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Title: New perspective on glycoside hydrolase binding to lignin from pretreated corn stover

Journal Article · · Biotechnology for Biofuels

Background: Non-specific binding of cellulases to lignin has been implicated as a major factor in the loss of cellulase activity during biomass conversion to sugars. It is believed that this binding may strongly impact process economics through loss of enzyme activities during hydrolysis and enzyme recycling scenarios. The current model suggests glycoside hydrolase activities are lost though non-specific/non-productive binding of carbohydrate-binding domains to lignin, limiting catalytic site access to the carbohydrate components of the cell wall. Results: In this study, we compared component enzyme affinities of a commercial Trichoderma reesei cellulase formulation, Cellic CTec2, towards extracted corn stover lignin using sodium dodecyl sulfate-polyacrylamide gel electrophoresis and p-nitrophenyl substrate activities to monitor component binding, activity loss, and total protein binding. Protein binding was strongly affected by pH and ionic strength. β-D-glucosidases and xylanases, which do not have carbohydrate-binding modules (CBMs) and are basic proteins, demonstrated the strongest binding at low ionic strength, suggesting that CBMs are not the dominant factor in enzyme adsorption to lignin. Despite strong adsorption to insoluble lignin, β-D-glucosidase and xylanase activities remained high, with process yields decreasing only 4–15 % depending on lignin concentration. Conclusion: We propose that specific enzyme adsorption to lignin from a mixture of biomass-hydrolyzing enzymes is a competitive affinity where β-D-glucosidases and xylanases can displace CBM interactions with lignin. Process parameters, such as temperature, pH, and salt concentration influence the individual enzymes’ affinity for lignin, and both hydrophobic and electrostatic interactions are responsible for this binding phenomenon. Moreover, our results suggest that concern regarding loss of critical cell wall degrading enzymes to lignin adsorption may be unwarranted when complex enzyme mixtures are used to digest biomass.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Alliance for Sustainable Energy, LLC (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)
Grant/Contract Number:
AC36–08GO28308; AC36-08GO28308
OSTI ID:
1618630
Alternate ID(s):
OSTI ID: 1236147; OSTI ID: 1239800
Report Number(s):
NREL/JA-2700-64797; 214; PII: 397
Journal Information:
Biotechnology for Biofuels, Journal Name: Biotechnology for Biofuels Vol. 8 Journal Issue: 1; ISSN 1754-6834
Publisher:
Springer Science + Business MediaCopyright Statement
Country of Publication:
Netherlands
Language:
English
Citation Metrics:
Cited by: 71 works
Citation information provided by
Web of Science

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Cited By (14)

Toward a fundamental understanding of cellulase-lignin interactions in the whole slurry enzymatic saccharification process: Elucidating Cellulase-Lignin Interactions for Whole Slurry Saccharification journal July 2016
Using a linear pH-responsive zwitterionic copolymer to recover cellulases in enzymatic hydrolysate and to enhance the enzymatic hydrolysis of lignocellulose journal June 2019
The effect of alkali-soluble lignin on purified core cellulase and hemicellulase activities during hydrolysis of extractive ammonia-pretreated lignocellulosic biomass journal June 2018
Cellulases adsorb reversibly on biomass lignin: DJAJADI et al. journal October 2018
Preparation of high molecular weight pH-responsive lignin-polyethylene glycol (L-PEG) and its application in enzymatic saccharification of lignocelluloses journal November 2019
Benchmarking hydrolytic potential of cellulase cocktail obtained from mutant strain of Talaromyces verruculosus IIPC 324 with commercial biofuel enzymes journal January 2019
Effect of cellulolytic enzyme binding on lignin isolated from alkali and acid pretreated switchgrass on enzymatic hydrolysis journal November 2019
Recovering cellulase and increasing glucose yield during lignocellulosic hydrolysis using lignin-MPEG with a sensitive pH response journal January 2019
Model-based optimization and scale-up of multi-feed simultaneous saccharification and co-fermentation of steam pre-treated lignocellulose enables high gravity ethanol production journal April 2016
Stimulation and inhibition of enzymatic hydrolysis by organosolv lignins as determined by zeta potential and hydrophobicity journal June 2017
Adding tetrahydrofuran to dilute acid pretreatment provides new insights into substrate changes that greatly enhance biomass deconstruction by Clostridium thermocellum and fungal enzymes journal November 2017
Lignin from hydrothermally pretreated grass biomass retards enzymatic cellulose degradation by acting as a physical barrier rather than by inducing nonproductive adsorption of enzymes journal April 2018
Penicillium citrinum UFV1 β-glucosidases: purification, characterization, and application for biomass saccharification journal August 2018
Brassinosteroid overproduction improves lignocellulose quantity and quality to maximize bioethanol yield under green-like biomass process in transgenic poplar journal January 2020

Figures / Tables (13)