Geometric Phase Appears in the Ultracold Hydrogen Exchange Reaction

Kendrick, Brian Kent; Hazra, Jisha; Balakrishnan, Naduvalath

doi:10.1103/PhysRevLett.115.153201

Title: Geometric Phase Appears in the Ultracold Hydrogen Exchange Reaction

Journal Article · Thu Oct 08 00:00:00 EDT 2015 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.115.153201· OSTI ID:1457248

^[1]; Hazra, Jisha ^[2]; Balakrishnan, Naduvalath ^[2]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Nevada, Las Vegas, NV (United States)

In this work, quantum reactive scattering calculations for the hydrogen exchange reaction H + H₂(v = 4, j = 0) → H + H₂(v', j') and its isotopic analogues are reported for ultracold collision energies. Because of the unique properties associated with ultracold collisions, it is shown that the geometric phase effectively controls the reactivity. The rotationally resolved rate coefficients computed with and without the geometric phase are shown to differ by up to 4 orders of magnitude. The effect is also significant in the vibrationally resolved and total rate coefficients. Finally, the dynamical origin of the effect is discussed and the large geometric phase effect reported here might be exploited to control the reactivity through the application of external fields or by the selection of a particular nuclear spin state.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1457248

Alternate ID(s):: OSTI ID: 1223148

Report Number(s):: LA-UR-15-24804; PRLTAO; TRN: US1901331

Journal Information:: Physical Review Letters, Vol. 115, Issue 15; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 47 works

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Cited By (4)

Tunneling chemical exchange reaction D + HD → D ₂ + H in solid HD and D ₂ at temperatures below 1 K Sheludiakov, S.; Ahokas, J.; Järvinen, J. Physical Chemistry Chemical Physics, Vol. 18, Issue 42 https://doi.org/10.1039/c6cp05486b	journal	January 2016
Non-adiabatic quantum reactive scattering in hyperspherical coordinates Kendrick, Brian K. The Journal of Chemical Physics, Vol. 148, Issue 4 https://doi.org/10.1063/1.5014989	journal	January 2018
Controlling rotational quenching rates in cold molecular collisions Croft, J. F. E.; Balakrishnan, N. The Journal of Chemical Physics, Vol. 150, Issue 16 https://doi.org/10.1063/1.5091576	journal	April 2019
Observation of the geometric phase effect in the H + HD → H ₂ + D reaction Yuan, Daofu; Guan, Yafu; Chen, Wentao Science, Vol. 362, Issue 6420 https://doi.org/10.1126/science.aav1356	journal	December 2018

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