Enhanced Raman Scattering on In-plane Anisotropic Layered Materials

Liang, Liangbo; Meunier, Vincent; Sumpter, Bobby G.; Ling, Xi; Lin, Jingjing; Zhang, Shuqing; Mao, Nannan; Zhang, Na; Tong, Lianming; Zhang, Jin

doi:10.1021/jacs.5b10144

Title: Enhanced Raman Scattering on In-plane Anisotropic Layered Materials

Journal Article · Thu Nov 19 00:00:00 EST 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b10144· OSTI ID:1235000

Liang, Liangbo ^[1]; Meunier, Vincent ^[2]; Sumpter, Bobby G. ^[1]; Ling, Xi ^[3]; Lin, Jingjing ^[4]; Zhang, Shuqing ^[4]; Mao, Nannan ^[4]; Zhang, Na ^[4]; Tong, Lianming ^[4]; Zhang, Jin ^[4]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Rensselaer Polytechnic Inst., Troy, NY (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Chinese Academy of Sciences (CAS), Beijing (China). National Laboratory for Molecular Sciences (BNLMS)

Surface-enhanced Raman scattering (SERS) on two-dimensional (2D) layered materials has provided a unique platform to study the chemical mechanism (CM) of the enhancement due to its natural separation from electromagnetic enhancement. The CM stems from the basic charge interactions between the substrate and molecules. Despite the extensive studies of the energy alignment between 2D materials and molecules, an understanding of how the electronic properties of the substrate are explicitly involved in the charge interaction is still unclear. Lately, a new group of 2D layered materials with anisotropic structure, including orthorhombic black phosphorus (BP) and triclinic rhenium disulphide (ReS2), has attracted great interest due to their unique anisotropic electrical and optical properties. Herein, we report a unique anisotropic Raman enhancement on few-layered BP and ReS2 using copper phthalocyanine (CuPc) molecules as a Raman probe, which is absent on isotropic graphene and h-BN. According to detailed Raman tensor analysis and density functional theory calculations, anisotropic charge interactions due to the anisotropic carrier mobilities of the 2D materials are responsible for the angular dependence of the Raman enhancement. Our findings not only provide new insights into the CM process in SERS, but also open up new avenues for the exploration and application of the electronic properties of anisotropic 2D layered materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1235000

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 49; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 112 works

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