skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Investigation of phase miscibility of CoCrPt thin films using anomalous x-ray scattering and extended x-ray absorption fine structure

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.2188041· OSTI ID:1223951
 [1];  [2];  [3];  [4];  [5];  [6]
  1. National Univ. of Singapore (Singapore); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. National Univ. of Singapore (Singapore)
  3. Chonbuk National Univ., Jeonju (Korea)
  4. Univ. of Minnesota, Minneapolis, MN (United States)
  5. Academia Sinica, Taiwan (China)
  6. Pohang Univ. of Science and Technology, Pohang (Korea)

The phase miscibility of Co, Cr and Pt in oriented nanostructured CoCrPt magnetic thin films was investigated using anomalous x-ray scattering (AXS) from the (002) reflection and extended x-ray absorption fine structure (EXAFS) at CoK, CrK and PtLIII edges. The AXS measurements at CoK edge clearly showed the presence of Co in the crystalline region. However, Cr was not detected in the lattice. The EXAFS at CoK edge indicated that the nearest neighboring atoms of Co were mixed with 80% Co and 20% Pt, consistent with the results of EXAFS at PtLIII edge. Our observations suggested that only Pt and Co were at the Co (002) lattice of the nanotextured CoCrPt thin films. Here, this indicated that the AXS alone may not be reliable to determine the phase miscibility in textured thin films. Complementary information from the EXAFS was useful to understand the phase miscibility of nanoscale materials.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); NUS Academic Research Grant; US Department of the Navy, Office of Naval Research (ONR)
Grant/Contract Number:
W-31-109-ENG-38
OSTI ID:
1223951
Journal Information:
Applied Physics Letters, Vol. 88, Issue 12; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
ENGLISH
Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

References (25)

Magnetic properties of electron beam evaporated CoPt alloy thin films journal January 1997
Magneto-optical Kerr spectroscopy of a new chemically ordered alloy: Co 3 Pt journal October 1993
Segregated microstructure in sputtered Co‐Cr film revealed by selective wet etching journal March 1987
A suite of programs for calculating x‐ray absorption, reflection, and diffraction performance for a variety of materials at arbitrary wavelengths journal January 1992
The UWXAFS analysis package: philosophy and details journal March 1995
Structural study of CoCrPt films by anomalous x-ray scattering and extended x-ray absorption fine structure journal March 2002
Grain growth and ordering kinetics in CoPt thin films journal January 1996
Evidence of a Surface-Mediated Magnetically Induced Miscibility Gap in Co-Pt Alloy Thin Films journal August 1995
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure journal September 1998
Selective Study of Fe Atoms at the Interfaces of an Fe/Ir(100) Superlattice by means of Diffraction Anomalous Fine Structure journal April 1997
Observation of internal interfaces in Pt x Co 1 x ( x 0.7 ) alloy films: A likely cause of perpendicular magnetic anisotropy journal August 1996
Interfacial structure in (111) Au:Ni multilayers investigated by anomalous x-ray diffraction journal September 2001
Local structure in the stripe phase of La 1.6 x Sr x Nd 0.4 CuO 4 journal September 2002
Determination of absolute indium content in InGaN/GaN multiple quantum wells using anomalous x-ray scattering journal December 2002
Structure determination of nanostructured Ni–Co films by anomalous x-ray scattering journal October 1999
Quantitative measurement of Cr segregation in Co0.8−xCrxPt0.1B0.1 recording media by scatter diagram analysis journal February 2002
Long-range order and short-range order study on CoCrPt/Ti films by synchrotron x-ray scattering and extended x-ray absorption fine structure spectroscopy journal January 2002
Effects of Pt and Ta addition on compositional microstructure of CoCr-alloy thin film media journal May 2000
Experimental observation of solute segregation in longitudinal CoPtCr/Cr magnetic thin films journal November 1993
On the relationship of high coercivity and L10 ordered phase in CoPt and FePt thin films journal October 1999
Diffraction anomalous fine structure: A new x-ray structural technique journal November 1992
Properties of high rate sputtered perpendicular recording media journal April 1985
Scattering-matrix formulation of curved-wave multiple-scattering theory: Application to x-ray-absorption fine structure journal April 1990
Magnetocrystalline anisotropy and phase transformation in Co-Pt alloy journal September 1984
Microstructural segregation in CoCrTa and CoCrPt longitudinal magnetic recording media journal April 1997