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Title: Carbide Coatings for Nickel Alloys, Graphite and Carbon/Carbon Composites to be used in Fluoride Salt Valves

Technical Report ·
DOI:https://doi.org/10.2172/1233714· OSTI ID:1233714
 [1];  [1]
  1. Johns Hopkins Univ., Baltimore, MD (United States)

The focus of this research was concerned with developing materials technology that supports the evolution of Generation IV Advanced High Temperature Reactor (AHTR) concepts. Specifically, we investigate refractory carbide coatings for 1) nickel alloys, and 2) commercial carbon-carbon composites (CCCs). Numerous compelling reasons have driven us to focus on carbon and carbide materials. First, unlike metals, the strength and modulus of CCCs increase with rising temperature. Secondly, graphite and carbon composites have been proven effective for resisting highly corrosive fluoride melts such as molten cryolite [Na₃AlF₆] at ~1000°C in aluminum reduction cells. Thirdly, graphite and carbide materials exhibit extraordinary radiation damage tolerance and stability up to 2000°C. Finally, carbides are thermodynamically more stable in liquid fluoride salt than the corresponding metals (i.e. Cr and Zr) found in nickel based alloys.

Research Organization:
Johns Hopkins Univ., Baltimore, MD (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE)
DOE Contract Number:
AC07-05ID14517
OSTI ID:
1233714
Report Number(s):
10-857; 10-857
Country of Publication:
United States
Language:
English

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