Chemical Society, Vol. 133, Issue 10
Electronic charging of non-metallic clusters: size-selected MoxSy clusters supported on an ultrathin alumina film on NiAl(110)
journal, January 2012
- Zhou, Jing; Zhou, Jia; Camillone, Nicholas
- Physical Chemistry Chemical Physics, Vol. 14, Issue 22
On the Mutual Potential Energy of a Plane Network of Doublets
journal, February 1927
- Topping, J.
- Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 114, Issue 766
Density functional study of water-gas shift reaction on M3O3x/Cu(111)
journal, January 2012
- Vidal, Alba B.; Liu, Ping
- Physical Chemistry Chemical Physics, Vol. 14, Issue 48
Catalytic application of niobium compounds
journal, February 2003
- Tanabe, Kozo
- Catalysis Today, Vol. 78, Issue 1-4
Photoelectron spectroscopy and diffraction of NbO x /Nb(110) surface
journal, July 2008
- Razinkin, A. S.; Shalaeva, E. V.; Kuznetsov, M. V.
- The Physics of Metals and Metallography, Vol. 106, Issue 1
Niobium-containing catalysts—the state of the art
journal, February 2003
- Ziolek, Maria
- Catalysis Today, Vol. 78, Issue 1-4
Remote Control of Catalytic Sites by Spillover Species: A Chemical Reaction Engineering Approach∗
journal, February 1996
- Delmon, Bernard; Froment, Gilbert F.
- Catalysis Reviews, Vol. 38, Issue 1
Ab Initio Study of the H2–H2S/MoS2 Gas–Solid Interface: The Nature of the Catalytically Active Sites
journal, January 2000
- Raybaud, P.; Hafner, J.; Kresse, G.
- Journal of Catalysis, Vol. 189, Issue 1
DFT Calculations of Unpromoted and Promoted MoS2-Based Hydrodesulfurization Catalysts
journal, October 1999
- Byskov, Line S.; Nørskov, Jens K.; Clausen, Bjerne S.
- Journal of Catalysis, Vol. 187, Issue 1
One-Dimensional Metallic Edge States in
journal, October 2001
- Bollinger, M. V.; Lauritsen, J. V.; Jacobsen, K. W.
- Physical Review Letters, Vol. 87, Issue 19
Atomic-scale insight into structure and morphology changes of MoS2 nanoclusters in hydrotreating catalysts
journal, January 2004
- Lauritsen, J. V.; Bollinger, M. V.; Lægsgaard, E.
- Journal of Catalysis, Vol. 221, Issue 2, p. 510-522
Hydrodesulfurization reaction pathways on MoS2 nanoclusters revealed by scanning tunneling microscopy
journal, May 2004
- Lauritsen, J.V.; Nyberg, M.; Nørskov, J.K.
- Journal of Catalysis, Vol. 224, Issue 1, p. 94-106
Cluster−Support Interactions and Morphology of MoS 2 Nanoclusters in a Graphite-Supported Hydrotreating Model Catalyst
journal, October 2006
- Kibsgaard, Jakob; Lauritsen, Jeppe V.; Lægsgaard, Erik
- Journal of the American Chemical Society, Vol. 128, Issue 42
Scanning tunneling microscopy studies of TiO2-supported hydrotreating catalysts: Anisotropic particle shapes by edge-specific MoS2–support bonding
journal, April 2009
- Kibsgaard, Jakob; Clausen, Bjerne S.; Topsøe, Henrik
- Journal of Catalysis, Vol. 263, Issue 1
Spectroscopy, microscopy and theoretical study of NO adsorption on MoS2 and Co–Mo–S hydrotreating catalysts
journal, April 2011
- Topsøe, Nan-Yu; Tuxen, Anders; Hinnemann, Berit
- Journal of Catalysis, Vol. 279, Issue 2
Atomic-scale insight into adsorption of sterically hindered dibenzothiophenes on MoS2 and Co–Mo–S hydrotreating catalysts
journal, November 2012
- Tuxen, Anders K.; Füchtbauer, Henrik G.; Temel, Burcin
- Journal of Catalysis, Vol. 295
MoS2 nanoparticle morphologies in hydrodesulfurization catalysis studied by scanning tunneling microscopy
journal, December 2013
- Walton, A. S.; Lauritsen, J. V.; Topsøe, H.
- Journal of Catalysis, Vol. 308
Atomic-Scale Structure of Single-Layer Nanoclusters
journal, January 2000
- Helveg, S.; Lauritsen, J. V.; Lægsgaard, E.
- Physical Review Letters, Vol. 84, Issue 5
Chemistry of one-dimensional metallic edge states in MoS 2 nanoclusters
journal, February 2003
- Lauritsen, J. V.; Nyberg, M.; Vang, R. T.
- Nanotechnology, Vol. 14, Issue 3
Ethanethiol Decomposition Pathways on MoS 2 (0001)
journal, January 1996
- Peterson, Susan L.; Schulz, Kirk H.
- Langmuir, Vol. 12, Issue 4
Methanethiol Adsorption on Defective MoS 2 (0001) Surfaces
journal, August 1999
- Wiegenstein, Christopher G.; Schulz, Kirk H.
- The Journal of Physical Chemistry B, Vol. 103, Issue 33
Gas-Phase Production of Molybdenum Carbide, Nitride, and Sulfide Clusters and Nanocrystallites
journal, September 2003
- Lightstone, James M.; Mann, Heather A.; Wu, Ming
- The Journal of Physical Chemistry B, Vol. 107, Issue 38
Experimental and theoretical studies on inorganic magic clusters: M4X6 (M=W, Mo, X=O, S)
journal, October 2004
- Bertram, N.; Kim, Y. D.; Ganteför, G.
- Chemical Physics Letters, Vol. 396, Issue 4-6
Electronic and geometric structures of MoxSy and WxSy (x =1, 2, 4; y =1–12) clusters
journal, November 2005
- Gemming, S.; Tamuliene, J.; Seifert, G.
- Applied Physics A, Vol. 82, Issue 1
Transition metal sulfide clusters below the cluster-platelet transition: Theory and experiment: Transition metal sulfide clusters below the cluster-platelet transition
journal, May 2010
- Gemming, Sibylle; Seifert, Gotthard; Götz, Matthias
- physica status solidi (b), Vol. 247, Issue 5
Metal atom incorporation studies on AxMo6S8 Chevrel phases
journal, January 1980
- Umarji, A. M.; Rao, G. V. Subba; Janawadkar, M. P.
- Journal of Physics and Chemistry of Solids, Vol. 41, Issue 5
A new increasing delocalization of M=3d-elements (Ti, Fe, Co) in the channels network of the ternary MyMo6Se8 Chevrel phases
journal, February 2003
- Mançour-Billah, A.; Chevrel, R.
- Journal of Solid State Chemistry, Vol. 170, Issue 2
Thermal Deligation of Mo6S8L6 Cluster Complexes. EXAFS and Other Spectroscopic Techniques Support Retention of the Mo6S8 Cluster Unit up to 500 .degree.C
journal, March 1995
- Hilsenbeck, Shane J.; McCarley, Robert E.; Goldman, Alan I.
- Chemistry of Materials, Vol. 7, Issue 3
Nanoplatelets made from MoS2 and WS2
journal, January 2006
- Bertram, N.; Cordes, J.; Kim, Y. D.
- Chemical Physics Letters, Vol. 418, Issue 1-3
Characterization and Reactivity of the Mo 4 S 6 + Cluster Deposited on Au(111)
journal, July 2008
- Lightstone, James M.; Patterson, Melissa J.; Liu, Ping
- The Journal of Physical Chemistry C, Vol. 112, Issue 30
Formation of Mo and MoSx nanoparticles on Au(111) from Mo(CO)6 and S2 precursors: electronic and chemical properties
journal, September 2001
- Rodriguez, José A.; Dvorak, Joseph; Jirsak, Tomas
- Surface Science, Vol. 490, Issue 3
Size-dependent structure of MoS2 nanocrystals
journal, January 2007
- Lauritsen, Jeppe V.; Kibsgaard, Jakob; Helveg, Stig
- Nature Nanotechnology, Vol. 2, Issue 1
Structural and electronic properties of clusters deposited on a Au(111) surface investigated with density functional theory
journal, June 2007
- Popov, Igor; Gemming, Sibylle; Seifert, Gotthard
- Physical Review B, Vol. 75, Issue 24
Self-assembly of Mo 6S 8 clusters on the Au(111) surface
journal, May 2007
- Popov, I.; Kunze, T.; Gemming, S.
- The European Physical Journal D, Vol. 45, Issue 3
Effect of Sulfiding Temperature on Activity and Structures of CO-MO/AL2O3 Catalysts. ii
journal, January 1984
- Candia, Roberto; Sørensen, Ole; Villadsen, JØRgen
- Bulletin des Sociétés Chimiques Belges, Vol. 93, Issue 8-9
Effect of the support on the structure of Mo-based hydrodesulfurization catalysts: Activated carbon versus alumina*1
journal, June 1987
- Vissers, J.
- Journal of Catalysis, Vol. 105, Issue 2
A Density Functional Study of the Chemical Differences between Type I and Type II MoS 2 -Based Structures in Hydrotreating Catalysts †
journal, February 2005
- Hinnemann, Berit; Nørskov, Jens K.; Topsøe, Henrik
- The Journal of Physical Chemistry B, Vol. 109, Issue 6
Atomic Structure of Antiphase Domain Boundaries of a Thin Film on NiAl(110)
journal, December 2003
- Kulawik, M.; Nilius, N.; Rust, H. -P.
- Physical Review Letters, Vol. 91, Issue 25
Atomic structure of the ultrathin alumina on NiAl(110) and its antiphase domain boundaries as seen by frequency modulation dynamic force microscopy
journal, September 2009
- Simon, G. H.; König, T.; Rust, H-P
- New Journal of Physics, Vol. 11, Issue 9
X-ray Diffraction Study of the Ultrathin Al2O3 Layer on NiAl(110)
journal, March 2004
- Stierle, A.
- Science, Vol. 303, Issue 5664
One-dimensional (Mo3S3)n clusters: Building blocks of clusters materials and ideal nanowires for molecular electronics
journal, May 2009
- Gemming, S.; Seifert, G.; Bertram, N.
- Chemical Physics Letters, Vol. 474, Issue 1-3
Bonding Trends and Dimensionality Crossover of Gold Nanoclusters on Metal-Supported MgO Thin Films
journal, July 2006
- Ricci, Davide; Bongiorno, Angelo; Pacchioni, Gianfranco
- Physical Review Letters, Vol. 97, Issue 3
NO 2 Adsorption on Ag(100) Supported MgO(100) Thin Films: Controlling the Adsorption State with Film Thickness
journal, April 2009
- Starr, David E.; Weis, Christoph; Yamamoto, Susumu
- The Journal of Physical Chemistry C, Vol. 113, Issue 17
Charging of atoms, clusters, and molecules on metal-supported oxides: A general and long-ranged phenomenon
journal, August 2008
- Frondelius, Pentti; Hellman, Anders; Honkala, Karoliina
- Physical Review B, Vol. 78, Issue 8
Counting Electrons Transferred through a Thin Alumina Film into Au Chains
journal, March 2008
- Nilius, N.; Ganduglia-Pirovano, M. V.; Brázdová, V.
- Physical Review Letters, Vol. 100, Issue 9
Activation of by a Long-Ranged Chemical Bond Mechanism
journal, March 2008
- Hellman, Anders; Grönbeck, Henrik
- Physical Review Letters, Vol. 100, Issue 11
Adsorption of Late Transition Metal Atoms on MgO/Mo(100) and MgO/Ag(100) Ultrathin Films: A Comparative DFT Study
journal, September 2009
- Sicolo, Sabrina; Giordano, Livia; Pacchioni, Gianfranco
- The Journal of Physical Chemistry C, Vol. 113, Issue 38
A work function study of ultra-thin alumina formation on NiAl(110) surface
journal, September 2005
- Song, Weijie; Yoshitake, Michiko
- Applied Surface Science, Vol. 251, Issue 1-4
Photon mapping of MgO thin films with an STM
journal, May 2007
- Benia, H. M.; Nilius, N.; Freund, H. -J.
- Surface Science, Vol. 601, Issue 10
Tuning the Charge State of (WO 3 ) 3 Nanoclusters Deposited on MgO/Ag(001) Films
journal, August 2012
- Zhu, Jia; Giordano, Livia; Lin, Shujuan
- The Journal of Physical Chemistry C, Vol. 116, Issue 33
Mechanistic Study of Methanol Synthesis from CO 2 and H 2 on a Modified Model Mo 6 S 8 Cluster
journal, January 2015
- Liu, Cheng; Liu, Ping
- ACS Catalysis, Vol. 5, Issue 2
Methanol Synthesis from H 2 and CO 2 on a Mo 6 S 8 Cluster: A Density Functional Study †
journal, March 2010
- Liu, Ping; Choi, YongMan; Yang, Yixiong
- The Journal of Physical Chemistry A, Vol. 114, Issue 11
Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas
journal, January 2007
- Spivey, James J.; Egbebi, Adefemi
- Chemical Society Reviews, Vol. 36, Issue 9
A Review of Recent Literature to Search for an Efficient Catalytic Process for the Conversion of Syngas to Ethanol
journal, March 2008
- Subramani, Velu; Gangwal, Santosh K.
- Energy & Fuels, Vol. 22, Issue 2
EFFECTS OF ALKALI METAL HALIDES IN THE FORMATION OF ALCOHOLS FROM CO AND H 2 OVER SILICA-SUPPORTED MOLYBDENUM CATALYSTS
journal, May 1984
- Tatsumi, Takashi; Muramatsu, Atsushi; Tominaga, Hiro-o
- Chemistry Letters, Vol. 13, Issue 5
Kinetic modelling of higher alcohol synthesis over alkali-promoted Cu/ZnO and MoS2 catalysts
journal, January 1990
- Smith, Kevin J.; Herman, Richard G.; Klier, Kamil
- Chemical Engineering Science, Vol. 45, Issue 8
The activity of several molybdenum compounds for the methanation of CO2
journal, February 1981
- Saito, M.
- Journal of Catalysis, Vol. 67, Issue 2
Kinetics of reverse water gas shift (RWGS) reaction on metal disulfide catalysts
journal, October 1997
- Osaki, Toshihiko; Narita, Norichika; Horiuchi, Tatsuro
- Journal of Molecular Catalysis A: Chemical, Vol. 125, Issue 1
Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄)
journal, January 2010
- Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 33
Size-Dependent Magnetism of Deposited Small Iron Clusters Studied by X-Ray Magnetic Circular Dichroism
journal, July 2002
- Lau, J. T.; Föhlisch, A.; Nietubyc̀, R.
- Physical Review Letters, Vol. 89, Issue 5
Magnetic properties of small size-selected Co and CoPt clusters on Ni
journal, August 2012
- Glaser, L.; Chen, K.; Fiedler, S.
- Physical Review B, Vol. 86, Issue 7
Photoelectron spectroscopy under ambient pressure and temperature conditions
journal, March 2009
- Frank Ogletree, D.; Bluhm, Hendrik; Hebenstreit, Eleonore D.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 601, Issue 1-2
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy
journal, January 2013
- Starr, D. E.; Liu, Z.; Hävecker, M.
- Chemical Society Reviews, Vol. 42, Issue 13
Design of a new reactor-like high temperature near ambient pressure scanning tunneling microscope for catalysis studies
journal, March 2013
- (Feng) Tao, Franklin; Nguyen, Luan; Zhang, Shiran
- Review of Scientific Instruments, Vol. 84, Issue 3
In Situ Imaging of Cu 2 O under Reducing Conditions: Formation of Metallic Fronts by Mass Transfer
journal, October 2013
- Baber, Ashleigh E.; Xu, Fang; Dvorak, Filip
- Journal of the American Chemical Society, Vol. 135, Issue 45
Cationic gold clusters ligated with differently substituted phosphines: effect of substitution on ligand reactivity and binding
journal, January 2015
- Johnson, Grant E.; Olivares, Astrid; Hill, David
- Physical Chemistry Chemical Physics, Vol. 17, Issue 22
Soft landing of mass-selected gold clusters: Influence of ion and ligand on charge retention and reactivity
journal, February 2015
- Johnson, Grant E.; Laskin, Julia
- International Journal of Mass Spectrometry, Vol. 377
Preparation and in Situ Characterization of Surfaces Using Soft Landing in a Fourier Transform Ion Cyclotron Resonance Mass Spectrometer
journal, June 2005
- Alvarez, Jormarie; Cooks, R. Graham; Barlow, S. E.
- Analytical Chemistry, Vol. 77, Issue 11
Monodisperse Au 11 Clusters Prepared by Soft Landing of Mass Selected Ions
journal, November 2011
- Johnson, Grant E.; Wang, Chongmin; Priest, Thomas
- Analytical Chemistry, Vol. 83, Issue 21
Charge Retention by Gold Clusters on Surfaces Prepared Using Soft Landing of Mass Selected Ions
journal, December 2011
- Johnson, Grant E.; Priest, Thomas; Laskin, Julia
- ACS Nano, Vol. 6, Issue 1
Coverage-Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-Selected Ions
journal, November 2012
- Johnson, Grant E.; Priest, Thomas; Laskin, Julia
- The Journal of Physical Chemistry C, Vol. 116, Issue 47, p. 24977-24986
Atomically Precise Gold Nanoclusters as New Model Catalysts
journal, March 2013
- Li, Gao; Jin, Rongchao
- Accounts of Chemical Research, Vol. 46, Issue 8
Structural properties of nanoclusters: Energetic, thermodynamic, and kinetic effects
journal, May 2005
- Baletto, Francesca; Ferrando, Riccardo
- Reviews of Modern Physics, Vol. 77, Issue 1
Global optimization of clusters using electronic structure methods
journal, May 2013
- Heiles, Sven; Johnston, Roy L.
- International Journal of Quantum Chemistry, Vol. 113, Issue 18
Magic silver cluster on a MgO(100) terrace with defects
journal, October 2007
- Barcaro, Giovanni; Fortunelli, Alessandro
- Physical Review B, Vol. 76, Issue 16
A Magic Pd−Ag Binary Cluster on the F s -Defected MgO(100) Surface
journal, August 2007
- Barcaro, Giovanni; Fortunelli, Alessandro
- The Journal of Physical Chemistry C, Vol. 111, Issue 30
Structure of Ag Clusters Grown on Fs-Defect Sites of an MgO(1 0 0) Surface
journal, July 2007
- Barcaro, Giovanni; Aprà, Edoardo; Fortunelli, Alessandro
- Chemistry - A European Journal, Vol. 13, Issue 22
A genetic algorithm for first principles global structure optimization of supported nano structures
journal, July 2014
- Vilhelmsen, Lasse B.; Hammer, Bjørk
- The Journal of Chemical Physics, Vol. 141, Issue 4
Works referencing / citing this record:
An experimental and theoretical study of metallorganic coordination networks of tetrahydroxyquinone on Cu(111)
journal, January 2019
- Carlotto, Silvia; Mohebbi, Elaheh; Sedona, Francesco
- New Journal of Chemistry, Vol. 43, Issue 48
A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts
journal, October 2019
- Yang, Hongzhou; Shang, Lu; Zhang, Qinghua
- Nature Communications, Vol. 10, Issue 1
Ice Melting to Release Reactants in Solution Syntheses
journal, February 2018
- Wei, Hehe; Huang, Kai; Zhang, Le
- Angewandte Chemie International Edition, Vol. 57, Issue 13
Synergetic effects of strain engineering and substrate defects on generating highly efficient single-atom catalysts for CO oxidation
journal, January 2019
- Zhao, Ke; Zhu, Yandi; Shi, Jinlei
- Journal of Materials Chemistry A, Vol. 7, Issue 15
Influence of source parameters on the growth of metal nanoparticles by sputter-gas-aggregation
journal, November 2017
- Khojasteh, Malak; Kresin, Vitaly V.
- Applied Nanoscience, Vol. 7, Issue 8
Recent advances in the precise control of isolated single-site catalysts by chemical methods
journal, June 2018
- Li, Zhijun; Wang, Dehua; Wu, Yuen
- National Science Review, Vol. 5, Issue 5
CeO 2 (111) electronic reducibility tuned by ultra-small supported bimetallic Pt–Cu clusters
journal, January 2019
- Paz-Borbón, Lauro Oliver; Buendía, Fernando; Garzón, Ignacio L.
- Physical Chemistry Chemical Physics, Vol. 21, Issue 28
Fabrication of Single-Atom Catalysts with Precise Structure and High Metal Loading
journal, October 2018
- Wang, Jing; Li, Zhijun; Wu, Yuen
- Advanced Materials, Vol. 30, Issue 48
Nanostructured Metal Catalysts for Selective Hydrogenation and Oxidation of Cellulosic Biomass to Chemicals
journal, November 2018
- Jin, Xin; Fang, Tianqi; Wang, Jinyao
- The Chemical Record, Vol. 19, Issue 9
Performance of Preformed Au/Cu Nanoclusters Deposited on MgO Powders in the Catalytic Reduction of 4-Nitrophenol in Solution
journal, February 2018
- Cai, Rongsheng; Ellis, Peter R.; Yin, Jinlong
- Small, Vol. 14, Issue 13
Von isolierten Ionen zu mehrschichtigen funktionellen Materialien durch sanfte Landung von Ionen
journal, November 2018
- Laskin, Julia; Johnson, Grant E.; Warneke, Jonas
- Angewandte Chemie, Vol. 130, Issue 50
Morphology of size-selected Pt n clusters on CeO 2 (111)
journal, March 2018
- Shahed, Syed Mohammad Fakruddin; Beniya, Atsushi; Hirata, Hirohito
- The Journal of Chemical Physics, Vol. 148, Issue 11
Decomposition of Copper Formate Clusters: Insight into Elementary Steps of Calcination and Carbon Dioxide Activation
journal, November 2019
- Pascher, Tobias F.; Ončák, Milan; Linde, Christian
- ChemistryOpen, Vol. 8, Issue 12
Supported Noble‐Metal Single Atoms for Heterogeneous Catalysis
journal, July 2019
- Li, Xuning; Yang, Xiaofeng; Huang, Yanqiang
- Advanced Materials, Vol. 31, Issue 50
On the reductive hydrogenation process of gas-phase metal dioxides: H2 activation or reduction of the metal center, what is more important?
journal, August 2019
- González-Navarrete, Patricio; Calatayud, Monica
- Theoretical Chemistry Accounts, Vol. 138, Issue 8
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts
journal, February 2019
- Lee, Sungsik; Halder, Avik; Ferguson, Glen A.
- Nature Communications, Vol. 10, Issue 1
Understanding ligand effects in gold clusters using mass spectrometry
journal, January 2016
- Johnson, Grant E.; Laskin, Julia
- The Analyst, Vol. 141, Issue 12
Scale-up of cluster beam deposition to the gram scale with the matrix assembly cluster source for heterogeneous catalysis (propylene combustion)
journal, February 2020
- Cai, Rongsheng; Cao, Lu; Griffin, Ross
- AIP Advances, Vol. 10, Issue 2
A Systematic Study on Bond Activation Energies of NO, N 2 , and O 2 on Hexamers of Eight Transition Metals
journal, January 2019
- Ichino, Tomoya; Takagi, Makito; Maeda, Satoshi
- ChemCatChem, Vol. 11, Issue 4
Ultrasmall MoO x Clusters as a Novel Cocatalyst for Photocatalytic Hydrogen Evolution
journal, December 2018
- Zhang, Huabin; Zhang, Peng; Qiu, Mei
- Advanced Materials
Controlled deposition of size-selected MnO nanoparticle thin films for water splitting applications: reduction of onset potential with particle size
journal, March 2018
- Khojasteh, Malak; Haghighat, Shima; Dawlaty, Jahan M.
- Nanotechnology, Vol. 29, Issue 21
Atomic Cobalt on Defective Bimodal Mesoporous Carbon toward Efficient Oxygen Reduction for Zinc–Air Batteries
journal, January 2019
- Lyu, Xiao; Li, Gen; Chen, Xiaokang
- Small Methods, Vol. 3, Issue 9
Fabrication of electrocatalytic Ta nanoparticles by reactive sputtering and ion soft landing
journal, November 2016
- Johnson, Grant E.; Moser, Trevor; Engelhard, Mark
- The Journal of Chemical Physics, Vol. 145, Issue 17
Electrocatalytic Water Splitting and CO 2 Reduction: Sustainable Solutions via Single‐Atom Catalysts Supported on 2D Materials
journal, February 2019
- Kwon, Ki Chang; Suh, Jun Min; Varma, Rajender S.
- Small Methods, Vol. 3, Issue 9
Using first principles calculations to interpret XANES experiments: extracting the size-dependence of the ( p , T ) phase diagram of sub-nanometer Cu clusters in an O 2 environment
journal, February 2019
- Mammen, Nisha; Spanu, Leonardo; Tyo, Eric C.
- Journal of Physics: Condensed Matter, Vol. 31, Issue 14
CO 2 electroreduction performance of a single transition metal atom supported on porphyrin-like graphene: a computational study
journal, January 2017
- Wang, Zhongxu; Zhao, Jingxiang; Cai, Qinghai
- Physical Chemistry Chemical Physics, Vol. 19, Issue 34
Mapping XANES spectra on structural descriptors of copper oxide clusters using supervised machine learning
journal, October 2019
- Liu, Yang; Marcella, Nicholas; Timoshenko, Janis
- The Journal of Chemical Physics, Vol. 151, Issue 16
The stability and oxidation of supported atomic-size Cu catalysts in reactive environments
journal, August 2019
- Iyemperumal, Satish Kumar; Fenton, Thomas G.; Gillingham, Samantha L.
- The Journal of Chemical Physics, Vol. 151, Issue 5
Self-organizing layers from complex molecular anions
journal, May 2018
- Warneke, Jonas; McBriarty, Martin E.; Riechers, Shawn L.
- Nature Communications, Vol. 9, Issue 1
Computational Modeling of Nanoparticle Coalescence
journal, March 2019
- Grammatikopoulos, Panagiotis; Sowwan, Mukhles; Kioseoglou, Joseph
- Advanced Theory and Simulations, Vol. 2, Issue 6
Activation of CO 2 by supported Cu clusters
journal, January 2017
- Iyemperumal, Satish Kumar; Deskins, N. Aaron
- Physical Chemistry Chemical Physics, Vol. 19, Issue 42
Moving Frontiers in Transition Metal Catalysis: Synthesis, Characterization and Modeling
journal, February 2019
- Sharapa, Dmitry I.; Doronkin, Dmitry E.; Studt, Felix
- Advanced Materials, Vol. 31, Issue 26
Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions
journal, May 2018
- Guo, Yu; Zhang, Ya-Wen
- Topics in Catalysis, Vol. 61, Issue 9-11
Perspective: Size selected clusters for catalysis and electrochemistry
journal, March 2018
- Halder, Avik; Curtiss, Larry A.; Fortunelli, Alessandro
- The Journal of Chemical Physics, Vol. 148, Issue 11
Single Metal Atom Photocatalysis
journal, January 2019
- Wang, Bin; Cai, Hairui; Shen, Shaohua
- Small Methods, Vol. 3, Issue 9
From Isolated Ions to Multilayer Functional Materials Using Ion Soft Landing
journal, November 2018
- Laskin, Julia; Johnson, Grant E.; Warneke, Jonas
- Angewandte Chemie International Edition, Vol. 57, Issue 50
A Sustainable Biomineralization Approach for the Synthesis of Highly Fluorescent Ultra-Small Pt Nanoclusters
journal, October 2019
- Balu, Rajkamal; Knott, Robert; Elvin, Christopher M.
- Biosensors, Vol. 9, Issue 4
Ice Melting to Release Reactants in Solution Syntheses
journal, February 2018
- Wei, Hehe; Huang, Kai; Zhang, Le
- Angewandte Chemie, Vol. 130, Issue 13
Moving Frontiers in Transition Metal Catalysis: Synthesis, Characterization and Modeling
text, January 2019
- Sharapa, D. I.; Doronkin, D. E.; Studt, F.
- Wiley
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts
journal, February 2019
- Lee, Sungsik; Halder, Avik; Ferguson, Glen A.
- Nature Communications, Vol. 10, Issue 1
A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts
journal, October 2019
- Yang, Hongzhou; Shang, Lu; Zhang, Qinghua
- Nature Communications, Vol. 10, Issue 1
A Sustainable Biomineralization Approach for the Synthesis of Highly Fluorescent Ultra-Small Pt Nanoclusters
journal, October 2019
- Balu, Rajkamal; Knott, Robert; Elvin, Christopher M.
- Biosensors, Vol. 9, Issue 4