Measuring Level Alignment at the Metal–Molecule Interface by In Situ Electrochemical 13C NMR
Journal Article
·
· ChemPhysChem, 16(4):747-751
A new technique to measure energy-level alignment at a metal–molecule interface between the Fermi level of the metal and the frontier orbitals of the molecule is proposed and experimentally demonstrated. The method, which combines the electrochemistry of organo-ligand-stabilized Au nanoparticles with 13C NMR spectroscopy (i.e. in situ electrochemical NMR), enables measuring both occupied and unoccupied states.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1222074
- Journal Information:
- ChemPhysChem, 16(4):747-751, Journal Name: ChemPhysChem, 16(4):747-751
- Country of Publication:
- United States
- Language:
- English
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