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Title: Direct Epoxidation of Propylene over Stavilized Cu Surface Sites on Titanium-Modified Cu2O

Journal Article · · Angewandte Chemie International Edition (Online)
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Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC00112704
OSTI ID:
1229020
Report Number(s):
BNL-111095-2015-JA
Journal Information:
Angewandte Chemie International Edition (Online), Vol. 54, Issue 41; ISSN 1521-3773
Publisher:
Gesselschaft Deutscher Chemiker
Country of Publication:
United States
Language:
English

References (28)

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High Catalytic Performance of MoO 3 -Bi 2 SiO 5 /SiO 2 for the Gas-Phase Epoxidation of Propylene by Molecular Oxygen journal February 2014
Reaction-Controlled Phase-Transfer Catalysis for Propylene Epoxidation to Propylene Oxide journal May 2001
Selective Vapor-Phase Epoxidation of Propylene over Au/TiO2Catalysts in the Presence of Oxygen and Hydrogen journal September 1998
Selective Propene Epoxidation on Immobilized Au 6-10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity journal February 2009
Selective Propene Epoxidation on Immobilized Au 6–10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity journal January 2009
Ethylene Epoxidation on Ag: Identification of the Crucial Surface Intermediate by Experimental and Theoretical Investigation of its Electronic Structure journal May 2004
Ethylene Epoxidation on Ag: Identification of the Crucial Surface Intermediate by Experimental and Theoretical Investigation of its Electronic Structure journal May 2004
Catalytic epoxidation of propene with H2O–O 2 reactants on Au/TiO 2 journal January 2009
Trimethylamine as a Gas-Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts journal January 2006
Trimethylamine as a Gas-Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts journal January 2006
Crystal-Plane-Controlled Selectivity of Cu 2 O Catalysts in Propylene Oxidation with Molecular Oxygen journal April 2014
Crystal-Plane-Controlled Selectivity of Cu 2 O Catalysts in Propylene Oxidation with Molecular Oxygen journal April 2014
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects journal April 2010
Tuning Selectivity in Propylene Epoxidation by Plasmon Mediated Photo-Switching of Cu Oxidation State journal March 2013
The Formation of Epoxides from Reactions of Oxametallacycles on Ag(110):  A Density Functional Theory Study journal October 2001
Oxametallacycle formation via ring-opening of 1-epoxy-3-butene on Ag(110): a combined experimental/theoretical approach journal December 2000
Low-Basicity Oxygen Atoms: A Key in the Search for Propylene Epoxidation Catalysts journal March 2007
Low-Basicity Oxygen Atoms: A Key in the Search for Propylene Epoxidation Catalysts journal March 2007
Copper as a selective catalyst for the epoxidation of propene journal December 2005
Chemical Structures and Performance of Perovskite Oxides journal July 2001
Catalysis Science of Bulk Mixed Oxides journal April 2012
Stabilization of Catalytically Active Cu + Surface Sites on Titanium-Copper Mixed-Oxide Films journal April 2014
Stabilization of Catalytically Active Cu + Surface Sites on Titanium-Copper Mixed-Oxide Films journal April 2014
Autocatalytic Reduction of a Cu 2 O/Cu(111) Surface by CO: STM, XPS, and DFT Studies journal July 2010
Effects of added 3d transition-metals on Ag-based catalysts for direct epoxidation of propylene by oxygen journal October 2005
Promoters in heterogeneous catalysis: The role of Cl on ethylene epoxidation over Ag journal April 2014
In Situ Imaging of Cu 2 O under Reducing Conditions: Formation of Metallic Fronts by Mass Transfer journal October 2013

Cited By (7)

Correlation between Copper Oxide Particle Size and Selectivity towards Propylene Oxide in Selective Oxidation of Propene journal November 2018
Über den Technologiewandel in der Propylenoxid-Herstellung: Vom Chlor zum Sauerstoff journal March 2017
Tuning the Catalytic Performance of Novel Composites Based on ZIF-8 and Nafen through Dimensional and Concentration Effects in the Synthesis of Propylene Glycol Methyl Ether: Tuning the Catalytic Performance of Novel Composites Based on ZIF-8 and Nafen through Dimensional and Concentration Effects in the Synthesis of Propyl journal June 2019
The oxidation of copper catalysts during ethylene epoxidation journal January 2015
Surface chemistry of group IB metals and related oxides journal January 2017
Enhanced hydrogenation of ethyl-levulinate to γ-valerolactone over Ni δ O x stabilized Cu + surface sites journal January 2016
A density functional theory study of propylene epoxidation mechanism on Ag 2 O(001) surface journal January 2018

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