Acid–Base Bifunctional Shell Cross-Linked Micelle Nanoreactor for One-Pot Tandem Reaction
- School of Chemical &, Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0100, United States
- Molecular Design Institute and Department of Chemistry, New York University, New York, New York 10003-6688, United States
Shell cross-linked micelles (SCMs) containing acidic sites in the shell and basic sites in the core are prepared from amphiphilic poly(2-oxazoline) triblock copolymers. The materials are utilized as two chamber nanoreactors for a prototypical acid-base bifunctional tandem deacetalization-nitroaldol reaction. The acid and base sites are localized in different regions of the micelle, allowing the two steps in the reaction sequence to largely proceed in separate compartments, akin to the compartmentalization that occurs in biological systems.
- Research Organization:
- Georgia Institute of Technology, Atlanta, GA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- FG02-03ER15459
- OSTI ID:
- 1234184
- Alternate ID(s):
- OSTI ID: 1240019; OSTI ID: 1657459
- Journal Information:
- ACS Catalysis, Journal Name: ACS Catalysis Vol. 6 Journal Issue: 2; ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 87 works
Citation information provided by
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