skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High-Resolution Mass Spectrometry and Molecular Characterization of Aqueous Photochemistry Products of Common Types of Secondary Organic Aerosols

Journal Article · · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
DOI:https://doi.org/10.1021/jp509476r· OSTI ID:1224935
 [1]; ; ;  [1]
  1. Department of Chemistry, University of California, Irvine, California 92697, United States

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI ID:
1224935
Journal Information:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Vol. 119 Journal Issue: 11; ISSN 1089-5639
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 55 works
Citation information provided by
Web of Science

References (84)

Technical Note: Molecular characterization of aerosol-derived water soluble organic carbon using ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry journal January 2008
Photochemical Aging of Secondary Organic Aerosol Particles Generated from the Oxidation of d-Limonene journal March 2007
Oligomers, organosulfates, and nitrooxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry journal January 2009
Fulvic Acids as Transition State of Organic Matter:  Indications from High Resolution Mass Spectrometry journal October 2006
Aerosol effects on the inter-cloud region of a small cumulus cloud field journal January 2009
The Effect of Solvent on the Analysis of Secondary Organic Aerosol Using Electrospray Ionization Mass Spectrometry journal October 2008
Molecular Characterization of Organosulfates in Organic Aerosols from Shanghai and Los Angeles Urban Areas by Nanospray-Desorption Electrospray Ionization High-Resolution Mass Spectrometry journal August 2014
Gas/Particle Partitioning and Secondary Organic Aerosol Yields journal July 1996
Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies journal January 2011
High-resolution mass spectrometric analysis of secondary organic aerosol produced by ozonation of limonene journal January 2008
Structural Changes in a Dissolved Soil Humic Acid during Photochemical Degradation Processes under O 2 and N 2 Atmosphere journal September 1998
Elemental Analysis of Organic Species with Electron Ionization High-Resolution Mass Spectrometry journal November 2007
High molecular weight SOA formation during limonene ozonolysis: insights from ultrahigh-resolution FT-ICR mass spectrometry characterization journal January 2012
Time-resolved molecular characterization of limonene/ozone aerosol using high-resolution electrospray ionization mass spectrometry journal January 2009
Photochemical generation of reactive species upon irradiation of rainwater: Negligible photoactivity of dissolved organic matter journal July 2010
Fogwater chemistry at Riverside, California journal January 1990
Nitrogen-Containing Organic Compounds and Oligomers in Secondary Organic Aerosol Formed by Photooxidation of Isoprene journal August 2011
Photolytic processing of secondary organic aerosols dissolved in cloud droplets journal January 2011
Fine Particle and Gaseous Emission Rates from Residential Wood Combustion journal June 2000
Molecular Characterization of Nitrogen-Containing Organic Compounds in Biomass Burning Aerosols Using High-Resolution Mass Spectrometry journal May 2009
Seasonal variation in molecular mass and optical properties of chromophoric dissolved organic material in coastal waters of southwest Florida journal October 2004
Absorption Spectra and Photolysis of Methyl Peroxide in Liquid and Frozen Water journal January 2012
Campholenic aldehyde ozonolysis: a mechanism leading to specific biogenic secondary organic aerosol constituents journal January 2014
Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement VI. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry journal November 1997
Ultrafast photochemistry of methyl hydroperoxide on ice particles journal October 2009
Molecular characterization of organic aerosol using nanospray desorption/electrospray ionization mass spectrometry: CalNex 2010 field study journal April 2013
Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry journal January 2008
Molecular Characterization of Biomass Burning Aerosols Using High-Resolution Mass Spectrometry journal February 2009
Secondary organic aerosol production from aqueous photooxidation of glycolaldehyde: Laboratory experiments journal March 2009
Photoinduced Oligomerization of Aqueous Pyruvic Acid journal March 2006
Experimental and Theoretical Study of Aqueous cis -Pinonic Acid Photolysis journal November 2013
Technical Note: Spectral representation of spatial correlations in variational assimilation with grid point models and application to the Belgian Assimilation System for Chemical Observations (BASCOE) journal January 2012
Photochemical degradation of dissolved organic carbon and its impact on the oceanic carbon cycle journal September 1991
Composition of Dissolved Organic Nitrogen in Continental Precipitation Investigated by Ultra-High Resolution FT-ICR Mass Spectrometry journal September 2009
Molecular Composition of Boreal Forest Aerosol from Hyytiälä, Finland, Using Ultrahigh Resolution Mass Spectrometry journal April 2013
Organosulfates in Humic-like Substance Fraction Isolated from Aerosols at Seven Locations in East Asia: A Study by Ultra-High-Resolution Mass Spectrometry journal December 2012
Molecular composition of biogenic secondary organic aerosols using ultrahigh-resolution mass spectrometry: comparing laboratory and field studies journal January 2014
Dominant factors controlling concentrations of aldehydes in rain, fog, dew water, and in the gas phase journal December 2005
Contributions of Organic Peroxides to Secondary Aerosol Formed from Reactions of Monoterpenes with O 3 journal June 2005
Peroxy radicals journal January 1969
Thermodynamics and kinetics of the hydrolysis of atmospherically relevant organonitrates and organosulfates journal January 2011
O/C and OM/OC Ratios of Primary, Secondary, and Ambient Organic Aerosols with High-Resolution Time-of-Flight Aerosol Mass Spectrometry journal June 2008
Aqueous chemistry and its role in secondary organic aerosol (SOA) formation journal January 2010
High-resolution mass spectrometry analysis of secondary organic aerosol generated by ozonolysis of isoprene journal March 2010
Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol journal January 2011
Appearance of strong absorbers and fluorophores in limonene-O 3 secondary organic aerosol due to NH 4 + -mediated chemical aging over long time scales journal January 2010
A review and synthesis of monoterpene speciation from forests in the United States journal January 2000
The Elucidation of Peroxyl Radical Reactions in Aqueous Solution with the Help of Radiation-Chemical Methods journal October 1991
Photochemical Kinetics of Pyruvic Acid in Aqueous Solution journal April 2014
Probing molecular associations of field-collected and laboratory-generated SOA with nano-DESI high-resolution mass spectrometry: SOA COMPOSITION WITH NANO-DESI HR-MS journal January 2013
SOA from methylglyoxal in clouds and wet aerosols: Measurement and prediction of key products journal December 2010
Degradation of nitrobenzene and nitrophenols by means of advanced oxidation processes in a homogeneous phase: Photolysis in the presence of hydrogen peroxide versus the Fenton reaction journal May 1992
Investigating the composition of organic aerosol resulting from cyclohexene ozonolysis: low molecular weight and heterogeneous reaction products journal January 2006
Alternative pathway for atmospheric particles growth journal April 2012
Uncertainties and assessments of chemistry-climate models of the stratosphere journal January 2003
Formation of brown carbon via reactions of ammonia with secondary organic aerosols from biogenic and anthropogenic precursors journal December 2012
Applications of High-Resolution Electrospray Ionization Mass Spectrometry to Measurements of Average Oxygen to Carbon Ratios in Secondary Organic Aerosols journal July 2012
Organic aerosol formation from the oxidation of biogenic hydrocarbons journal February 1999
Brown carbon formation from ketoaldehydes of biogenic monoterpenes journal January 2013
Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer journal December 2006
Molecular Characterization of Organic Aerosols Using Nanospray-Desorption/Electrospray Ionization-Mass Spectrometry journal October 2010
Direct aqueous photochemistry of isoprene high-NOx secondary organic aerosol journal January 2012
Concentrations and Sources of VOCs in Urban Domestic and Public Microenvironments journal March 2001
Secondary Organic Aerosol Formation from Acetylene (C 2 H 2 ): seed effect on SOA yields due to organic photochemistry in the aerosol aqueous phase journal January 2009
An approach toward quantification of organic compounds in complex environmental samples using high-resolution electrospray ionization mass spectrometry journal January 2013
Carboxylic Acids in Secondary Aerosols from Oxidation of Cyclic Monoterpenes by Ozone journal March 2000
Direct analysis of highly oxidised organic aerosol constituents by on-line ion trap mass spectrometry in the negative-ion mode journal January 2002
From mass to structure: an aromaticity index for high-resolution mass data of natural organic matter journal February 2006
Effects of anthropogenic emissions on the molecular composition of urban organic aerosols: An ultrahigh resolution mass spectrometry study journal June 2014
Phototransformation processes of 2,4-dinitrophenol, relevant to atmospheric water droplets journal August 2010
Effect of Solar Radiation on the Optical Properties and Molecular Composition of Laboratory Proxies of Atmospheric Brown Carbon journal August 2014
Probing the Source of Hydrogen Peroxide Associated with Coarse Mode Aerosol Particles in Southern California journal June 2010
An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol journal January 1994
Case Study of Water-Soluble Metal Containing Organic Constituents of Biomass Burning Aerosol journal February 2011
Formation and Stability of Atmospherically Relevant Isoprene-Derived Organosulfates and Organonitrates journal March 2011
Water-Soluble Atmospheric Organic Matter in Fog: Exact Masses and Chemical Formula Identification by Ultrahigh-Resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry journal May 2010
Analysis of the Unresolved Organic Fraction in Atmospheric Aerosols with Ultrahigh-Resolution Mass Spectrometry and Nuclear Magnetic Resonance Spectroscopy: Organosulfates As Photochemical Smog Constituents journal October 2010
Ultrahigh Mass Resolution and Accurate Mass Measurements as a Tool To Characterize Oligomers in Secondary Organic Aerosols journal June 2007
Molecular chemistry of organic aerosols through the application of high resolution mass spectrometry journal January 2011
Photochemistry and environment XIII: Phototransformation of 2-nitrophenol in aqueous solution journal July 1991
Identification of water-soluble organic carbon in non-urban aerosols using ultrahigh-resolution FT-ICR mass spectrometry: organic anions journal January 2012
Thermochromism of Model Organic Aerosol Matter journal November 2009
Seasonal differences of urban organic aerosol composition – an ultra-high resolution mass spectrometry study journal January 2012
Photodecomposition of Aldehydes and Ketones journal December 1936