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Title: Methods of refining natural oils and methods of producing fuel compositions

A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent selected from the group consisting of phosphorous acid, phosphinic acid, and a combination thereof; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.
Authors:
; ;
Publication Date:
OSTI Identifier:
1224887
Report Number(s):
9,175,231
13/335,538
DOE Contract Number:
EE0002872
Resource Type:
Patent
Resource Relation:
Patent File Date: 2011 Dec 22
Research Org:
Elevance Renewable Sciences, Inc., Woodridge, IL (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
02 PETROLEUM