CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

Wang, Wan -Hui; Himeda, Yuichiro; Muckerman, James T.; Manbeck, Gerald F.; Fujita, Etsuko

doi:10.1021/acs.chemrev.5b00197

Title: CO₂ hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO₂ reduction

Journal Article · Thu Sep 03 00:00:00 EDT 2015 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.5b00197· OSTI ID:1214520

Wang, Wan -Hui ^[1]; Himeda, Yuichiro ^[2]; Muckerman, James T. ^[3]; Manbeck, Gerald F. ^[3]; Fujita, Etsuko ^[3]

Dalian Univ., Panjin (China)
National Inst. of Advanced Industrial Science and Technology, Ibaraki (Japan); JST, ACT-C, Saitama (Japan)
Brookhaven National Lab. (BNL), Upton, NY (United States)

In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO₂ in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO₂ activation and utilization in several ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO₂ saturated solution using electricity produced by photovoltaics; (iii) CO₂ hydrogenation using solar-produced H₂; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO₂ at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1214520

Report Number(s):: BNL-108316-2015-JA; R&D Project: CO026; KC0304030

Journal Information:: Chemical Reviews, Journal Name: Chemical Reviews; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 1108 works

Citation information provided by
Web of Science

References (285)

Role of a Noninnocent Pincer Ligand in the Activation of CO ₂ at (PNN)Ru(H)(CO) Huff, Chelsea A.; Kampf, Jeff W.; Sanford, Melanie S. Organometallics, Vol. 31, Issue 13 https://doi.org/10.1021/om300403b	journal	June 2012
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities Arakawa, Hironori; Aresta, Michele; Armor, John N. Chemical Reviews, Vol. 101, Issue 4 https://doi.org/10.1021/cr000018s	journal	April 2001
Towards the development of a hydrogen battery Boddien, Albert; Federsel, Christopher; Sponholz, Peter Energy & Environmental Science, Vol. 5, Issue 10 https://doi.org/10.1039/c2ee22043a	journal	January 2012
Conversion of CO₂ into Formate by Homogeneously Catalyzed Hydrogenation in Water: Tuning Catalytic Activity and Water Solubility through the Acid–Base Equilibrium of the Ligand Himeda, Yuichiro European Journal of Inorganic Chemistry, Vol. 2007, Issue 25, p. 3927-3941 https://doi.org/10.1002/ejic.200700494	journal	September 2007
Well-Defined Iron Catalyst for Improved Hydrogenation of Carbon Dioxide and Bicarbonate Ziebart, Carolin; Federsel, Christopher; Anbarasan, Pazhamalai Journal of the American Chemical Society, Vol. 134, Issue 51 https://doi.org/10.1021/ja307924a	journal	December 2012
Electrochemical CO₂ Reduction on Metal Electrodes Hori, Y.; Vayenas, Constantinos G.; White, Ralph E. Modern Aspects of Electrochemistry, p. 89-189 https://doi.org/10.1007/978-0-387-49489-0_3	book	January 2008
Proton reduction to hydrogen in biological and chemical systems Tran, Phong D.; Barber, James Physical Chemistry Chemical Physics, Vol. 14, Issue 40 https://doi.org/10.1039/c2cp42413d	journal	January 2012
A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14 Han, Ali; Jin, Song; Chen, Huanlin Journal of Materials Chemistry A, Vol. 3, Issue 5 https://doi.org/10.1039/C4TA06071G	journal	January 2015
Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review) Ganesh, Ibram Renewable and Sustainable Energy Reviews, Vol. 31 https://doi.org/10.1016/j.rser.2013.11.045	journal	March 2014
Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications Faber, Matthew S.; Jin, Song Energy Environ. Sci., Vol. 7, Issue 11 https://doi.org/10.1039/C4EE01760A	journal	January 2014
Catalysis for the Valorization of Exhaust Carbon: from CO ₂ to Chemicals, Materials, and Fuels. Technological Use of CO ₂ Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella Chemical Reviews, Vol. 114, Issue 3 https://doi.org/10.1021/cr4002758	journal	November 2013
Theoretical mechanistic study of the formic acid decomposition assisted by a Ru(II)-phosphine catalyst Mazzone, Gloria; Alberto, Marta E.; Sicilia, Emilia Journal of Molecular Modeling, Vol. 20, Issue 5 https://doi.org/10.1007/s00894-014-2250-4	journal	May 2014
Splitting Water with Cobalt Artero, Vincent; Chavarot-Kerlidou, Murielle; Fontecave, Marc Angewandte Chemie International Edition, Vol. 50, Issue 32 https://doi.org/10.1002/anie.201007987	journal	July 2011
Reduction of CO2 by molecular hydrogen to formic acid and formaldehyde and their decomposition to CO and H2O Khan, M. M. Taqui; Halligudi, S. B.; Shukla, Sumita Journal of Molecular Catalysis, Vol. 57, Issue 1 https://doi.org/10.1016/0304-5102(89)80126-9	journal	January 1989
The Influence of the Second and Outer Coordination Spheres on Rh(diphosphine) ₂ CO ₂ Hydrogenation Catalysts Bays, J. Timothy; Priyadarshani, Nilusha; Jeletic, Matthew S. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5009199	journal	September 2014
New Strategies for CO2-to-Methanol Conversion Choudhury, Joyanta ChemCatChem, Vol. 4, Issue 5 https://doi.org/10.1002/cctc.201100495	journal	March 2012
Reversible hydrogen storage using CO₂ and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures Hull, Jonathan F.; Himeda, Yuichiro; Wang, Wan-Hui Nature Chemistry, Vol. 4, Issue 5, p. 383-388 https://doi.org/10.1038/nchem.1295	journal	March 2012
Efficient H ₂ generation from formic acid using azole complexes in water Manaka, Yuichi; Wang, Wan-Hui; Suna, Yuki Catal. Sci. Technol., Vol. 4, Issue 1 https://doi.org/10.1039/C3CY00830D	journal	January 2014
Worldwide innovations in the development of carbon capture technologies and the utilization of CO2 Markewitz, Peter; Kuckshinrichs, Wilhelm; Leitner, Walter Energy & Environmental Science, Vol. 5, Issue 6 https://doi.org/10.1039/c2ee03403d	journal	January 2012
Structure and Function of [Fe]-Hydrogenase and its Iron-Guanylylpyridinol (FeGP) Cofactor Shima, Seigo; Ermler, Ulrich European Journal of Inorganic Chemistry, Vol. 2011, Issue 7 https://doi.org/10.1002/ejic.201000955	journal	December 2010
Hydrogenation of Carbon Dioxide Catalyzed by PNP Pincer Iridium, Iron, and Cobalt Complexes: A Computational Design of Base Metal Catalysts Yang, Xinzheng ACS Catalysis, Vol. 1, Issue 8 https://doi.org/10.1021/cs2000329	journal	June 2011
The interconversion of formic acid and hydrogen/carbon dioxide using a binuclear ruthenium complex catalyst Gao, Yuan; Kuncheria, Joshi K.; Jenkins, Hilary A. Journal of the Chemical Society, Dalton Transactions, Issue 18 https://doi.org/10.1039/b004234j	journal	January 2000
Highly Efficient D2 Generation by Dehydrogenation of Formic Acid in D2O through H+/D+ Exchange on an Iridium Catalyst: Application to the Synthesis of Deuterated Compounds by Transfer Deuterogenation Wang, Wan-Hui; Hull, Jonathan F.; Muckerman, James T. Chemistry - A European Journal, Vol. 18, Issue 30 https://doi.org/10.1002/chem.201200576	journal	June 2012
Activation of water molecule. 1. Intermediates bearing on the water gas shift reaction catalyzed by platinum(0) complexes Yoshida, Toshikatsu; Ueda, Yasuhiko; Otsuka, Sei Journal of the American Chemical Society, Vol. 100, Issue 12 https://doi.org/10.1021/ja00480a054	journal	June 1978
Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R. Science, Vol. 334, Issue 6056, p. 643-644 https://doi.org/10.1126/science.1209786	journal	September 2011
Bioinspired Energy Conversion Systems for Hydrogen Production and Storage Fukuzumi, Shunichi European Journal of Inorganic Chemistry, Vol. 2008, Issue 9, p. 1351-1362 https://doi.org/10.1002/ejic.200701369	journal	March 2008
Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H ₂ and H/D Exchange with a Water-Soluble Rhodium Complex in Aqueous Solution Fukuzumi, Shunichi; Kobayashi, Takeshi; Suenobu, Tomoyoshi ChemSusChem, Vol. 1, Issue 10 https://doi.org/10.1002/cssc.200800147	journal	October 2008
Breakthroughs in Hydrogen Storage-Formic Acid as a Sustainable Storage Material for Hydrogen Joó, Ferenc ChemSusChem, Vol. 1, Issue 10 https://doi.org/10.1002/cssc.200800133	journal	October 2008
Enhanced Carbon Dioxide Hydrogenation Facilitated by Catalytic Quantities of Bicarbonate and Other Inorganic Salts Drake, Jessica L.; Manna, Cesar M.; Byers, Jeffery A. Organometallics, Vol. 32, Issue 23 https://doi.org/10.1021/om401057p	journal	November 2013
Chemical Equilibria in Formic Acid/Amine-CO ₂ Cycles under Isochoric Conditions using a Ruthenium(II) 1,2-Bis(diphenylphosphino)ethane Catalyst Sordakis, Katerina; Beller, Matthias; Laurenczy, Gábor ChemCatChem, Vol. 6, Issue 1 https://doi.org/10.1002/cctc.201300740	journal	November 2013
Direct observation of the reduction of carbon dioxide by rhenium bipyridine catalysts Sampson, Matthew D.; Froehlich, Jesse D.; Smieja, Jonathan M. Energy & Environmental Science, Vol. 6, Issue 12 https://doi.org/10.1039/c3ee42186d	journal	January 2013
Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO ₂ Darensbourg, Donald J. Chemical Reviews, Vol. 107, Issue 6 https://doi.org/10.1021/cr068363q	journal	June 2007
Artificial Z-Scheme Constructed with a Supramolecular Metal Complex and Semiconductor for the Photocatalytic Reduction of CO ₂ Sekizawa, Keita; Maeda, Kazuhiko; Domen, Kazunari Journal of the American Chemical Society, Vol. 135, Issue 12 https://doi.org/10.1021/ja311541a	journal	March 2013
Accelerating Effect of a Proton on the Reduction of CO ₂ Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex Hayashi, Hideki; Ogo, Seiji; Abura, Tsutomu Journal of the American Chemical Society, Vol. 125, Issue 47 https://doi.org/10.1021/ja036117f	journal	November 2003
Dehydrogenative Oxidation of Alcohols in Aqueous Media Using Water-Soluble and Reusable Cp*Ir Catalysts Bearing a Functional Bipyridine Ligand Kawahara, Ryoko; Fujita, Ken-ichi; Yamaguchi, Ryohei Journal of the American Chemical Society, Vol. 134, Issue 8 https://doi.org/10.1021/ja210857z	journal	February 2012
Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water Beley, Marc; Collin, Jean-Paul; Ruppert, Romain Journal of the Chemical Society, Chemical Communications, Issue 19 https://doi.org/10.1039/c39840001315	journal	January 1984
Hydrogenases Lubitz, Wolfgang; Ogata, Hideaki; Rüdiger, Olaf Chemical Reviews, Vol. 114, Issue 8 https://doi.org/10.1021/cr4005814	journal	March 2014
Direct formation of formic acid from carbon dioxide and dihydrogen using the [{Rh(cod)Cl} ₂ ]–Ph ₂ P(CH ₂ ) ₄ PPh ₂ catalyst system Graf, Elisabeth; Leitner, Walter J. Chem. Soc., Chem. Commun., Issue 8 https://doi.org/10.1039/c39920000623	journal	January 1992
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Learning from the Neighbors: Improving Homogeneous Catalysts with Functional Ligands Motivated by Heterogeneous and Biocatalysis Askevold, Bjorn; Roesky, Herbert W.; Schneider, Sven ChemCatChem, Vol. 4, Issue 3 https://doi.org/10.1002/cctc.201100347	journal	February 2012
Dual functionality of formamidine polymers, as ligands and as bases, in ruthenium-catalysed hydrogen evolution from formic acid Enthaler, Stephan; Junge, Henrik; Fischer, Anna Polymer Chemistry, Vol. 4, Issue 9 https://doi.org/10.1039/c3py00120b	journal	January 2013
Water-soluble (η6-arene)ruthenium(II)-phosphine complexes and their catalytic activity in the hydrogenation of bicarbonate in aqueous solution Horváth, Henrietta; Laurenczy, Gábor; Kathó, Ágnes Journal of Organometallic Chemistry, Vol. 689, Issue 6 https://doi.org/10.1016/j.jorganchem.2003.11.036	journal	March 2004
Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO ₂ Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes Wang, Wan-Hui; Muckerman, James T.; Fujita, Etsuko ACS Catalysis, Vol. 3, Issue 5 https://doi.org/10.1021/cs400172j	journal	April 2013
Cobalt phosphide nanorods as an efficient electrocatalyst for the hydrogen evolution reaction Huang, Zhipeng; Chen, Zhongzhong; Chen, Zhibo Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.08.013	journal	October 2014
Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies Takeda, Hiroyuki; Ishitani, Osamu Coordination Chemistry Reviews, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.ccr.2009.09.030	journal	February 2010
Electrocatalytic CO ₂ Reduction with a Homogeneous Catalyst in Ionic Liquid: High Catalytic Activity at Low Overpotential Grills, David C.; Matsubara, Yasuo; Kuwahara, Yutaka The Journal of Physical Chemistry Letters, Vol. 5, Issue 11 https://doi.org/10.1021/jz500759x	journal	May 2014
Utilisation of CO2 as a chemical feedstock: opportunities and challenges Aresta, Michele; Dibenedetto, Angela Dalton Transactions, Issue 28 https://doi.org/10.1039/b700658f	journal	January 2007
Exploring the Reactivity of Nickel Pincer Complexes in the Decomposition of Formic Acid to CO ₂ /H ₂ and the Hydrogenation of NaHCO ₃ to HCOONa Enthaler, Stephan; Brück, Andreas; Kammer, Anja ChemCatChem, Vol. 7, Issue 1 https://doi.org/10.1002/cctc.201402716	journal	October 2014
Efficient Disproportionation of Formic Acid to Methanol Using Molecular Ruthenium Catalysts Savourey, Solène; Lefèvre, Guillaume; Berthet, Jean-Claude Angewandte Chemie International Edition, Vol. 53, Issue 39 https://doi.org/10.1002/anie.201405457	journal	August 2014
Electrochemical Reduction of Carbon Dioxide to Formic Acid Lu, Xu; Leung, Dennis Y. C.; Wang, Huizhi ChemElectroChem, Vol. 1, Issue 5 https://doi.org/10.1002/celc.201300206	journal	May 2014
CO ₂ Hydrogenation Catalyzed by Iridium Complexes with a Proton-Responsive Ligand Onishi, Naoya; Xu, Shaoan; Manaka, Yuichi Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/ic502904q	journal	February 2015
Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts Chen, Wei-Fu; Muckerman, James T.; Fujita, Etsuko Chemical Communications, Vol. 49, Issue 79 https://doi.org/10.1039/c3cc44076a	journal	January 2013
Towards a methanol economy based on homogeneous catalysis: methanol to H ₂ and CO ₂ to methanol Alberico, E.; Nielsen, M. Chemical Communications, Vol. 51, Issue 31 https://doi.org/10.1039/C4CC09471A	journal	January 2015
Catalysis of Proton Reduction by a [BO ₄ ]-Bridged Dicobalt Glyoxime Laga, Stephanie M.; Blakemore, James D.; Henling, Lawrence M. Inorganic Chemistry, Vol. 53, Issue 24 https://doi.org/10.1021/ic501804h	journal	November 2014
Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes Morris, David J.; Clarkson, Guy J.; Wills, Martin Organometallics, Vol. 28, Issue 14 https://doi.org/10.1021/om900099u	journal	July 2009
Dehydrogenative Oxidation of Primary and Secondary Alcohols Catalyzed by a Cp*Ir Complex Having a Functional C,N-Chelate Ligand Fujita, Ken-ichi; Yoshida, Tetsuya; Imori, Yoichiro Organic Letters, Vol. 13, Issue 9 https://doi.org/10.1021/ol2005424	journal	May 2011
Water-Soluble IrIII N-Heterocyclic Carbene Based Catalysts for the Reduction of CO2 to Formate by Transfer Hydrogenation and the Deuteration of Aryl Amines in Water Azua, Arturo; Sanz, Sergio; Peris, Eduardo Chemistry - A European Journal, Vol. 17, Issue 14 https://doi.org/10.1002/chem.201002907	journal	March 2011
Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst Kang, Peng; Meyer, Thomas J.; Brookhart, Maurice Chemical Science, Vol. 4, Issue 9 https://doi.org/10.1039/c3sc51339d	journal	January 2013
Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex Tanaka, Ryo; Yamashita, Makoto; Chung, Lung Wa Organometallics, Vol. 30, Issue 24 https://doi.org/10.1021/om2010172	journal	December 2011
Transfer hydrogenation of a variety of ketones catalyzed by rhodium complexes in aqueous solution and their application to asymmetric reduction using chiral Schiff base ligands Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki Journal of Molecular Catalysis A: Chemical, Vol. 195, Issue 1-2 https://doi.org/10.1016/S1381-1169(02)00576-9	journal	March 2003
Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure Maenaka, Yuta; Suenobu, Tomoyoshi; Fukuzumi, Shunichi Energy & Environmental Science, Vol. 5, Issue 6 https://doi.org/10.1039/c2ee03315a	journal	January 2012
Electrocatalytic reduction of CO2 based on polypyridyl complexes of rhodium and ruthenium Bolinger, C. Mark; Sullivan, B. Patrick; Conrad, David Journal of the Chemical Society, Chemical Communications, Issue 12 https://doi.org/10.1039/c39850000796	journal	January 1985
Iron-Catalyzed Hydrogen Production from Formic Acid Boddien, Albert; Loges, Björn; Gärtner, Felix Journal of the American Chemical Society, Vol. 132, Issue 26 https://doi.org/10.1021/ja100925n	journal	July 2010
Molecular devices featuring sequential photoinduced charge separations for the storage of multiple redox equivalents Pellegrin, Yann; Odobel, Fabrice Coordination Chemistry Reviews, Vol. 255, Issue 21-22 https://doi.org/10.1016/j.ccr.2010.12.017	journal	November 2011
Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes Tamaki, Y.; Morimoto, T.; Koike, K. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1118336109	journal	August 2012
Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure Wang, Wan-Hui; Hull, Jonathan F.; Muckerman, James T. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21888g	journal	January 2012
Recent advances in the homogeneous hydrogenation of carbon dioxide Jessop, Philip G.; Joó, Ferenc; Tai, Chih-Cheng Coordination Chemistry Reviews, Vol. 248, Issue 21-24, p. 2425-2442 https://doi.org/10.1016/j.ccr.2004.05.019	journal	December 2004
Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst Tedsree, Karaked; Li, Tong; Jones, Simon Nature Nanotechnology, Vol. 6, Issue 5 https://doi.org/10.1038/nnano.2011.42	journal	April 2011
Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials Loges, Björn; Boddien, Albert; Gärtner, Felix Topics in Catalysis, Vol. 53, Issue 13-14 https://doi.org/10.1007/s11244-010-9522-8	journal	May 2010
Homogeneous Catalytic System for Reversible Dehydrogenation−Hydrogenation Reactions of Nitrogen Heterocycles with Reversible Interconversion of Catalytic Species Yamaguchi, Ryohei; Ikeda, Chikako; Takahashi, Yoshinori Journal of the American Chemical Society, Vol. 131, Issue 24 https://doi.org/10.1021/ja9022623	journal	June 2009
Electrocatalytic reduction of CO2 into formate with [(η5Me5C5)M(L)Cl]+ complexes (L = 2,2′-bipyridine ligands; M  Rh(III) and Ir(III)) Caix, Chrystelle; Chardon-Noblat, Sylvie; Deronzier, Alain Journal of Electroanalytical Chemistry, Vol. 434, Issue 1-2 https://doi.org/10.1016/S0022-0728(97)00058-2	journal	August 1997
Half-Sandwich Complexes with 4,7-Dihydroxy-1,10-phenanthroline: Water-Soluble, Highly Efficient Catalysts for Hydrogenation of Bicarbonate Attributable to the Generation of an Oxyanion on the Catalyst Ligand Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki Organometallics, Vol. 23, Issue 7 https://doi.org/10.1021/om030382s	journal	March 2004
Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22528j	journal	January 2012
A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst Fellay, Céline; Dyson, Paul J.; Laurenczy, Gábor Angewandte Chemie International Edition, Vol. 47, Issue 21, p. 3966-3968 https://doi.org/10.1002/anie.200800320	journal	May 2008
Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production Horvath, S.; Fernandez, L. E.; Soudackov, A. V. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1118333109	journal	April 2012
Comparison of [Ni(P ^Ph ₂ N ^Ph ₂ ) ₂ (CH ₃ CN)] ²⁺ and [Pd(P ^Ph ₂ N ^Ph ₂ ) ₂ ] ²⁺ as Electrocatalysts for H ₂ Production Wiedner, Eric S.; Helm, Monte L. Organometallics, Vol. 33, Issue 18 https://doi.org/10.1021/om4010669	journal	January 2014
Tungsten Carbide-Nitride on Graphene Nanoplatelets as a Durable Hydrogen Evolution Electrocatalyst Chen, Wei-Fu; Schneider, Jonathan M.; Sasaki, Kotaro ChemSusChem, Vol. 7, Issue 9 https://doi.org/10.1002/cssc.201402454	journal	July 2014
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media Moret, Séverine; Dyson, Paul J.; Laurenczy, Gábor Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5017	journal	June 2014
Continuous Hydrogen Generation from Formic Acid: Highly Active and Stable Ruthenium Catalysts Boddien, Albert; Loges, Björn; Junge, Henrik Advanced Synthesis & Catalysis, Vol. 351, Issue 14-15 https://doi.org/10.1002/adsc.200900431	journal	October 2009
Molybdenum carbide stabilized on graphene with high electrocatalytic activity for hydrogen evolution reaction Pan, Lin Feng; Li, Yu Hang; Yang, Shuang Chem. Commun., Vol. 50, Issue 86 https://doi.org/10.1039/C4CC05698A	journal	January 2014
Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H ₂ /O ₂ Fuel Cells Loges, BjÃ¶rn; Boddien, Albert; Junge, Henrik Angewandte Chemie International Edition, Vol. 47, Issue 21 https://doi.org/10.1002/anie.200705972	journal	May 2008
Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst Filonenko, Georgy A.; van Putten, Robbert; Schulpen, Erik N. ChemCatChem, Vol. 6, Issue 6 https://doi.org/10.1002/cctc.201402119	journal	April 2014
Artificial Photosynthesis over Crystalline TiO ₂ -Based Catalysts: Fact or Fiction? Yang, Chieh-Chao; Yu, Yi-Hui; van der Linden, Bart Journal of the American Chemical Society, Vol. 132, Issue 24 https://doi.org/10.1021/ja101318k	journal	June 2010
Cooperating Ligands in Catalysis Grützmacher, Hansjörg Angewandte Chemie International Edition, Vol. 47, Issue 10 https://doi.org/10.1002/anie.200704654	journal	February 2008
Experimental and Computational Studies of the Reaction of Carbon Dioxide with Pincer-Supported Nickel and Palladium Hydrides Suh, Hee-Won; Schmeier, Timothy J.; Hazari, Nilay Organometallics, Vol. 31, Issue 23 https://doi.org/10.1021/om3008597	journal	November 2012
Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water Fukuzumi, Shunichi; Kobayashi, Takeshi; Suenobu, Tomoyoshi Journal of the American Chemical Society, Vol. 132, Issue 5 https://doi.org/10.1021/ja910349w	journal	February 2010
Photochemical Reduction of CO ₂ Using TiO ₂ : Effects of Organic Adsorbates on TiO ₂ and Deposition of Pd onto TiO ₂ Yui, Tatsuto; Kan, Akira; Saitoh, Chieko ACS Applied Materials & Interfaces, Vol. 3, Issue 7 https://doi.org/10.1021/am200425y	journal	June 2011
Multifunctional ligands in transition metal catalysis Crabtree, Robert H. New J. Chem., Vol. 35, Issue 1 https://doi.org/10.1039/C0NJ00776E	journal	January 2011
Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation Milstein, David Topics in Catalysis, Vol. 53, Issue 13-14 https://doi.org/10.1007/s11244-010-9523-7	journal	May 2010
Crystallographic and FTIR Spectroscopic Evidence of Changes in Fe Coordination Upon Reduction of the Active Site of the Fe-Only Hydrogenase from Desulfovibrio d esulfuricans Nicolet, Yvain; de Lacey, Antonio L.; Vernède, Xavier Journal of the American Chemical Society, Vol. 123, Issue 8, p. 1596-1601 https://doi.org/10.1021/ja0020963	journal	February 2001
Hydrogenation of aqueous mixtures of calcium carbonate and carbon dioxide using a water-soluble rhodium(I)–tertiary phosphine complex catalyst Jószai, István; Joó, Ferenc Journal of Molecular Catalysis A: Chemical, Vol. 224, Issue 1-2 https://doi.org/10.1016/j.molcata.2004.08.045	journal	December 2004
The reduction of carbon dioxide in iron biocatalyst catalytic hydrogenation reaction: a theoretical study Yang, Longhua; Wang, Hongming; Zhang, Ning Dalton Transactions, Vol. 42, Issue 31 https://doi.org/10.1039/c3dt50337b	journal	January 2013
(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation Erlandsson, Mikael; Landaeta, Vanessa R.; Gonsalvi, Luca European Journal of Inorganic Chemistry, Vol. 2008, Issue 4 https://doi.org/10.1002/ejic.200700792	journal	February 2008
Review: Photochemical and Thermochemical Production of Solar Fuels from H ₂ O and CO ₂ Using Metal Oxide Catalysts Smestad, Greg P.; Steinfeld, Aldo Industrial & Engineering Chemistry Research, Vol. 51, Issue 37 https://doi.org/10.1021/ie3007962	journal	June 2012
Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight Wang, Wan-Hui; Xu, Shaoan; Manaka, Yuichi ChemSusChem, Vol. 7, Issue 7 https://doi.org/10.1002/cssc.201301414	journal	May 2014
A Computational Investigation of the Insertion of Carbon Dioxide into Four- and Five-Coordinate Iridium Hydrides Bernskoetter, Wesley H.; Hazari, Nilay European Journal of Inorganic Chemistry, Vol. 2013, Issue 22-23 https://doi.org/10.1002/ejic.201300170	journal	May 2013
New Water-Soluble Iridium(I)–N-Heterocyclic Carbene–Tertiary Phosphine Mixed-Ligand Complexes as Catalysts of Hydrogenation and Redox Isomerization Horváth, Henrietta; Kathó, Ágnes; Udvardy, Antal Organometallics, Vol. 33, Issue 22 https://doi.org/10.1021/om5006148	journal	November 2014
p K _a Measurements of P(RNCH ₂ CH ₃ ) ₃ N Kisanga, Philip B.; Verkade, John G.; Schwesinger, Reinhard The Journal of Organic Chemistry, Vol. 65, Issue 17 https://doi.org/10.1021/jo000427o	journal	August 2000
The decomposition of formic acid catalysed by soluble metal complexes Coffey, R. S. Chemical Communications (London), Issue 18 https://doi.org/10.1039/c1967000923b	journal	January 1967
Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2 Leitner, Walter Angewandte Chemie International Edition in English, Vol. 34, Issue 20 https://doi.org/10.1002/anie.199522071	journal	November 1995
Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine–diamine complexes Zhang, Peili; Wang, Mei; Gloaguen, Frederic Chemical Communications, Vol. 49, Issue 82 https://doi.org/10.1039/c3cc43491e	journal	January 2013
Highly efficient hydrogen evolution by decomposition of formic acid using an iridium catalyst with 4,4′-dihydroxy-2,2′-bipyridine Himeda, Yuichiro Green Chemistry, Vol. 11, Issue 12 https://doi.org/10.1039/b914442k	journal	January 2009
Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide Nielsen, Martin; Alberico, Elisabetta; Baumann, Wolfgang Nature, Vol. 495, Issue 7439 https://doi.org/10.1038/nature11891	journal	February 2013
Cobalt complexes as artificial hydrogenases for the reductive side of water splitting Eckenhoff, William T.; McNamara, William R.; Du, Pingwu Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9 https://doi.org/10.1016/j.bbabio.2013.05.003	journal	August 2013
Small molecule mimics of hydrogenases: hydrides and redox Gloaguen, Frédéric; Rauchfuss, Thomas B. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B801796B	journal	January 2009
A New Approach to the Reduction of Carbon Dioxide: CO ₂ Reduction to Formate by Transfer Hydrogenation in i PrOH Sanz, Sergio; Benítez, Miriam; Peris, Eduardo Organometallics, Vol. 29, Issue 1 https://doi.org/10.1021/om900820x	journal	October 2009
Towards Oil Independence Through Renewable Methanol Chemistry Olah, George A. Angewandte Chemie International Edition, Vol. 52, Issue 1 https://doi.org/10.1002/anie.201204995	journal	December 2012
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001679	journal	December 2009
Formic Acid As a Hydrogen Storage Medium: Ruthenium-Catalyzed Generation of Hydrogen from Formic Acid in Emulsions Czaun, Miklos; Goeppert, Alain; Kothandaraman, Jotheeswari ACS Catalysis, Vol. 4, Issue 1 https://doi.org/10.1021/cs4007974	journal	December 2013
Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst Conley, Brian L.; Pennington-Boggio, Megan K.; Boz, Emine Chemical Reviews, Vol. 110, Issue 4 https://doi.org/10.1021/cr9003133	journal	April 2010
A survey of Hammett substituent constants and resonance and field parameters Hansch, Corwin.; Leo, A.; Taft, R. W. Chemical Reviews, Vol. 91, Issue 2 https://doi.org/10.1021/cr00002a004	journal	March 1991
Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review Barelli, L.; Bidini, G.; Gallorini, F. Energy, Vol. 33, Issue 4 https://doi.org/10.1016/j.energy.2007.10.018	journal	April 2008
Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid Barnard, Jonathan H.; Wang, Chao; Berry, Neil G. Chemical Science, Vol. 4, Issue 3 https://doi.org/10.1039/c2sc21923a	journal	January 2013
Simultaneous Tuning of Activity and Water Solubility of Complex Catalysts by Acid−Base Equilibrium of Ligands for Conversion of Carbon Dioxide Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki Organometallics, Vol. 26, Issue 3 https://doi.org/10.1021/om060899e	journal	January 2007
Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts Wang, Mei; Chen, Lin; Sun, Licheng Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03309g	journal	January 2012
Ruthenium(II)-Catalyzed Hydrogenation of Carbon Dioxide to Formic Acid. Theoretical Study of Real Catalyst, Ligand Effects, and Solvation Effects Ohnishi, Yu-ya; Matsunaga, Tadashi; Nakao, Yoshihide Journal of the American Chemical Society, Vol. 127, Issue 11 https://doi.org/10.1021/ja043697n	journal	March 2005
Base-Free Production of H ₂ by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex Oldenhof, Sander; de Bruin, Bas; Lutz, Martin Chemistry - A European Journal, Vol. 19, Issue 35 https://doi.org/10.1002/chem.201302230	journal	July 2013
Redox-Active Ligands in Catalysis Praneeth, Vijayendran K. K.; Ringenberg, Mark R.; Ward, Thomas R. Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204100	journal	September 2012
Efficient Hydrogen Liberation from Formic Acid Catalyzed by a Well-Defined Iron Pincer Complex under Mild Conditions Zell, Thomas; Butschke, Burkhard; Ben-David, Yehoshoa Chemistry - A European Journal, Vol. 19, Issue 25 https://doi.org/10.1002/chem.201301383	journal	May 2013
Formic acid dehydrogenation catalysed by ruthenium complexes bearing the tripodal ligands triphos and NP ₃ Mellone, Irene; Peruzzini, Maurizio; Rosi, Luca Dalton Trans., Vol. 42, Issue 7 https://doi.org/10.1039/C2DT32043F	journal	January 2013
Direct XANES Evidence for Charge Transfer in Co−CO ₂ Complexes Fujita, Etsuko; Furenlid, Lars R.; Renner, Mark W. Journal of the American Chemical Society, Vol. 119, Issue 19 https://doi.org/10.1021/ja970151a	journal	May 1997
A Rechargeable Hydrogen Battery Based on Ru Catalysis Hsu, Shih-Fan; Rommel, Susanne; Eversfield, Philipp Angewandte Chemie International Edition, Vol. 53, Issue 27 https://doi.org/10.1002/anie.201310972	journal	May 2014
Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions Alberico, Elisabetta; Sponholz, Peter; Cordes, Christoph Angewandte Chemie International Edition, Vol. 52, Issue 52 https://doi.org/10.1002/anie.201307224	journal	December 2013
Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes Suna, Yuki; Ertem, Mehmed Z.; Wang, Wan-Hui Organometallics, Vol. 33, Issue 22 https://doi.org/10.1021/om500832d	journal	November 2014
In situ NMR characterisation of an intermediate in the catalytic hydrogenation of CO2 and HCO3- in aqueous solution Laurenczy, Gábor; Jedner, Stephanie; Alessio, Enzo Inorganic Chemistry Communications, Vol. 10, Issue 5 https://doi.org/10.1016/j.inoche.2007.01.020	journal	May 2007
Biomass-derived electrocatalytic composites for hydrogen evolution Chen, Wei-Fu; Iyer, Shilpa; Iyer, Shweta Energy & Environmental Science, Vol. 6, Issue 6 https://doi.org/10.1039/c3ee40596f	journal	January 2013
Anthropogenic Chemical Carbon Cycle for a Sustainable Future Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain Journal of the American Chemical Society, Vol. 133, Issue 33 https://doi.org/10.1021/ja202642y	journal	August 2011
Earth-abundant hydrogen evolution electrocatalysts McKone, James R.; Marinescu, Smaranda C.; Brunschwig, Bruce S. Chem. Sci., Vol. 5, Issue 3 https://doi.org/10.1039/C3SC51711J	journal	January 2014
Use of carbon dioxide in energy storage Williams, Richard; Crandall, Richard S.; Bloom, Allen Applied Physics Letters, Vol. 33, Issue 5 https://doi.org/10.1063/1.90403	journal	September 1978
Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO Balaraman, Ekambaram; Gunanathan, Chidambaram; Zhang, Jing Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1089	journal	July 2011
A review of iron and cobalt porphyrins, phthalocyanines and related complexes for electrochemical and photochemical reduction of carbon dioxide Manbeck, Gerald F.; Fujita, Etsuko Journal of Porphyrins and Phthalocyanines, Vol. 19, Issue 01-03 https://doi.org/10.1142/S1088424615300013	journal	January 2015
Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-Biaryl Sulfonated Phosphines in Aqueous Solution Guerriero, Antonella; Bricout, Hervé; Sordakis, Katerina ACS Catalysis, Vol. 4, Issue 9 https://doi.org/10.1021/cs500655x	journal	August 2014
Asymmetric Transfer Hydrogenation of Ketones with Bifunctional Transition Metal-Based Molecular Catalysts ^† Ikariya, Takao; Blacker, A. John Accounts of Chemical Research, Vol. 40, Issue 12 https://doi.org/10.1021/ar700134q	journal	December 2007
Insights into metalloenzyme microenvironments: biomimetic metal complexes with a functional second coordination sphere Zhao, Meng; Wang, Hai-Bo; Ji, Liang-Nian Chemical Society Reviews, Vol. 42, Issue 21 https://doi.org/10.1039/c3cs60162e	journal	January 2013
A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides Federsel, Christopher; Boddien, Albert; Jackstell, Ralf Angewandte Chemie International Edition, Vol. 49, Issue 50 https://doi.org/10.1002/anie.201004263	journal	November 2010
Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process Beley, Marc.; Collin, Jean Paul.; Ruppert, Romain. Journal of the American Chemical Society, Vol. 108, Issue 24 https://doi.org/10.1021/ja00284a003	journal	November 1986
CO2-“Neutral” Hydrogen Storage Based on Bicarbonates and Formates Boddien, Albert; Gärtner, Felix; Federsel, Christopher Angewandte Chemie International Edition, Vol. 50, Issue 28 https://doi.org/10.1002/anie.201101995	journal	May 2011
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes Tanaka, Ryo; Yamashita, Makoto; Nozaki, Kyoko Journal of the American Chemical Society, Vol. 131, Issue 40 https://doi.org/10.1021/ja903574e	journal	October 2009
Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes Noyori, Ryoji; Hashiguchi, Shohei Accounts of Chemical Research, Vol. 30, Issue 2 https://doi.org/10.1021/ar9502341	journal	February 1997
Photoelectrochemical reduction of CO2 in water under visible-light irradiation by a p-type InP photocathode modified with an electropolymerized ruthenium complex Arai, Takeo; Sato, Shunsuke; Uemura, Keiko Chemical Communications, Vol. 46, Issue 37 https://doi.org/10.1039/c0cc02061c	journal	January 2010
Homogeneous hydrogenation of carbon dioxide and bicarbonate in aqueous solution catalyzed by water-soluble ruthenium(II) phosphine complexes Elek, János; Nádasdi, Levente; Papp, Gábor Applied Catalysis A: General, Vol. 255, Issue 1 https://doi.org/10.1016/S0926-860X(03)00644-6	journal	November 2003
Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect Hou, Cheng; Jiang, Jingxing; Zhang, Shidong ACS Catalysis, Vol. 4, Issue 9 https://doi.org/10.1021/cs500688q	journal	August 2014
Formic Acid Dehydrogenation Catalysed by Tris(TPPTS) Ruthenium Species: Mechanism of the Initial “Fast” Cycle Thevenon, Arnaud; Frost-Pennington, Ewan; Weijia, Gan ChemCatChem, Vol. 6, Issue 11 https://doi.org/10.1002/cctc.201402410	journal	September 2014
A New Mode of Activation of CO2 by Metal-Ligand Cooperation with Reversible CC and MO Bond Formation at Ambient Temperature Vogt, Matthias; Gargir, Moti; Iron, Mark A. Chemistry - A European Journal, Vol. 18, Issue 30 https://doi.org/10.1002/chem.201201730	journal	June 2012
Activation of carbon dioxide Leitner, Walter; Dinjus, Eckhard; Gaßner, Franz Journal of Organometallic Chemistry, Vol. 475, Issue 1-2 https://doi.org/10.1016/0022-328X(94)84030-X	journal	July 1994
Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO ₂ to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities Costentin, Cyrille; Passard, Guillaume; Robert, Marc Journal of the American Chemical Society, Vol. 136, Issue 33 https://doi.org/10.1021/ja506193v	journal	August 2014
In situ hydrogenation of captured CO2 to formate with polyethyleneimine and Rh/monophosphine system Li, Yu-Nong; He, Liang-Nian; Liu, An-Hua Green Chemistry, Vol. 15, Issue 10 https://doi.org/10.1039/c3gc41265b	journal	January 2013
Development of Molecular Electrocatalysts for CO₂ Reduction and H₂ Production/Oxidation Rakowski Dubois, M.; Dubois, Daniel L. Accounts of Chemical Research, Vol. 42, Issue 12, p. 1974-1982 https://doi.org/10.1021/ar900110c	journal	December 2009
Reduction potentials of CO2- and the alcohol radicals Schwarz, H. A.; Dodson, R. W. The Journal of Physical Chemistry, Vol. 93, Issue 1 https://doi.org/10.1021/j100338a079	journal	January 1989
Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: The Accelerating Effect of Certain Alcohols and Amines Munshi, Pradip; Main, A. Denise; Linehan, John C. Journal of the American Chemical Society, Vol. 124, Issue 27 https://doi.org/10.1021/ja0167856	journal	July 2002
Substantial improvement in the efficiency and durability of a photocatalyst for carbon dioxide reduction using a benzoimidazole derivative as an electron donor Tamaki, Yusuke; Koike, Kazuhide; Morimoto, Tatsuki Journal of Catalysis, Vol. 304 https://doi.org/10.1016/j.jcat.2013.04.002	journal	August 2013
Amine-Free Reversible Hydrogen Storage in Formate Salts Catalyzed by Ruthenium Pincer Complex without pH Control or Solvent Change Kothandaraman, Jotheeswari; Czaun, Miklos; Goeppert, Alain ChemSusChem, Vol. 8, Issue 8 https://doi.org/10.1002/cssc.201403458	journal	March 2015
Transfer hydrogenation in aqueous media Wei, Yawen; Wu, Xiaofeng; Wang, Chao Catalysis Today, Vol. 247 https://doi.org/10.1016/j.cattod.2014.03.066	journal	June 2015
One Site Is Enough: A Theoretical Investigation of Iron-Catalyzed Dehydrogenation of Formic Acid Sánchez-de-Armas, Rocío; Xue, Liqin; Ahlquist, Mårten S. G. Chemistry - A European Journal, Vol. 19, Issue 36 https://doi.org/10.1002/chem.201301970	journal	July 2013
Mechanistic insights into hydride transfer for catalytic hydrogenation of CO ₂ with cobalt complexes Kumar, N.; Camaioni, D. M.; Dupuis, M. Dalton Trans., Vol. 43, Issue 31 https://doi.org/10.1039/C4DT01551G	journal	January 2014
Evaluation of the Formate Dehydrogenase Activity of Three-Legged Pianostool Complexes in Dilute Aqueous Solution: Formate Dehydrogenase Activity of Three-Legged Pianostool Complexes Keller, Sascha G.; Ringenberg, Mark R.; Häussinger, Daniel European Journal of Inorganic Chemistry, Vol. 2014, Issue 34 https://doi.org/10.1002/ejic.201402348	journal	November 2014
Ruthenium(II)-Catalyzed Hydrogen Generation from Formic Acid using Cationic, Ammoniomethyl-Substituted Triarylphosphine Ligands Gan, Weijia; Snelders, Dennis J. M.; Dyson, Paul J. ChemCatChem, Vol. 5, Issue 5 https://doi.org/10.1002/cctc.201200782	journal	March 2013
A Cobalt-Based Catalyst for the Hydrogenation of CO ₂ under Ambient Conditions Jeletic, Matthew S.; Mock, Michael T.; Appel, Aaron M. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja406601v	journal	July 2013
Mechanism of CO ₂ hydrogenation to formates by homogeneous Ru-PNP pincer catalyst: from a theoretical description to performance optimization Filonenko, Georgy A.; Hensen, Emiel J. M.; Pidko, Evgeny A. Catal. Sci. Technol., Vol. 4, Issue 10 https://doi.org/10.1039/C4CY00568F	journal	January 2014
Toward more efficient photochemical CO2 reduction: Use of scCO2 or photogenerated hydrides Doherty, Mark D.; Grills, David C.; Muckerman, James T. Coordination Chemistry Reviews, Vol. 254, Issue 21-22 https://doi.org/10.1016/j.ccr.2009.12.013	journal	November 2010
Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst Boddien, A.; Mellmann, D.; Gartner, F. Science, Vol. 333, Issue 6050 https://doi.org/10.1126/science.1206613	journal	September 2011
Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform Bigi, Julian P.; Hanna, Tamara E.; Harman, W. Hill Chem. Commun., Vol. 46, Issue 6 https://doi.org/10.1039/B915846D	journal	January 2010
Hydrogenation of carbon dioxide to formic acid using a 6,6′-dichloro-2,2′-bipyridine complex of ruthenium,cis-[Ru(6,6′-Cl2bpy)2(H2O)2](CF3SO3)2 Lau, Chak Po; Chen, Yu Zhong Journal of Molecular Catalysis A: Chemical, Vol. 101, Issue 1 https://doi.org/10.1016/1381-1169(95)00068-2	journal	July 1995
Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles McCrory, Charles C. L.; Uyeda, Christopher; Peters, Jonas C. Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja210661k	journal	February 2012
Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions Thoi, V. Sara; Sun, Yujie; Long, Jeffrey R. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35272A	journal	January 2013
Homogeneous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides Jessop, Philip G.; Hsiao, Yi; Ikariya, Takao Journal of the American Chemical Society, Vol. 118, Issue 2 https://doi.org/10.1021/ja953097b	journal	January 1996
Ligand-Promoted Dehydrogenation of Alcohols Catalyzed by Cp*Ir Complexes. A New Catalytic System for Oxidant-Free Oxidation of Alcohols Fujita, Ken-ichi; Tanino, Nobuhide; Yamaguchi, Ryohei Organic Letters, Vol. 9, Issue 1 https://doi.org/10.1021/ol062806v	journal	January 2007
Hydrogenation of carbon dioxide to formic acid using water-soluble rhodium catalyststs Gassner, Franz; Leitner, Walter Journal of the Chemical Society, Chemical Communications, Issue 19 https://doi.org/10.1039/c39930001465	journal	January 1993
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s^-1 for H₂ Production Helm, M. L.; Stewart, M. P.; Bullock, R. M. Science, Vol. 333, Issue 6044, p. 863-866 https://doi.org/10.1126/science.1205864	journal	August 2011
Homogeneous Hydrogenation of Carbon Dioxide Jessop, Philip G.; Ikariya, Takao.; Noyori, Ryoji. Chemical Reviews, Vol. 95, Issue 2 https://doi.org/10.1021/cr00034a001	journal	March 1995
State-of-the-Art Catalysts for Hydrogenation of Carbon Dioxide Federsel, Christopher; Jackstell, Ralf; Beller, Matthias Angewandte Chemie International Edition, Vol. 49, Issue 36 https://doi.org/10.1002/anie.201000533	journal	July 2010
Selective Formic Acid Decomposition for High-Pressure Hydrogen Generation: A Mechanistic Study Fellay, Céline; Yan, Ning; Dyson, Paul J. Chemistry - A European Journal, Vol. 15, Issue 15 https://doi.org/10.1002/chem.200801824	journal	February 2009
Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity Langer, Robert; Diskin-Posner, Yael; Leitus, Gregory Angewandte Chemie International Edition, Vol. 50, Issue 42 https://doi.org/10.1002/anie.201104542	journal	September 2011
Inner- versus Outer-Sphere Ru-Catalyzed Formic Acid Dehydrogenation: A Computational Study Manca, Gabriele; Mellone, Irene; Bertini, Federica Organometallics, Vol. 32, Issue 23 https://doi.org/10.1021/om400761t	journal	November 2013
Synergy between molybdenum nitride and gold leading to platinum-like activity for hydrogen evolution Morozan, Adina; Goellner, Vincent; Zitolo, Andrea Physical Chemistry Chemical Physics, Vol. 17, Issue 6 https://doi.org/10.1039/C4CP04358H	journal	January 2015
Recent advances in direct formic acid fuel cells (DFAFC) Yu, Xingwen; Pickup, Peter G. Journal of Power Sources, Vol. 182, Issue 1, p. 124-132 https://doi.org/10.1016/j.jpowsour.2008.03.075	journal	July 2008
Highly active ruthenium complexes with bidentate phosphine ligands for the solvent-free catalytic synthesis of N,N-dimethylformamide and methyl formate Kröcher, Oliver; Köppel, René A.; Baiker, Alfons Chemical Communications, Issue 5 https://doi.org/10.1039/a608150i	journal	January 1997
‘(η6-arene)Ru(bis-NHC)’ complexes for the reduction of CO2 to formate with hydrogen and by transfer hydrogenation with iPrOH Sanz, Sergio; Azua, Arturo; Peris, Eduardo Dalton Transactions, Vol. 39, Issue 27 https://doi.org/10.1039/c003220d	journal	January 2010
Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis Gunanathan, Chidambaram; Milstein, David Accounts of Chemical Research, Vol. 44, Issue 8 https://doi.org/10.1021/ar2000265	journal	August 2011
Selective Conversion of CO ₂ to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst DiMeglio, John L.; Rosenthal, Joel Journal of the American Chemical Society, Vol. 135, Issue 24 https://doi.org/10.1021/ja4033549	journal	June 2013
Catalytic hydrogen production at cobalt centres Losse, Sebastian; Vos, Johannes G.; Rau, Sven Coordination Chemistry Reviews, Vol. 254, Issue 21-22 https://doi.org/10.1016/j.ccr.2010.06.004	journal	November 2010
Hydrogen Generation from Formic Acid Decomposition by Ruthenium Carbonyl Complexes. Tetraruthenium Dodecacarbonyl Tetrahydride as an Active Intermediate Czaun, Miklos; Goeppert, Alain; May, Robert ChemSusChem, Vol. 4, Issue 9 https://doi.org/10.1002/cssc.201000446	journal	March 2011
Chemical Technologies for Exploiting and Recycling Carbon Dioxide into the Value Chain Peters, Martina; Köhler, Burkhard; Kuckshinrichs, Wilhelm ChemSusChem, Vol. 4, Issue 9 https://doi.org/10.1002/cssc.201000447	journal	August 2011
Interconversion between Formic Acid and H2/CO2 using Rhodium and Ruthenium Catalysts for CO2 Fixation and H2 Storage Himeda, Yuichiro; Miyazawa, Satoru; Hirose, Takuji ChemSusChem, Vol. 4, Issue 4 https://doi.org/10.1002/cssc.201000327	journal	January 2011
Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium–Triphos catalyst: from mechanistic investigations to multiphase catalysis Wesselbaum, Sebastian; Moha, Verena; Meuresch, Markus Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC02087A	journal	January 2015
Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines Wiedner, Eric S.; Appel, Aaron M.; DuBois, Daniel L. Inorganic Chemistry, Vol. 52, Issue 24 https://doi.org/10.1021/ic4025475	journal	November 2013
Structure-Reactivity Relationships in the Hydrogenation of Carbon Dioxide with Ruthenium Complexes Bearing Pyridinylazolato Ligands Muller, Keven; Sun, Yu; Heimermann, Andreas Chemistry - A European Journal, Vol. 19, Issue 24 https://doi.org/10.1002/chem.201204199	journal	April 2013
A Charge/Discharge Device for Chemical Hydrogen Storage and Generation Papp, Gábor; Csorba, Jenő; Laurenczy, Gábor Angewandte Chemie International Edition, Vol. 50, Issue 44 https://doi.org/10.1002/anie.201104951	journal	September 2011
Base‐Free Non‐Noble‐Metal‐Catalyzed Hydrogen Generation from Formic Acid: Scope and Mechanistic Insights Mellmann, Dörthe; Barsch, Enrico; Bauer, Matthias Chemistry – A European Journal, Vol. 20, Issue 42 https://doi.org/10.1002/chem.201403602	journal	September 2014
The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer Filonenko, Georgy A.; Conley, Matthew P.; Copéret, Christophe ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs4006869	journal	October 2013
The Cofactor of the Iron–Sulfur Cluster Free Hydrogenase Hmd: Structure of the Light-Inactivation Product Shima, Seigo; Lyon, Erica J.; Sordel-Klippert, Melanie Angewandte Chemie International Edition, Vol. 43, Issue 19 https://doi.org/10.1002/anie.200353763	journal	May 2004
Catalytic Hydrogenation of Carbon Dioxide and Bicarbonates with a Well-Defined Cobalt Dihydrogen Complex Federsel, Christopher; Ziebart, Carolin; Jackstell, Ralf Chemistry - A European Journal, Vol. 18, Issue 1 https://doi.org/10.1002/chem.201101343	journal	December 2011
Recent advances in the photocatalytic conversion of carbon dioxide to fuels with water and/or hydrogen using solar energy and beyond Izumi, Yasuo Coordination Chemistry Reviews, Vol. 257, Issue 1 https://doi.org/10.1016/j.ccr.2012.04.018	journal	January 2013
Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges Du, Pingwu; Eisenberg, Richard Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee03250c	journal	January 2012
Recent advances in catalytic hydrogenation of carbon dioxide Wang, Wei; Wang, Shengping; Ma, Xinbin Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c1cs15008a	journal	January 2011
Reversible CO ₂ binding triggered by metal–ligand cooperation in a rhenium( i ) PNP pincer-type complex and the reaction with dihydrogen Vogt, Matthias; Nerush, Alexander; Diskin-Posner, Yael Chem. Sci., Vol. 5, Issue 5 https://doi.org/10.1039/c4sc00130c	journal	January 2014
Chemistry’s Role in Regenerative Energy Schlögl, Robert Angewandte Chemie International Edition, Vol. 50, Issue 29 https://doi.org/10.1002/anie.201103415	journal	June 2011
A mechanistic study of proton reduction catalyzed by a pentapyridine cobalt complex: evidence for involvement of an anation-based pathway King, Amanda E.; Surendranath, Yogesh; Piro, Nicholas A. Chemical Science, Vol. 4, Issue 4 https://doi.org/10.1039/c3sc22239j	journal	January 2013
RETRACTED: Photocatalytic CO2 transformation into fuel: A review on advances in photocatalyst and photoreactor Das, Sreejon; Wan Daud, W. M. A. Renewable and Sustainable Energy Reviews, Vol. 39 https://doi.org/10.1016/j.rser.2014.07.046	journal	November 2014
Water-soluble analogs of [RuCl3(NO)(PPh3)2] and their catalytic activity in the hydrogenation of carbon dioxide and bicarbonate in aqueous solution Kathó, A. Journal of Molecular Catalysis A: Chemical, Vol. 204-205 https://doi.org/10.1016/S1381-1169(03)00293-0	journal	September 2003
The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site Shima, S.; Pilak, O.; Vogt, S. Science, Vol. 321, Issue 5888 https://doi.org/10.1126/science.1158978	journal	July 2008
Selective Electrocatalytic Reduction of CO ₂ to Formate by Water-Stable Iridium Dihydride Pincer Complexes Kang, Peng; Cheng, Chen; Chen, Zuofeng Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja300543s	journal	March 2012
Prospects for conversion of solar energy into chemical fuels: the concept of a solar fuels industry Harriman, Anthony Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 371, Issue 1996 https://doi.org/10.1098/rsta.2011.0415	journal	August 2013
The Active Site of Methanol Synthesis over Cu/ZnO/Al₂O₃ Industrial Catalysts Behrens, M.; Studt, F.; Kasatkin, I. Science, Vol. 336, Issue 6083, p. 893-897 https://doi.org/10.1126/science.1219831	journal	April 2012
Selective CO ₂ Conversion to Formate Conjugated with H ₂ O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts Sato, Shunsuke; Arai, Takeo; Morikawa, Takeshi Journal of the American Chemical Society, Vol. 133, Issue 39 https://doi.org/10.1021/ja204881d	journal	October 2011
Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H ₂ and CO ₂ Myers, T. W.; Berben, L. A. Chem. Sci., Vol. 5, Issue 7 https://doi.org/10.1039/c4sc01035c	journal	January 2014
Mechanistic investigation of CO2 hydrogenation by Ru(ii) and Ir(iii) aqua complexes under acidic conditions: two catalytic systems differing in the nature of the rate determining step Ogo, Seiji; Kabe, Ryota; Hayashi, Hideki Dalton Transactions, Issue 39 https://doi.org/10.1039/b607993h	journal	January 2006
Catalytic Hydrogenation of Cyclic Carbonates: A Practical Approach from CO ₂ and Epoxides to Methanol and Diols Han, Zhaobin; Rong, Liangce; Wu, Jiang Angewandte Chemie International Edition, Vol. 51, Issue 52 https://doi.org/10.1002/anie.201207781	journal	November 2012
Effect of surface reconstruction of TiO2(001) single crystal on the photoreaction of acetic acid Wilson, J. Journal of Catalysis, Vol. 214, Issue 1 https://doi.org/10.1016/S0021-9517(02)00172-0	journal	February 2003
Continuous-Flow Hydrogenation of Carbon Dioxide to Pure Formic Acid using an Integrated scCO ₂ Process with Immobilized Catalyst and Base Wesselbaum, Sebastian; Hintermair, Ulrich; Leitner, Walter Angewandte Chemie International Edition, Vol. 51, Issue 34 https://doi.org/10.1002/anie.201203185	journal	July 2012
Photochemical reduction of carbon dioxide to formate catalyzed by 2,2t́-bipyridine- or 1,10-phenanthroline-ruthenium(II) complexes Lehn, Jean-Marie; Ziessel, Raymond Journal of Organometallic Chemistry, Vol. 382, Issue 1-2 https://doi.org/10.1016/0022-328X(90)85224-M	journal	February 1990
Catalytic CO ₂ Hydrogenation to Formate by a Ruthenium Pincer Complex Huff, Chelsea A.; Sanford, Melanie S. ACS Catalysis, Vol. 3, Issue 10 https://doi.org/10.1021/cs400609u	journal	September 2013
Monoiron Hydrogenase Catalysis: Hydrogen Activation with the Formation of a Dihydrogen, Fe−H ^δ− ···H ^δ+ −O, Bond and Methenyl-H ₄ MPT ⁺ Triggered Hydride Transfer Yang, Xinzheng; Hall, Michael B. Journal of the American Chemical Society, Vol. 131, Issue 31 https://doi.org/10.1021/ja902689n	journal	July 2009
Formic acid as a hydrogen source – recent developments and future trends Grasemann, Martin; Laurenczy, Gábor Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee21928j	journal	January 2012
Efficient Homogeneous Catalytic Hydrogenation of Esters to Alcohols Zhang, Jing; Leitus, Gregory; Ben-David, Yehoshoa Angewandte Chemie International Edition, Vol. 45, Issue 7 https://doi.org/10.1002/anie.200503771	journal	February 2006
Photoinduced Electron Transfer from Nitrogen-Doped Tantalum Oxide to Adsorbed Ruthenium Complex Yamanaka, Ken-ichi; Sato, Shunsuke; Iwaki, Masayo The Journal of Physical Chemistry C, Vol. 115, Issue 37 https://doi.org/10.1021/jp205223k	journal	August 2011
Hydrogen generation from formic acid and alcohols using homogeneous catalysts Johnson, Tarn C.; Morris, David J.; Wills, Martin Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B904495G	journal	January 2010
Cascade Catalysis for the Homogeneous Hydrogenation of CO ₂ to Methanol Huff, Chelsea A.; Sanford, Melanie S. Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja208760j	journal	November 2011
Highly Robust Hydrogen Generation by Bioinspired Ir Complexes for Dehydrogenation of Formic Acid in Water: Experimental and Theoretical Mechanistic Investigations at Different pH Wang, Wan-Hui; Ertem, Mehmed Z.; Xu, Shaoan ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b01090	journal	August 2015
Rhodium(I) catalyzed decomposition of formic acid Strauss, S. H.; Whitmire, K. H.; Shriver, D. F. Journal of Organometallic Chemistry, Vol. 174, Issue 3 https://doi.org/10.1016/S0022-328X(00)85605-3	journal	August 1979
[Ni(P ^Ph ₂ N ^C6H4X ₂ ) ₂ ] ²⁺ Complexes as Electrocatalysts for H ₂ Production: Effect of Substituents, Acids, and Water on Catalytic Rates Kilgore, Uriah J.; Roberts, John A. S.; Pool, Douglas H. Journal of the American Chemical Society, Vol. 133, Issue 15 https://doi.org/10.1021/ja109755f	journal	April 2011
Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee41272e	journal	January 2013
Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO ₂ Reduction Catalyst Schmeier, Timothy J.; Dobereiner, Graham E.; Crabtree, Robert H. Journal of the American Chemical Society, Vol. 133, Issue 24 https://doi.org/10.1021/ja2035514	journal	June 2011
Sodium hydroxide-assisted growth of uniform Pd nanoparticles on nanoporous carbon MSC-30 for efficient and complete dehydrogenation of formic acid under ambient conditions Zhu, Qi-Long; Tsumori, Nobuko; Xu, Qiang Chem. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C3SC52448E	journal	January 2014
Catalytic Hydrogenation of CO ₂ to Formic Acid with Silica-Tethered Iridium Catalysts Xu, Zheng; McNamara, Nicholas D.; Neumann, Gregory T. ChemCatChem, Vol. 5, Issue 7 https://doi.org/10.1002/cctc.201200839	journal	April 2013
Synthesis and structure of a ruthenium(II) complex incorporating κN bound 2-pyridonato ligands; a new catalytic system for transfer hydrogenation of ketones Kelson, Eric P.; Phengsy, Proma P. Journal of the Chemical Society, Dalton Transactions, Issue 22 https://doi.org/10.1039/b007041f	journal	January 2000
Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand Oldenhof, Sander; Lutz, Martin; de Bruin, Bas Chemical Science, Vol. 6, Issue 2 https://doi.org/10.1039/C4SC02555E	journal	January 2015
Highly efficient conversion of carbon dioxide catalyzed by half-sandwich complexes with pyridinol ligand: The electronic effect of oxyanion Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki Journal of Photochemistry and Photobiology A: Chemistry, Vol. 182, Issue 3 https://doi.org/10.1016/j.jphotochem.2006.04.025	journal	September 2006
ortho-Metalation of Iron(0) Tribenzylphosphine Complexes: Homogeneous Catalysts for the Generation of Hydrogen from Formic Acid Boddien, Albert; Gärtner, Felix; Jackstell, Ralf Angewandte Chemie International Edition, Vol. 49, Issue 47 https://doi.org/10.1002/anie.201004621	journal	October 2010
Solvent-dependent reactions of carbon dioxide with a platinum(II) dihydride. Reversible formation of a platinum(II) formatohydride and a cationic platinum(II) dimer, [Pt2H3(PEt3)4][HCO2] Paonessa, Ralph S.; Trogler, William C. Journal of the American Chemical Society, Vol. 104, Issue 12 https://doi.org/10.1021/ja00376a058	journal	June 1982
Homogeneous hydrogenation of carbon dioxide to methanol Li, Yu-Nong; Ma, Ran; He, Liang-Nian Catal. Sci. Technol., Vol. 4, Issue 6 https://doi.org/10.1039/C3CY00564J	journal	January 2014
The roles of the first and second coordination spheres in the design of molecular catalysts for H ₂ production and oxidation Rakowski DuBois, M.; DuBois, Daniel L. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B801197B	journal	January 2009
Free formic acid by hydrogenation of carbon dioxide in sodium formate solutions Zhao, Guoying; Joó, Ferenc Catalysis Communications, Vol. 14, Issue 1 https://doi.org/10.1016/j.catcom.2011.07.017	journal	October 2011
Ruthenium(II)Phosphite Complexes as Catalysts for the Hydrogenation of Carbon Dioxide Muller, Keven; Sun, Yu; Thiel, Werner R. ChemCatChem, Vol. 5, Issue 6 https://doi.org/10.1002/cctc.201200818	journal	February 2013
Hydrogen Generation at Ambient Conditions: Application in Fuel Cells Boddien, Albert; Loges, Björn; Junge, Henrik ChemSusChem, Vol. 1, Issue 8-9 https://doi.org/10.1002/cssc.200800093	journal	September 2008
Reaction-Controlled Phase-Transfer Catalysis for Propylene Epoxidation to Propylene Oxide Zuwei, X. Science, Vol. 292, Issue 5519 https://doi.org/10.1126/science.292.5519.1139	journal	May 2001
Aqueous CO ₂ Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles Chen, Yihong; Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 49 https://doi.org/10.1021/ja309317u	journal	November 2012
Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage? Enthaler, Stephan; von Langermann, Jan; Schmidt, Thomas Energy & Environmental Science, Vol. 3, Issue 9 https://doi.org/10.1039/b907569k	journal	January 2010
Synthesis and Structure of [6,6‘-Bi(5,7-dimethyl-1,4,8,11-tetraazacyclotetradecane)]dinickel(II) Triflate and Its Catalytic Activity for Photochemical CO ₂ Reduction Mochizuki, Katsura; Manaka, Shinobu; Takeda, Ikuyo Inorganic Chemistry, Vol. 35, Issue 18 https://doi.org/10.1021/ic960208e	journal	January 1996
CO₂ Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu₂O Films Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234 https://doi.org/10.1021/ja3010978	journal	April 2012
Formation and Characterization of Water-Soluble Hydrido-Ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane and Their Catalytic Activity in Hydrogenation of CO ₂ and HCO ₃ ^- in Aqueous Solution Laurenczy, Gábor; Joó, Ferenc; Nádasdi, Levente Inorganic Chemistry, Vol. 39, Issue 22 https://doi.org/10.1021/ic000200b	journal	October 2000
Electrocatalytic CO ₂ reduction by M(bpy-R)(CO) ₄ (M = Mo, W; R = H, tBu) complexes. Electrochemical, spectroscopic, and computational studies and comparison with group 7 catalysts Clark, Melissa L.; Grice, Kyle A.; Moore, Curtis E. Chem. Sci., Vol. 5, Issue 5 https://doi.org/10.1039/c3sc53470g	journal	January 2014
Synthesis, characterization and reactivity of heterobimetallic complexes (η ⁵ -C ₅ R ₅ )Ru(CO)(μ-dppm)M(CO) ₂ (η ⁵ -C ₅ H ₅ ) (R = H, CH ₃ ; M = Mo, W). Interconversion of hydrogen/carbon dioxide and formic acid by these complexes Man, Man Lok; Zhou, Zhongyuan; Ng, Siu Man Dalton Trans., Issue 19 https://doi.org/10.1039/b306835h	journal	January 2003
Rhodium-catalyzed hydrogenation of carbon dioxide to formic acid Tsai, Jing Cherng; Nicholas, Kenneth M. Journal of the American Chemical Society, Vol. 114, Issue 13 https://doi.org/10.1021/ja00039a024	journal	June 1992
Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst Bielinski, Elizabeth A.; Lagaditis, Paraskevi O.; Zhang, Yuanyuan Journal of the American Chemical Society, Vol. 136, Issue 29 https://doi.org/10.1021/ja505241x	journal	July 2014
Theoretical investigation of catalytic HCO3− hydrogenation in aqueous solutions Kovács, Gábor; Schubert, Gábor; Joó, Ferenc Catalysis Today, Vol. 115, Issue 1-4 https://doi.org/10.1016/j.cattod.2006.02.018	journal	June 2006
MoP nanosheets supported on biomass-derived carbon flake: One-step facile preparation and application as a novel high-active electrocatalyst toward hydrogen evolution reaction Cui, Wei; Liu, Qian; Xing, Zhicai Applied Catalysis B: Environmental, Vol. 164 https://doi.org/10.1016/j.apcatb.2014.09.016	journal	March 2015
Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction Xiao, Peng; Sk, Mahasin Alam; Thia, Larissa Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00957F	journal	January 2014
Metal Hydride and Ligand Proton Transfer Mechanism for the Hydrogenation of Dimethyl Carbonate to Methanol Catalyzed by a Pincer Ruthenium Complex Yang, Xinzheng ACS Catalysis, Vol. 2, Issue 6 https://doi.org/10.1021/cs3000683	journal	April 2012
Efficient and durable hydrogen evolution electrocatalyst based on nonmetallic nitrogen doped hexagonal carbon Liu, Yanming; Yu, Hongtao; Quan, Xie Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06843	journal	October 2014
Towards a Practical Setup for Hydrogen Production from Formic Acid Sponholz, Peter; Mellmann, Dörthe; Junge, Henrik ChemSusChem, Vol. 6, Issue 7 https://doi.org/10.1002/cssc.201300186	journal	June 2013
Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts Schneider, Jacob; Jia, Hongfei; Muckerman, James T. Chem. Soc. Rev., Vol. 41, Issue 6 https://doi.org/10.1039/C1CS15278E	journal	January 2012
Carbon Dioxide Hydrogenation Catalyzed by a Ruthenium Dihydride: A DFT and High-Pressure Spectroscopic Investigation Urakawa, Atsushi; Jutz, Fabian; Laurenczy, Gábor Chemistry - A European Journal, Vol. 13, Issue 14 https://doi.org/10.1002/chem.200601339	journal	May 2007
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Recyclable Catalyst for Conversion of Carbon Dioxide into Formate Attributable to an Oxyanion on the Catalyst Ligand Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki Journal of the American Chemical Society, Vol. 127, Issue 38 https://doi.org/10.1021/ja054236k	journal	September 2005
pH-Responsive N-heterocyclic carbene copper(i) complexes: syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide Wang, Wenlong; Zhang, Guodong; Lang, Rui Green Chemistry, Vol. 15, Issue 3 https://doi.org/10.1039/c3gc36830k	journal	January 2013
Unprecedented Catalytic Hydrogenation of Urea Derivatives to Amines and Methanol Balaraman, Ekambaram; Ben-David, Yehoshoa; Milstein, David Angewandte Chemie International Edition, Vol. 50, Issue 49 https://doi.org/10.1002/anie.201106612	journal	November 2011
An efficient binuclear catalyst for decomposition of formic acid Gao, Yuan; Kuncheria, Joshi; Puddephatt, Richard J. Chemical Communications, Issue 21 https://doi.org/10.1039/a805789c	journal	January 1998
Homogeneous catalytic hydrogenation of supercritical carbon dioxide Jessop, Philip G.; Ikariya, Takao; Noyori, Ryoji Nature, Vol. 368, Issue 6468 https://doi.org/10.1038/368231a0	journal	March 1994
Organic molecules as mediators and catalysts for photocatalytic and electrocatalytic CO ₂ reduction Oh, Yeonji; Hu, Xile Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35276A	journal	January 2013
Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water Federsel, Christopher; Jackstell, Ralf; Boddien, Albert ChemSusChem, Vol. 3, Issue 9 https://doi.org/10.1002/cssc.201000151	journal	July 2010
Cobaloxime-Based Photocatalytic Devices for Hydrogen Production Fihri, Aziz; Artero, Vincent; Razavet, Mathieu Angewandte Chemie International Edition, Vol. 47, Issue 3 https://doi.org/10.1002/anie.200702953	journal	January 2008
Methanol Synthesis Waugh, K. C. Catalysis Today, Vol. 15, Issue 1 https://doi.org/10.1016/0920-5861(92)80122-4	journal	May 1992
The Hidden Equilibrium in Aqueous Sodium Carbonate Solutions ? Evidence for the Formation of the Dicarbonate Anion Zeller, Klaus-Peter; Schuler, Paul; Haiss, Peter European Journal of Inorganic Chemistry, Vol. 2005, Issue 1 https://doi.org/10.1002/ejic.200400445	journal	January 2005
Photocatalytic generation of solar fuels from the reduction of H ₂ O and CO ₂ : a look at the patent literature Protti, Stefano; Albini, Angelo; Serpone, Nick Physical Chemistry Chemical Physics, Vol. 16, Issue 37 https://doi.org/10.1039/C4CP02828G	journal	January 2014
Photocatalytic CO ₂ Reduction using Non-Titanium Metal Oxides and Sulfides Navalón, Sergio; Dhakshinamoorthy, Amarajothi; Álvaro, Mercedes ChemSusChem, Vol. 6, Issue 4 https://doi.org/10.1002/cssc.201200670	journal	March 2013
An Aqueous Rechargeable Formate-Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis Bi, Qing-Yuan; Lin, Jian-Dong; Liu, Yong-Mei Angewandte Chemie International Edition, Vol. 53, Issue 49 https://doi.org/10.1002/anie.201409500	journal	November 2014
Colloid-catalysed arene hydrogenation in aqueous/supercritical fluid biphasic media Jason Bonilla, R.; Jessop, Philip G.; James, Brian R. Chemical Communications, Issue 11 https://doi.org/10.1039/a907193h	journal	January 2000
Improving the Efficiency of the Hydrogenation of Carbonates and Carbon Dioxide to Methanol Li, Yuehui; Junge, Kathrin; Beller, Matthias ChemCatChem, Vol. 5, Issue 5 https://doi.org/10.1002/cctc.201300013	journal	March 2013
Liquid-Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions Jiang , Hai-Long; Singh , Sanjay Kumar; Yan , Jun-Min ChemSusChem, Vol. 3, Issue 5 https://doi.org/10.1002/cssc.201000023	journal	April 2010
Involvement of a Binuclear Species with the Re−C(O)O−Re Moiety in CO ₂ Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands: Strikingly Slow Formation of the Re−Re and Re−C(O)O−Re Species from Re(dmb)(CO) ₃ S (dmb = 4,4‘-Dimethyl-2,2‘-bipyridine, S = Solvent) Hayashi, Yukiko; Kita, Shouichi; Brunschwig, Bruce S. Journal of the American Chemical Society, Vol. 125, Issue 39 https://doi.org/10.1021/ja035960a	journal	October 2003
New Way for CO ₂ Reduction under Visible Light by a Combination of a Cu Electrode and Semiconductor Thin Film: Cu ₂ O Conduction Type and Morphology Effect Ba, Xin; Yan, Li-Li; Huang, Sheng The Journal of Physical Chemistry C, Vol. 118, Issue 42 https://doi.org/10.1021/jp5063397	journal	October 2014
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Production of HCOOH/NEt ₃ Adducts by CO ₂ /H ₂ Incorporation into Neat NEt ₃ Preti, Debora; Squarcialupi, Sergio; Fachinetti, Giuseppe Angewandte Chemie International Edition, Vol. 49, Issue 14 https://doi.org/10.1002/anie.200906054	journal	March 2010
Catalytic Fixation of Carbon Dioxide to Formic acid by Transition-Metal Complexes Under mild Conditions Inoue, Yoshio; Izumida, Hitoshi; Sasaki, Yoshiyuki Chemistry Letters, Vol. 5, Issue 8 https://doi.org/10.1246/cl.1976.863	journal	August 1976
Mechanistic and Kinetic Studies of Cobalt Macrocycles in a Photochemical CO2 Reduction System: Evidence of Co-CO2 Adducts as Intermediates Ogata, Tomoyuki; Yanagida, Shozo; Brunschwig, Bruce S. Journal of the American Chemical Society, Vol. 117, Issue 25 https://doi.org/10.1021/ja00130a009	journal	June 1995
Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja5116937	journal	December 2014
Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions—a novel possibility of carbon dioxide activation† Joó, Ferenc; Joó, Ferenc; Nádasdi, Levente Chemical Communications, Issue 11 https://doi.org/10.1039/a902368b	journal	January 1999
A Continuous-Flow Method for the Generation of Hydrogen from Formic Acid Majewski, Artur; Morris, David J.; Kendall, Kevin ChemSusChem, Vol. 3, Issue 4 https://doi.org/10.1002/cssc.201000017	journal	April 2010
Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
In Situ Formation of Ruthenium Catalysts for the Homogeneous Hydrogenation of Carbon Dioxide Tai, Chih-Cheng; Pitts, Justine; Linehan, John C. Inorganic Chemistry, Vol. 41, Issue 6 https://doi.org/10.1021/ic010866l	journal	March 2002
Catalytic Disproportionation of Formic Acid to Generate Methanol Miller, Alexander J. M.; Heinekey, D. Michael; Mayer, James M. Angewandte Chemie International Edition, Vol. 52, Issue 14 https://doi.org/10.1002/anie.201208470	journal	February 2013
Heterogeneous photocatalytic synthesis of methane from acetic acid - new Kolbe reaction pathway Kraeutler, Bernhard; Bard, Allen J. Journal of the American Chemical Society, Vol. 100, Issue 7 https://doi.org/10.1021/ja00475a049	journal	March 1978
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under mild conditions with water soluble rhodium(I)- and ruthenium(II)-phosphine catalysts Jo�, Ferenc; Laurenczy, G�bor; Kar�dy, P�ter Applied Organometallic Chemistry, Vol. 14, Issue 12 https://doi.org/10.1002/1099-0739(200012)14:12<857::AID-AOC86>3.0.CO;2-9	journal	January 2000

Cited By (221)

Hydrogenation of CO ₂ to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water Rohmann, Kai; Kothe, Jens; Haenel, Matthias W. Angewandte Chemie, Vol. 128, Issue 31 https://doi.org/10.1002/ange.201603878	journal	June 2016
Insight into catalytic reduction of CO 2 to methane with silanes using Brookhart's cationic Ir( iii ) pincer complex Fang, Shaoqin; Chen, Hongcai; Wei, Haiyan RSC Advances, Vol. 8, Issue 17 https://doi.org/10.1039/c7ra13486j	journal	January 2018
Heterogeneous catalysts for hydrogenation of CO ₂ and bicarbonates to formic acid and formates Bulushev, Dmitri A.; Ross, Julian R. H. Catalysis Reviews, Vol. 60, Issue 4 https://doi.org/10.1080/01614940.2018.1476806	journal	June 2018
Copper–Silver Bimetallic Nanowire Arrays for Electrochemical Reduction of Carbon Dioxide Wang, Yuanxing; Niu, Cailing; Zhu, Yachuan Nanomaterials, Vol. 9, Issue 2 https://doi.org/10.3390/nano9020173	journal	January 2019
The Role of Support in Formic Acid Decomposition on Gold Catalysts Sobolev, Vladimir; Asanov, Igor; Koltunov, Konstantin Energies, Vol. 12, Issue 21 https://doi.org/10.3390/en12214198	journal	November 2019
Polyoxometalate-based ionic liquids-promoted CO2 conversion Wang, Mei-Yan; Ma, Ran; He, Liang-Nian Science China Chemistry, Vol. 59, Issue 5 https://doi.org/10.1007/s11426-016-5560-9	journal	March 2016
Photodriven CO dimerization on Cu ₂ O from an electronic-structure perspective Hedström, Svante; Halldin Stenlid, Joakim; Liu, Chang Sustainable Energy & Fuels, Vol. 4, Issue 2 https://doi.org/10.1039/c9se00753a	journal	January 2020
An antimonene/Cp*Rh(phen)Cl/black phosphorus hybrid nanosheet-based Z-scheme artificial photosynthesis for enhanced photo/bio-catalytic CO ₂ reduction Ji, Xiaoyuan; Kang, Yong; Fan, Taojian Journal of Materials Chemistry A, Vol. 8, Issue 1 https://doi.org/10.1039/c9ta11167k	journal	January 2020
Surface-Amine-Implanting Approach for Catalyst Functionalization: Prominently Enhancing Catalytic Hydrogen Generation from Formic Acid: Surface-Amine-Implanting Approach for Catalyst Functionalization: Prominently Enhancing Catalytic Hydrogen Generation from Formic Acid Zhu, De-Jie; Wen, Yue-Hong; Xu, Qiang European Journal of Inorganic Chemistry, Vol. 2017, Issue 40 https://doi.org/10.1002/ejic.201701108	journal	October 2017
Efficient light-driven CO ₂ hydrogenation on Ru/CeO ₂ catalysts Quan, Fengjiao; Zhan, Guangming; Mao, Chengliang Catalysis Science & Technology, Vol. 8, Issue 24 https://doi.org/10.1039/c8cy01787e	journal	January 2018
Unexpected concerted two-proton transfer for amination of formic acid to formamide catalysed by Mn bipyridinol complexes Yan, Xiuli; Ge, Hongyu; Yang, Xinzheng Catalysis Science & Technology, Vol. 8, Issue 22 https://doi.org/10.1039/c8cy01424h	journal	January 2018
Carbon dioxide hydrogenation catalysed by well-defined Mn( i ) PNP pincer hydride complexes Bertini, Federica; Glatz, Mathias; Gorgas, Nikolaus Chemical Science, Vol. 8, Issue 7 https://doi.org/10.1039/c7sc00209b	journal	January 2017
Base-free hydrogenation of CO ₂ to formic acid in water with an iridium complex bearing a N,N′-diimine ligand Lu, Sheng-Mei; Wang, Zhijun; Li, Jun Green Chemistry, Vol. 18, Issue 16 https://doi.org/10.1039/c6gc00856a	journal	January 2016
Ionic Liquid-Promoted Three-Component Domino Reaction of Propargyl Alcohols, Carbon Dioxide and 2-Aminoethanols: A Thermodynamically Favorable Synthesis of 2-Oxazolidinones Xia, Shu-Mei; Song, Yu; Li, Xue-Dong Molecules https://doi.org/10.20944/preprints201810.0351.v1	journal	October 2018
Pd/C‐catalyzed reduction of NaHCO ₃ into formate with 2‐pyrrolidone under hydrothermal conditions Zhu, Yanjie; Yang, Yang; Wang, Xiaoguang Energy Science & Engineering, Vol. 7, Issue 3 https://doi.org/10.1002/ese3.317	journal	March 2019
Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups Erken, Christina; Kaithal, Akash; Sen, Suman RWTH Aachen University https://doi.org/10.18154/rwth-2018-231655	text	January 2018
Influence of Calcination Temperature on Activity and Selectivity of Ni–CeO2 and Ni–Ce0.8Zr0.2O2 Catalysts for CO2 Methanation Yu, Yang; Bian, Zhoufeng; Song, Fujiao Topics in Catalysis, Vol. 61, Issue 15-17 https://doi.org/10.1007/s11244-018-1010-6	journal	July 2018
Carbon dioxide hydrogenation over nickel-, ruthenium-, and copper-based catalysts: Review of kinetics and mechanism Jalama, Kalala Catalysis Reviews, Vol. 59, Issue 2 https://doi.org/10.1080/01614940.2017.1316172	journal	April 2017
Chemoselective and efficient catalytic hydrogenation of furfural by iridium and ruthenium half-sandwich complexes Oklu, Novisi K.; Makhubela, Banothile C. E. New Journal of Chemistry, Vol. 44, Issue 22 https://doi.org/10.1039/d0nj01811b	journal	January 2020
Silver‐Nanowire‐Catalyzed Three‐Component Coupling of Carbon Dioxide, Amines and Propargylic Alcohols for the Synthesis of β‐Oxopropyl Carbamates Wang, Qiong; Xiong, Wenfang; Deng, Xiulong Asian Journal of Organic Chemistry https://doi.org/10.1002/ajoc.201800610	journal	December 2018
Choline-based ionic liquids for CO2 capture and conversion Li, Ruipeng; Zhao, Yanfei; Li, Zhiyong Science China Chemistry, Vol. 62, Issue 2 https://doi.org/10.1007/s11426-018-9358-6	journal	November 2018
Heterogeneous Phase Microwave-Assisted Reactions under CO2 or CO Pressure Calcio Gaudino, Emanuela; Rinaldi, Laura; Rotolo, Laura Molecules, Vol. 21, Issue 3 https://doi.org/10.3390/molecules21030253	journal	February 2016
Lewis Base Promoted Reduction of CO ₂ with BH ₃ NH ₃ into Boryl Formates: CO ₂ as a Carbon Source in Organic Synthesis Under Mild Conditions: Lewis Base Promoted Reduction of CO ₂ with BH ₃ NH ₃ into Boryl Formates: CO ₂ as a Carbon Source in Organic Synthesis Under Mild Conditions Zhang, Bo; Du, Gaixia; Hang, Wei European Journal of Organic Chemistry, Vol. 2018, Issue 14 https://doi.org/10.1002/ejoc.201800320	journal	April 2018
Well-Defined Cesium Benzotriazolide as an Active Catalyst for Generating Disubstituted Ureas from Carbon Dioxide and Amines Truong, Cong Chien; Kim, Jin; Lee, Yunho ChemCatChem, Vol. 9, Issue 2 https://doi.org/10.1002/cctc.201601320	journal	December 2016
CO ₂ activation by manganese pincer complexes through different modes of metal–ligand cooperation Kumar, Amit; Daw, Prosenjit; Espinosa-Jalapa, Noel Angel Dalton Transactions, Vol. 48, Issue 39 https://doi.org/10.1039/c9dt03088c	journal	January 2019
Unravelling charge carrier dynamics in protonated g-C3N4 interfaced with carbon nanodots as co-catalysts toward enhanced photocatalytic CO2 reduction: A combined experimental and first-principles DFT study Ong, Wee-Jun; Putri, Lutfi Kurnianditia; Tan, Yoong-Chuen Nano Research, Vol. 10, Issue 5 https://doi.org/10.1007/s12274-016-1391-4	journal	February 2017
Elucidating the origins of enhanced CO ₂ reduction in manganese electrocatalysts bearing pendant hydrogen-bond donors Tignor, Steven E.; Shaw, Travis W.; Bocarsly, Andrew B. Dalton Transactions, Vol. 48, Issue 33 https://doi.org/10.1039/c9dt02060h	journal	January 2019
A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction Lv, Jing-Jing; Jouny, Matthew; Luc, Wesley Advanced Materials, Vol. 30, Issue 49 https://doi.org/10.1002/adma.201803111	journal	October 2018
A phenanthroline-based porous organic polymer for the iridium-catalyzed hydrogenation of carbon dioxide to formate Gunasekar, Gunniya Hariyanandam; Yoon, Sungho Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta03807h	journal	January 2019
Application of POCOP Pincer Nickel Complexes to the Catalytic Hydroboration of Carbon Dioxide Zhang, Jie; Chang, Jiarui; Liu, Ting Catalysts, Vol. 8, Issue 11 https://doi.org/10.3390/catal8110508	journal	November 2018
Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO ₂ Fixation Reactions Bhanja, Piyali; Modak, Arindam; Bhaumik, Asim Chemistry – A European Journal, Vol. 24, Issue 29 https://doi.org/10.1002/chem.201800075	journal	April 2018
Formic acid-mediated liquefaction of chitin Zhang, Jiaguang; Yan, Ning Green Chemistry, Vol. 18, Issue 18 https://doi.org/10.1039/c6gc01053a	journal	January 2016
Hydricity, electrochemistry, and excited-state chemistry of Ir complexes for CO ₂ reduction Manbeck, Gerald F.; Garg, Komal; Shimoda, Tomoe Faraday Discussions, Vol. 198 https://doi.org/10.1039/c6fd00223d	journal	January 2017
Ligand Effect on the Stability of Water‐Soluble Iridium Catalysts for High‐Pressure Hydrogen Gas Production by Dehydrogenation of Formic Acid Iguchi, Masayuki; Onishi, Naoya; Himeda, Yuichiro ChemPhysChem, Vol. 20, Issue 10 https://doi.org/10.1002/cphc.201900425	journal	March 2019
Can Steam- and CO-Rich Streams Be Produced Sequentially in the Isothermal Chemical Looping Super-Dry Reforming Scheme? Wang, Xinhe; Wei, Jinjia; Zhang, Junshe ACS Omega, Vol. 5, Issue 10 https://doi.org/10.1021/acsomega.9b04464	journal	March 2020
Ruthenium-catalyzed hydrogenation of CO ₂ as a route to methyl esters for use as biofuels or fine chemicals Wang, Zheng; Zhao, Ziwei; Li, Yong Chemical Science https://doi.org/10.1039/d0sc02942d	journal	January 2020
Tungstate catalysis: pressure-switched 2- and 6-electron reductive functionalization of CO ₂ with amines and phenylsilane Wang, Mei-Yan; Wang, Ning; Liu, Xiao-Fang Green Chemistry, Vol. 20, Issue 7 https://doi.org/10.1039/c7gc03416d	journal	January 2018
A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates Schieweck, Benjamin Georg; Westhues, Niklas; Klankermayer, Jürgen RWTH Aachen University https://doi.org/10.18154/rwth-2019-06858	text	January 2019
Acceleration of CO ₂ insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics Heimann, Jessica E.; Bernskoetter, Wesley H.; Hazari, Nilay Chemical Science, Vol. 9, Issue 32 https://doi.org/10.1039/c8sc02535e	journal	January 2018
Copper catalysis: ligand-controlled selective N -methylation or N -formylation of amines with CO ₂ and phenylsilane Li, Xue-Dong; Xia, Shu-Mei; Chen, Kai-Hong Green Chemistry, Vol. 20, Issue 21 https://doi.org/10.1039/c8gc02280a	journal	January 2018
Conversion of Carbon Dioxide into Formic Acid Fegade, Umesh; Jethave, Ganesh Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology, p. 91-110 https://doi.org/10.1007/978-3-030-28638-5_4	book	November 2019
Metal-free imidazolium hydrogen carbonate ionic liquids as bifunctional catalysts for the one-pot synthesis of cyclic carbonates from olefins and CO 2 Liu, Jia; Yang, Guoqiang; Liu, Ying Green Chemistry, Vol. 21, Issue 14 https://doi.org/10.1039/c9gc01088b	journal	January 2019
A ruthenium-based plasmonic hybrid photocatalyst for aqueous carbon dioxide conversion with a high reaction rate and selectivity Jun, Hwiseok; Choi, Shinyoung; Yang, Moon Young Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/c9ta05880j	journal	January 2019
Selective Reduction of Oxygen on Non‐Noble Metal Copper Nanocatalysts Kuhn, Andrew N.; Ma, Yanling; Zhang, Cheng Energy Technology, Vol. 8, Issue 3 https://doi.org/10.1002/ente.201901213	journal	December 2019
pH-Regulated Aqueous Catalytic Hydrogenation of Biomass Carbohydrate Derivatives by Using Semisandwich Iridium Complexes Wu, Wei-Peng; Xu, Yong-Jian; Chang, Shang-Wei ChemCatChem, Vol. 8, Issue 21 https://doi.org/10.1002/cctc.201601009	journal	September 2016
Direct catalytic hydrogenation of CO2 to formate over a Schiff-base-mediated gold nanocatalyst Liu, Qinggang; Yang, Xiaofeng; Li, Lin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01673-3	journal	November 2017
Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+ Firouzbakht, Marjan; Rijs, Nicole J.; Schlangen, Maria Topics in Catalysis, Vol. 61, Issue 7-8 https://doi.org/10.1007/s11244-018-0903-8	journal	January 2018
Semiconductor Quantum Dots: An Emerging Candidate for CO ₂ Photoreduction Wu, Hao‐Lin; Li, Xu‐Bing; Tung, Chen‐Ho Advanced Materials, Vol. 31, Issue 36 https://doi.org/10.1002/adma.201900709	journal	June 2019
Coordination of 3-Methylindole-Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent Two-Electron Reduction: Coordination of 3-Methylindole-Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent van de Watering, Fenna F.; Stroek, Wowa; Ivar van der Vlugt, Jarl European Journal of Inorganic Chemistry, Vol. 2018, Issue 11 https://doi.org/10.1002/ejic.201701209	journal	February 2018
Development of Effective Catalysts for Hydrogen Storage Technology Using Formic Acid Onishi, Naoya; Iguchi, Masayuki; Yang, Xinchun Advanced Energy Materials, Vol. 9, Issue 23 https://doi.org/10.1002/aenm.201801275	journal	September 2018
Atomically Dispersed Bimetallic FeNi Catalysts as Highly Efficient Bifunctional Catalysts for Reversible Oxygen Evolution and Oxygen Reduction Reactions Cheng, Yi; He, Shuai; Veder, Jean‐Pierre ChemElectroChem, Vol. 6, Issue 13 https://doi.org/10.1002/celc.201900483	journal	July 2019
Evaluating the carbon inventory, carbon fluxes and carbon cycles for a long-term sustainable world Tomkins, P.; Müller, T. E. Green Chemistry, Vol. 21, Issue 15 https://doi.org/10.1039/c9gc00528e	journal	January 2019
CO ₂ electroreduction performance of a single transition metal atom supported on porphyrin-like graphene: a computational study Wang, Zhongxu; Zhao, Jingxiang; Cai, Qinghai Physical Chemistry Chemical Physics, Vol. 19, Issue 34 https://doi.org/10.1039/c7cp04299j	journal	January 2017
Emerging Applications of Plasmons in Driving CO ₂ Reduction and N ₂ Fixation Yang, Jianhua; Guo, Yanzhen; Lu, Wenzheng Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802227	journal	July 2018
CO ₂ Reduction: From the Electrochemical to Photochemical Approach Wu, Jinghua; Huang, Yang; Ye, Wen Advanced Science, Vol. 4, Issue 11 https://doi.org/10.1002/advs.201700194	journal	September 2017
Arising synergetic and antagonistic effects in the design of Ni- and Ru-based water splitting electrocatalysts Marques Mota, Filipe; Choi, Chi Hun; Boppella, Ramireddy Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta08535h	journal	January 2019
Bio-mimetic self-assembled computationally designed catalysts of Mo and W for hydrogenation of CO ₂ /dehydrogenation of HCOOH inspired by the active site of formate dehydrogenase Shiekh, Bilal Ahmad; Kaur, Damanjit; Kumar, Sourav Physical Chemistry Chemical Physics, Vol. 21, Issue 38 https://doi.org/10.1039/c9cp03406d	journal	January 2019
Recent developments in the catalytic hydrogenation of CO ₂ to formic acid/formate using heterogeneous catalysts Gunasekar, Gunniya Hariyanandam; Park, Kwangho; Jung, Kwang-Deog Inorganic Chemistry Frontiers, Vol. 3, Issue 7 https://doi.org/10.1039/c5qi00231a	journal	January 2016
Supported Single Atoms as New Class of Catalysts for Electrochemical Reduction of Carbon Dioxide Cheng, Yi; Yang, Shize; Jiang, San Ping Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201800440	journal	February 2019
Bio-based 1,3-diisobutyl imidazolium hydrogen oxalate [iBu ₂ IM](HC ₂ O ₄ ) as CO ₂ shuttle de Robillard, G.; Fournier, A. H.; Cattey, H. Green Chemistry, Vol. 19, Issue 20 https://doi.org/10.1039/c7gc02167d	journal	January 2017
Catalytic hydrogenation of carboxylic acids using low-valent and high-valent metal complexes Yoshioka, Shota; Saito, Susumu Chemical Communications, Vol. 54, Issue 95 https://doi.org/10.1039/c8cc06543h	journal	January 2018
Phosphine-free ruthenium NCN-ligand complexes and their use in catalytic CO ₂ hydrogenation Sung, Molly M. H.; Prokopchuk, Demyan E.; Morris, Robert H. Dalton Transactions, Vol. 48, Issue 44 https://doi.org/10.1039/c9dt03143j	journal	January 2019
CO ₂ reduction or HCO ₂ ⁻ oxidation? Solvent-dependent thermochemistry of a nickel hydride complex Ceballos, Bianca M.; Tsay, Charlene; Yang, Jenny Y. Chemical Communications, Vol. 53, Issue 53 https://doi.org/10.1039/c7cc02511d	journal	January 2017
Poly(ethyleneimine)-Mediated Consecutive Hydrogenation of Carbon Dioxide to Methanol with Ru Catalysts: Poly(ethyleneimine)-Mediated Consecutive Hydrogenation of Carbon Dioxide to Methanol with Ru Catalysts Yoshimura, Atsuki; Watari, Ryo; Kuwata, Shigeki European Journal of Inorganic Chemistry, Vol. 2019, Issue 18 https://doi.org/10.1002/ejic.201900322	journal	May 2019
Conversion of CO ₂ from air into formate using amines and phosphorus-nitrogen PN ³ P-Ru( ii ) pincer complexes Guan, Chao; Pan, Yupeng; Ang, Eleanor Pei Ling Green Chemistry, Vol. 20, Issue 18 https://doi.org/10.1039/c8gc02186d	journal	January 2018
A MOF-assisted phosphine free bifunctional iron complex for the hydrogenation of carbon dioxide, sodium bicarbonate and carbonate to formate Coufourier, Sébastien; Gaillard, Sylvain; Clet, Guillaume Chemical Communications, Vol. 55, Issue 34 https://doi.org/10.1039/c8cc09771b	journal	January 2019
Mechanistic Insights on the Reduction of CO ₂ to Silylformates Catalyzed by Ir-NSiN Species Julián, Alejandro; Guzmán, Jefferson; Jaseer, E. A. Chemistry - A European Journal, Vol. 23, Issue 49 https://doi.org/10.1002/chem.201702246	journal	August 2017
Changing the Mechanism for CO ₂ Hydrogenation Using Solvent-Dependent Thermodynamics Burgess, Samantha A.; Appel, Aaron M.; Linehan, John C. Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201709319	journal	October 2017
On-demand hydrogen production from formic acid by light-active dinuclear iridium catalysts Sofue, Yuki; Nomura, Kotohiro; Inagaki, Akiko Chemical Communications, Vol. 56, Issue 33 https://doi.org/10.1039/d0cc00704h	journal	January 2020
Tuning the catalytic activity of heterogeneous two-dimensional transition metal dichalcogenides for hydrogen evolution Noh, Seung Hyo; Hwang, Jeemin; Kang, Joonhee Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/c8ta07141a	journal	January 2018
A Novel Photo-Driven Hydrogenation Reaction of an NAD+-Type Complex Toward Artificial Photosynthesis Ohtsu, Hideki; Saito, Tsubasa; Tsuge, Kiyoshi Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00580	journal	August 2019
Reversible Hydrogen Releasing and Fixing with Poly(Vinylfluorenol) through a Mild Ir‐Catalyzed Dehydrogenation and Electrochemical Hydrogenation Kato, Ryo; Oka, Kouki; Yoshimasa, Keisuke Macromolecular Rapid Communications, Vol. 40, Issue 16 https://doi.org/10.1002/marc.201900139	journal	June 2019
Protic NNN and NCN Pincer-Type Ruthenium Complexes Featuring (Trifluoromethyl)pyrazole Arms: Synthesis and Application to Catalytic Hydrogen Evolution from Formic Acid Nakahara, Yoshiko; Toda, Tatsuro; Matsunami, Asuka Chemistry - An Asian Journal, Vol. 13, Issue 1 https://doi.org/10.1002/asia.201701474	journal	December 2017
Operando Modeling of Multicomponent Reactive Solutions in Homogeneous Catalysis: from Non‐standard Free Energies to Reaction Network Control Kuliaev, Pavel O.; Pidko, Evgeny A. ChemCatChem, Vol. 12, Issue 3 https://doi.org/10.1002/cctc.201901911	journal	December 2019
Heterogeneous catalysts for catalytic CO2 conversion into value-added chemicals Whang, Ho Seok; Lim, Jinkyu; Choi, Min Suk BMC Chemical Engineering, Vol. 1, Issue 1 https://doi.org/10.1186/s42480-019-0007-7	journal	March 2019
Efficient Carboxylation of Terminal Alkynes with Carbon Dioxide Catalyzed by Ligand‐Free Copper Catalyst under Ambient Conditions Wang, Wan‐Hui; Jia, Lihong; Feng, Xiujuan Asian Journal of Organic Chemistry, Vol. 8, Issue 8 https://doi.org/10.1002/ajoc.201900288	journal	July 2019
Selective light driven reduction of CO ₂ to HCOOH in water using a {MoV ₉ } _n ( n = 1332–3600) based soft-oxometalate (SOM) Barman, Soumitra; Das, Santu; S. S., Sreejith Chemical Communications, Vol. 54, Issue 19 https://doi.org/10.1039/c7cc09520a	journal	January 2018
Advances and challenges in modeling solvated reaction mechanisms for renewable fuels and chemicals Basdogan, Yasemin; Maldonado, Alex M.; Keith, John A. WIREs Computational Molecular Science, Vol. 10, Issue 2 https://doi.org/10.1002/wcms.1446	journal	August 2019
Hydrogen Production and Storage on a Formic Acid/Bicarbonate Platform using Water-Soluble N -Heterocyclic Carbene Complexes of Late Transition Metals Jantke, Dominik; Pardatscher, Lorenz; Drees, Markus ChemSusChem, Vol. 9, Issue 19 https://doi.org/10.1002/cssc.201600861	journal	September 2016
Use of CO2 as Source of Carbon for Energy-Rich Cn Products Xiao, Jiang; Guo, Xinwen; Song, Chunshan An Economy Based on Carbon Dioxide and Water https://doi.org/10.1007/978-3-030-15868-2_6	book	January 2019
Computational Design of Quaterpyridine‐Based Fe/Mn–Complexes for the Direct Hydrogenation of CO ₂ to HCOOH: A Direction for Atom‐Economic Approach Biswas, Santu; Pramanik, Anup; Sarkar, Pranab ChemistrySelect, Vol. 3, Issue 18 https://doi.org/10.1002/slct.201800169	journal	May 2018
Enhancement of electrocatalytic abilities for reducing carbon dioxide: functionalization with a redox-active ligand-coordinated metal complex Ahsan, Habib Md.; Breedlove, Brian K.; Piangrawee, Santivongskul Dalton Transactions, Vol. 47, Issue 33 https://doi.org/10.1039/c8dt02288g	journal	January 2018
Pore-structure-directed CO 2 electroreduction to formate on SnO 2 /C catalysts He, Yeheng; Jiang, Wen-Jie; Zhang, Yun Journal of Materials Chemistry A, Vol. 7, Issue 31 https://doi.org/10.1039/c9ta05937g	journal	January 2019
Conformational twisting of a formate-bridged diiridium complex enables catalytic formic acid dehydrogenation Lauridsen, Paul J.; Lu, Zhiyao; Celaje, Jeff J. A. Dalton Transactions, Vol. 47, Issue 38 https://doi.org/10.1039/c8dt03268h	journal	January 2018
Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex Schneck, Felix; Schendzielorz, Florian; Hatami, Nareh Angewandte Chemie International Edition, Vol. 57, Issue 44 https://doi.org/10.1002/anie.201803396	journal	July 2018
A DFT Study of CO₂Hydrogenation on Faujasite-Supported Ir₄Clusters: on the Role of Water for Selectivity Control Szyja, Bartłomiej M.; Smykowski, Daniel; Szczygieł, Jerzy ChemCatChem, Vol. 8, Issue 15 https://doi.org/10.1002/cctc.201600644	journal	June 2016
Integrated Bismuth Oxide Ultrathin Nanosheets/Carbon Foam Electrode for Highly Selective and Energy‐Efficient Electrocatalytic Conversion of CO ₂ to HCOOH Meng, Fan‐Lu; Zhang, Qi; Liu, Kai‐Hua Chemistry – A European Journal https://doi.org/10.1002/chem.201903158	journal	October 2019
Iridium–NHC-based catalyst for ambient pressure storage and low temperature release of H ₂ via the CO ₂ /HCO ₂ H couple Semwal, Shrivats; Kumar, Abhishek; Choudhury, Joyanta Catalysis Science & Technology, Vol. 8, Issue 23 https://doi.org/10.1039/c8cy02069h	journal	January 2018
Poly(ethyleneimine)-tethered Ir Complex Catalyst Immobilized in Titanate Nanotubes for Hydrogenation of CO ₂ to Formic Acid Kuwahara, Yasutaka; Fujie, Yuki; Yamashita, Hiromi ChemCatChem, Vol. 9, Issue 11 https://doi.org/10.1002/cctc.201700508	journal	May 2017
Synthesis of Carboxylic Acids and Esters from CO2 Wu, Xiao-Feng; Zheng, Feng Topics in Current Chemistry Collections https://doi.org/10.1007/978-3-319-77757-3_1	book	January 2016
Formic Acid‐Based Liquid Organic Hydrogen Carrier System with Heterogeneous Catalysts Zhong, Heng; Iguchi, Masayuki; Chatterjee, Maya Advanced Sustainable Systems, Vol. 2, Issue 2 https://doi.org/10.1002/adsu.201700161	journal	January 2018
Ionic Liquid-Promoted Three-Component Domino Reaction of Propargyl Alcohols, Carbon Dioxide and 2-Aminoethanols: A Thermodynamically Favorable Synthesis of 2-Oxazolidinones Xia, Shumei; Song, Yu; Li, Xuedong Molecules, Vol. 23, Issue 11 https://doi.org/10.3390/molecules23113033	journal	November 2018
The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion Schneck, Felix; Ahrens, Jennifer; Finger, Markus Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03239-3	journal	March 2018
Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO ₂ Hydrogenation: Integrated Reaction and Catalyst Separation for CO ₂ -Scrubbing Solutions Scott, Martin; Blas Molinos, Beatriz; Westhues, Christian ChemSusChem, Vol. 10, Issue 6 https://doi.org/10.1002/cssc.201601814	journal	February 2017
CO ₂ Catalysis Kleij, Arjan W.; North, Michael; Urakawa, Atsushi ChemSusChem, Vol. 10, Issue 6 https://doi.org/10.1002/cssc.201700218	journal	February 2017
Hydrogenation of CO2 to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water Rohmann, Kai; Kothe, Jens; Haenel, Matthias W. RWTH Aachen University https://doi.org/10.18154/rwth-2017-01809	text	January 2016
Palladium on Nitrogen-Doped Mesoporous Carbon: A Bifunctional Catalyst for Formate-Based, Carbon-Neutral Hydrogen Storage Wang, Fanan; Xu, Jinming; Shao, Xianzhao ChemSusChem, Vol. 9, Issue 3 https://doi.org/10.1002/cssc.201501376	journal	January 2016
A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons Yang, Haiyan; Zhang, Chen; Gao, Peng Catalysis Science & Technology, Vol. 7, Issue 20 https://doi.org/10.1039/c7cy01403a	journal	January 2017
Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir( iii ) complex Takahashi, Hiroyuki; Kodama, Shintaro; Ishii, Youichi Dalton Transactions, Vol. 46, Issue 36 https://doi.org/10.1039/c7dt02528a	journal	January 2017
The long and successful journey of electrochemically active amino acids. From fundamental adsorption studies to potential surface engineering tools. Dourado, AndrÉ H. B.; PastriÁN, FabiÁN C.; Torresi, Susana I. CÓRdoba De Anais da Academia Brasileira de Ciências, Vol. 90, Issue 1 suppl 1 https://doi.org/10.1590/0001-3765201720170434	journal	January 2018
Unambiguous hydrogenation of CO ₂ by coinage-metal hydride anions: an intuitive idea based on in silico experiments Habib, Md; Sarkar, Ritabrata; Biswas, Santu Physical Chemistry Chemical Physics, Vol. 21, Issue 14 https://doi.org/10.1039/c9cp00133f	journal	January 2019
A simple strategy for engineering heterostructures of Au nanoparticle-loaded metal–organic framework nanosheets to achieve plasmon-enhanced photocatalytic CO ₂ conversion under visible light Chen, Liyong; Wang, Yanxin; Yu, Fengyang Journal of Materials Chemistry A, Vol. 7, Issue 18 https://doi.org/10.1039/c9ta01840a	journal	January 2019
Catalytic Disproportionation of Formic Acid to Methanol by an Iridium Complex Immobilized on Bipyridine‐Periodic Mesoporous Organosilica Yamaguchi, Sho; Maegawa, Yoshifumi; Onishi, Naoya ChemCatChem, Vol. 11, Issue 19 https://doi.org/10.1002/cctc.201900999	journal	September 2019
The effect of ICT on CO2 emissions in emerging economies: does the level of income matters? Environmental Science and Pollution Research, Vol. 25, Issue 23, p. 22850-22860 https://doi.org/10.1007/s11356-018-2379-2	journal	May 2018
Formic Acid Manufacture: Carbon Dioxide Utilization Alternatives Rumayor, Marta; Dominguez-Ramos, Antonio; Irabien, Angel Applied Sciences, Vol. 8, Issue 6 https://doi.org/10.3390/app8060914	journal	June 2018
Orbital Interactions in Bi-Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO ₂ Reduction toward Formate Production Wen, Guobin; Lee, Dong Un; Ren, Bohua Advanced Energy Materials, Vol. 8, Issue 31 https://doi.org/10.1002/aenm.201802427	journal	September 2018
From Ruthenium to Iron and Manganese-A Mechanistic View on Challenges and Design Principles of Base-Metal Hydrogenation Catalysts Zell, Thomas; Langer, Robert ChemCatChem, Vol. 10, Issue 9 https://doi.org/10.1002/cctc.201701722	journal	March 2018
Recent Trends, Benchmarking, and Challenges of Electrochemical Reduction of CO ₂ by Molecular Catalysts Elouarzaki, Kamal; Kannan, Vishvak; Jose, Vishal Advanced Energy Materials, Vol. 9, Issue 24 https://doi.org/10.1002/aenm.201900090	journal	May 2019
Progress and Perspective of Electrocatalytic CO ₂ Reduction for Renewable Carbonaceous Fuels and Chemicals Zhang, Wenjun; Hu, Yi; Ma, Lianbo Advanced Science, Vol. 5, Issue 1 https://doi.org/10.1002/advs.201700275	journal	September 2017
Ambiguous electrocatalytic CO ₂ reduction behaviour of a nickel bis(aldimino)pyridine pincer complex Narayanan, Remya; McKinnon, Meaghan; Reed, Blake R. Dalton Transactions, Vol. 45, Issue 39 https://doi.org/10.1039/c6dt01872f	journal	January 2016
Carbonate-Promoted Hydrogenation of Carbon Dioxide to Multicarbon Carboxylates Banerjee, Aanindeeta; Kanan, Matthew W. ACS Central Science, Vol. 4, Issue 5 https://doi.org/10.1021/acscentsci.8b00108	journal	April 2018
A new strategy for CO ₂ utilization with waste plastics: conversion of hydrogen carbonate into formate using polyvinyl chloride in water Lu, Lihui; Zhong, Heng; Wang, Tianfu Green Chemistry, Vol. 22, Issue 2 https://doi.org/10.1039/c9gc02484k	journal	January 2020
Iridium Complexes with Proton-Responsive Azole-Type Ligands as Effective Catalysts for CO ₂ Hydrogenation Suna, Yuki; Himeda, Yuichiro; Fujita, Etsuko ChemSusChem, Vol. 10, Issue 22 https://doi.org/10.1002/cssc.201701676	journal	November 2017
Base‐Free Hydrogenation of Carbon Dioxide to Methyl Formate with a Molecular Ruthenium‐Phosphine Catalyst Westhues, Niklas; Belleflamme, Maurice; Klankermayer, Jürgen ChemCatChem, Vol. 11, Issue 21 https://doi.org/10.1002/cctc.201900627	journal	March 2019
A review of plasma-assisted catalytic conversion of gaseous carbon dioxide and methane into value-added platform chemicals and fuels Puliyalil, Harinarayanan; Lašič Jurković, Damjan; Dasireddy, Venkata D. B. C. RSC Advances, Vol. 8, Issue 48 https://doi.org/10.1039/c8ra03146k	journal	January 2018
A new diphosphine-carbonyl complex of ruthenium: an efficient precursor for C–C and C–N bond coupling catalysis Mukherjee, Aparajita; Hrovat, David A.; Richmond, Michael G. Dalton Transactions, Vol. 47, Issue 30 https://doi.org/10.1039/c8dt01085d	journal	January 2018
A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates Schieweck, Benjamin G.; Westhues, Niklas F.; Klankermayer, Jürgen Chemical Science, Vol. 10, Issue 26 https://doi.org/10.1039/c8sc05230a	journal	January 2019
Mechanism of Formic Acid Disproportionation Catalyzed by an Iridium Complex Immobilized on Bipyridine‐Periodic Mesoporous Organosilica: A Case Study Based on Kinetics Analysis Yamaguchi, Sho; Hashimoto, Shunsuke Asian Journal of Organic Chemistry, Vol. 9, Issue 1 https://doi.org/10.1002/ajoc.201900692	journal	December 2019
Direct Photochemical C–H Carboxylation of Aromatic Diamines with CO2 under Electron-Donor- and Base-free Conditions Matsumoto, Takeshi; Uchijo, Daiki; Koike, Takuji Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-33060-3	journal	October 2018
Partial sulfuration-induced defect and interface tailoring on bismuth oxide for promoting electrocatalytic CO ₂ reduction Yang, Xuxiao; Deng, Peilin; Liu, Dongyu Journal of Materials Chemistry A, Vol. 8, Issue 5 https://doi.org/10.1039/c9ta11363k	journal	January 2020
Methylformate from CO 2 : an integrated process combining catalytic hydrogenation and reactive distillation Scott, Martin; Westhues, Christian G.; Kaiser, Teresa Green Chemistry, Vol. 21, Issue 23 https://doi.org/10.1039/c9gc03006a	journal	January 2019
Composition-tunable synthesis of “clean” syngas via a one-step synthesis of metal-free pyridinic-N-enriched self-supported CNTs: the synergy of electrocatalyst pyrolysis temperature and potential Liu, Kai-Hua; Zhong, Hai-Xia; Yang, Xiao-Yang Green Chemistry, Vol. 19, Issue 18 https://doi.org/10.1039/c7gc01095h	journal	January 2017
Two-dimensional nanomaterials for photocatalytic CO ₂ reduction to solar fuels Chen, Yong; Jia, Gan; Hu, Yingfei Sustainable Energy & Fuels, Vol. 1, Issue 9 https://doi.org/10.1039/c7se00344g	journal	January 2017
Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation Catalyzed by Iridium Complexes Bearing Pyridyl-pyrazole Ligands: Effect of an Electron-donating Substituent on the Pyrazole Ring on the Catalytic Activity and Durability Onishi, Naoya; Kanega, Ryoichi; Fujita, Etsuko Advanced Synthesis & Catalysis, Vol. 361, Issue 2 https://doi.org/10.1002/adsc.201801323	journal	November 2018
Catalytic reactivity of an iridium complex with a proton responsive N-donor ligand in CO ₂ hydrogenation to formate Gunasekar, Gunniya Hariyanandam; Yoon, Yeahsel; Baek, Il-hyun RSC Advances, Vol. 8, Issue 3 https://doi.org/10.1039/c7ra12343d	journal	January 2018
Atomic Ni Anchored Covalent Triazine Framework as High Efficient Electrocatalyst for Carbon Dioxide Conversion Lu, Chenbao; Yang, Jian; Wei, Shice Advanced Functional Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adfm.201806884	journal	March 2019
Sustainable fixation of CO ₂ into epoxides to form cyclic carbonates using hollow marigold CuCo ₂ O ₄ spinel microspheres as a robust catalyst Prasad, Divya; Patil, Komal N.; Bhanushali, Jayesh T. Catalysis Science & Technology, Vol. 9, Issue 16 https://doi.org/10.1039/c9cy00945k	journal	January 2019
Picolinamide‐Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability Kanega, Ryoichi; Onishi, Naoya; Wang, Lin Chemistry – A European Journal, Vol. 24, Issue 69 https://doi.org/10.1002/chem.201800428	journal	March 2018
Making a Splash in Homogeneous CO ₂ Hydrogenation: Elucidating the Impact of Solvent on Catalytic Mechanisms Wiedner, Eric S.; Linehan, John C. Chemistry – A European Journal, Vol. 24, Issue 64 https://doi.org/10.1002/chem.201801759	journal	July 2018
nBu ₄ NI-catalyzed oxidative cross-coupling of carbon dioxide, amines, and aryl ketones: access to O-β-oxoalkyl carbamates Peng, Youbin; Liu, Juan; Qi, Chaorong Chemical Communications, Vol. 53, Issue 18 https://doi.org/10.1039/c6cc09762f	journal	January 2017
A Ruthenium Complex-Porphyrin-Fullerene-Linked Molecular Pentad as an Integrative Photosynthetic Model Yamamoto, Masanori; Föhlinger, Jens; Petersson, Jonas Angewandte Chemie, Vol. 129, Issue 12 https://doi.org/10.1002/ange.201612456	journal	February 2017
Formic Acid Production Via Methane Peroxide Oxidation Over Oxalic Acid Activated Fe-MFI Catalysts Taran, Oxana P.; Yashnik, Svetlana A.; Boltenkov, Vadim V. Topics in Catalysis, Vol. 62, Issue 5-6 https://doi.org/10.1007/s11244-019-01151-8	journal	March 2019
Ir-catalyzed selective reduction of CO ₂ to the methoxy or formate level with HSiMe(OSiMe ₃ ) ₂ Guzmán, Jefferson; García-Orduña, Pilar; Polo, Víctor Catalysis Science & Technology, Vol. 9, Issue 11 https://doi.org/10.1039/c8cy02353k	journal	January 2019
An effective amino acid-assisted growth of ultrafine palladium nanocatalysts toward superior synergistic catalysis for hydrogen generation from formic acid Hong, Cheng-Bin; Zhu, De-Jie; Ma, Dong-Dong Inorganic Chemistry Frontiers, Vol. 6, Issue 4 https://doi.org/10.1039/c9qi00037b	journal	January 2019
Carbon Dioxide Insertion into Bridging Iron Hydrides: Kinetic and Mechanistic Studies: Carbon Dioxide Insertion into Bridging Iron Hydrides: Kinetic and Mechanistic Studies Hong, Dae Ho; Murray, Leslie J. European Journal of Inorganic Chemistry, Vol. 2019, Issue 15 https://doi.org/10.1002/ejic.201801404	journal	February 2019
Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities Vogiatzis, Konstantinos D.; Polynski, Mikhail V.; Kirkland, Justin K. Chemical Reviews, Vol. 119, Issue 4 https://doi.org/10.1021/acs.chemrev.8b00361	journal	October 2018
Future perspectives for formaldehyde: pathways for reductive synthesis and energy storage Heim, Leo E.; Konnerth, Hannelore; Prechtl, Martin H. G. Green Chemistry, Vol. 19, Issue 10 https://doi.org/10.1039/c6gc03093a	journal	January 2017
Mechanisms of catalytic reduction of CO 2 with heme and nonheme metal complexes Fukuzumi, Shunichi; Lee, Yong-Min; Ahn, Hyun S. Chemical Science, Vol. 9, Issue 28 https://doi.org/10.1039/c8sc02220h	journal	January 2018
Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system Singh, Ashish Kumar; Singh, Suryabhan; Kumar, Abhinav Catalysis Science & Technology, Vol. 6, Issue 1 https://doi.org/10.1039/c5cy01276g	journal	January 2016
Enhancing C–C bond formation by surface strain: a computational investigation for C2 and C3 intermediate formation on strained Cu surfaces Chan, Yu-Te; Huang, I-Shou; Tsai, Ming-Kang Physical Chemistry Chemical Physics, Vol. 21, Issue 41 https://doi.org/10.1039/c9cp02977j	journal	January 2019
Mechanistic insight into electroreduction of carbon dioxide on FeN _x ( x = 0–4) embedded graphene Zhao, Tingting; Tian, Yu; Wang, Yuelin Physical Chemistry Chemical Physics, Vol. 21, Issue 42 https://doi.org/10.1039/c9cp03370j	journal	January 2019
Kinetics and mechanisms of catalytic water oxidation Fukuzumi, Shunichi; Lee, Yong-Min; Nam, Wonwoo Dalton Transactions, Vol. 48, Issue 3 https://doi.org/10.1039/c8dt04341h	journal	January 2019
Recent Advances in Power-to-X Technology for the Production of Fuels and Chemicals Rego de Vasconcelos, Bruna; Lavoie, Jean-Michel Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00392	journal	June 2019
Tandem copper hydride–Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen Romero, Erik A.; Zhao, Tianxiang; Nakano, Ryo Nature Catalysis, Vol. 1, Issue 10 https://doi.org/10.1038/s41929-018-0140-3	journal	October 2018
Bi ₂ O ₂ CO ₃ Nanosheets as Electrocatalysts for Selective Reduction of CO ₂ to Formate at Low Overpotential Lv, Weixin; Bei, Jingjing; Zhang, Rui ACS Omega, Vol. 2, Issue 6 https://doi.org/10.1021/acsomega.7b00437	journal	June 2017
Catalytic hydrogenation of CO ₂ at a structurally rigidified cobalt center Choi, Jonghoon; Lee, Yunho Inorganic Chemistry Frontiers, Vol. 7, Issue 9 https://doi.org/10.1039/c9qi01431d	journal	January 2020
Mechanistic insights into HCO ₂ H dehydrogenation and CO ₂ hydrogenation catalyzed by Ir(Cp*) containing tetrahydroxy bipyrimidine ligand: the role of sodium and proton shuttle Wonglakhon, Tanakorn; Surawatanawong, Panida Dalton Transactions, Vol. 47, Issue 47 https://doi.org/10.1039/c8dt03283a	journal	January 2018
Carbon Vacancies in a Melon Polymeric Matrix Promote Photocatalytic Carbon Dioxide Conversion Yang, Pengju; Zhuzhang, Hangyu; Wang, Ruirui Angewandte Chemie International Edition, Vol. 58, Issue 4 https://doi.org/10.1002/anie.201810648	journal	January 2019
Enhanced Liquid Fuel Production from CO ₂ Hydrogenation: Catalytic Performance of Bimetallic Catalysts over a Two-Stage Reactor System Guo, Lisheng; Cui, Yu; Zhang, Peipei ChemistrySelect, Vol. 3, Issue 48 https://doi.org/10.1002/slct.201803335	journal	December 2018
A CO ₂ -induced ROCO ₂ Na/ROCO ₂ H buffer solution promoted the carboxylative cyclization of propargyl alcohol to synthesize cyclic carbonates Yan, Shaorui; Zhou, Ruinian; Han, Feng Catalysis Science & Technology, Vol. 10, Issue 3 https://doi.org/10.1039/c9cy02311a	journal	January 2020
Hydrogenation of CO ₂ to Formate with H ₂ : Transition Metal Free Catalyst Based on a Lewis Pair Zhao, Tianxiang; Hu, Xingbang; Wu, Youting Angewandte Chemie International Edition, Vol. 58, Issue 3 https://doi.org/10.1002/anie.201809634	journal	November 2018
Recent Advances in Palladium-Catalyzed Carboxylation with CO ₂: Recent Advances in Palladium-Catalyzed Carboxylation with CO ₂ Song, Jian; Liu, Qing; Liu, Hui European Journal of Organic Chemistry, Vol. 2018, Issue 6 https://doi.org/10.1002/ejoc.201701436	journal	January 2018
3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2 Coordination and Reduction and Formic Acid Dehydrogenation van de Watering, Fenna; Heijtbrink, Nicol; van der Vlugt, Jarl Inorganics, Vol. 5, Issue 4 https://doi.org/10.3390/inorganics5040073	journal	October 2017
Development of an Iridium-Based Catalyst for High-Pressure Evolution of Hydrogen from Formic Acid Iguchi, Masayuki; Himeda, Yuichiro; Manaka, Yuichi ChemSusChem, Vol. 9, Issue 19 https://doi.org/10.1002/cssc.201600697	journal	August 2016
Closing the carbon cycle to maximise climate change mitigation: power-to-methanol vs. power-to-direct air capture Daggash, H. A.; Patzschke, C. F.; Heuberger, C. F. Sustainable Energy & Fuels, Vol. 2, Issue 6 https://doi.org/10.1039/c8se00061a	journal	January 2018
Strategies for Designing Nanoparticles for Electro‐ and Photocatalytic CO ₂ Reduction Choi, Ji Yong; Choi, Woong; Park, Joon Woo Chemistry – An Asian Journal, Vol. 15, Issue 2 https://doi.org/10.1002/asia.201901533	journal	December 2019
1,3-N,O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles Drover, Marcus W.; Love, Jennifer A.; Schafer, Laurel L. Chemical Society Reviews, Vol. 46, Issue 10 https://doi.org/10.1039/c6cs00715e	journal	January 2017
Homogeneous Catalytic Reduction of CO ₂ with Silicon‐Hydrides, State of the Art Fernández‐Alvarez, Francisco J.; Oro, Luis A. ChemCatChem, Vol. 10, Issue 21 https://doi.org/10.1002/cctc.201800699	journal	July 2018
Catalytic transformation of functionalized carboxylic acids using multifunctional rhenium complexes Naruto, Masayuki; Agrawal, Santosh; Toda, Katsuaki Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-03436-y	journal	June 2017
Selective production of aromatics from CO ₂ Xu, Yuebing; Shi, Chengming; Liu, Bing Catalysis Science & Technology, Vol. 9, Issue 3 https://doi.org/10.1039/c8cy02024h	journal	January 2019
Covalently linking CuInS ₂ quantum dots with a Re catalyst by click reaction for photocatalytic CO ₂ reduction Huang, Jing; Gatty, Mélina Gilbert; Xu, Bo Dalton Transactions, Vol. 47, Issue 31 https://doi.org/10.1039/c8dt01631c	journal	January 2018
New horizon in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO ₂ into hydrocarbon chemicals and fuels Zhou, Wei; Cheng, Kang; Kang, Jincan Chemical Society Reviews, Vol. 48, Issue 12 https://doi.org/10.1039/c8cs00502h	journal	January 2019
Catalysis of Carbon Dioxide Photoreduction on Nanosheets: Fundamentals and Challenges Sun, Zhenyu; Talreja, Neetu; Tao, Hengcong Angewandte Chemie International Edition, Vol. 57, Issue 26 https://doi.org/10.1002/anie.201710509	journal	May 2018
Homogeneous Light-Driven Catalytic Direct Carboxylation with CO ₂ Tan, Fen; Yin, Guoyin Chinese Journal of Chemistry, Vol. 36, Issue 6 https://doi.org/10.1002/cjoc.201800011	journal	April 2018
Electrochemical exfoliation from an industrial ingot: ultrathin metallic bismuth nanosheets for excellent CO ₂ capture and electrocatalytic conversion Wu, Dan; Shen, Xinquan; Liu, Jianwen Nanoscale, Vol. 11, Issue 45 https://doi.org/10.1039/c9nr07863k	journal	January 2019
Hydrogenation of CO ₂ to Formate with H ₂ : Transition Metal Free Catalyst Based on a Lewis Pair Zhao, Tianxiang; Hu, Xingbang; Wu, Youting Angewandte Chemie, Vol. 131, Issue 3 https://doi.org/10.1002/ange.201809634	journal	November 2018
Recent Progress in Semiconductor-Based Nanocomposite Photocatalysts for Solar-to-Chemical Energy Conversion Wang, Feifan; Li, Qi; Xu, Dongsheng Advanced Energy Materials, Vol. 7, Issue 23 https://doi.org/10.1002/aenm.201700529	journal	September 2017
From CO ₂ methanation to ambitious long-chain hydrocarbons: alternative fuels paving the path to sustainability Marques Mota, Filipe; Kim, Dong Ha Chemical Society Reviews, Vol. 48, Issue 1 https://doi.org/10.1039/c8cs00527c	journal	January 2019
Nanofibrous rhodium with a new morphology for the hydrogenation of CO ₂ to formate Zahedifar, Mahboobeh; Zhiani, Rahele; Sadeghzadeh, Seyed Mohsen New Journal of Chemistry, Vol. 43, Issue 11 https://doi.org/10.1039/c8nj05228j	journal	January 2019
Single‐Site Ruthenium Pincer Complex Knitted into Porous Organic Polymers for Dehydrogenation of Formic Acid Wang, Xinbo; Ling, Eleanor Ang Pei; Guan, Chao ChemSusChem, Vol. 11, Issue 20 https://doi.org/10.1002/cssc.201801980	journal	September 2018
Mechanistic Considerations on Homogeneously Catalyzed Formic Acid Dehydrogenation: Mechanistic Considerations on Homogeneously Catalyzed Formic Acid Dehydrogenation Iglesias, Manuel; Oro, Luis A. European Journal of Inorganic Chemistry, Vol. 2018, Issue 20-21 https://doi.org/10.1002/ejic.201800159	journal	April 2018
Cooperative Catalysis of Nickel and Nickel Oxide for Efficient Reduction of CO ₂ to CH ₄ Bi, Qingyuan; Huang, Xieyi; Yin, Guoheng ChemCatChem, Vol. 11, Issue 4 https://doi.org/10.1002/cctc.201801896	journal	January 2019
Biomimetic heterobimetallic architecture of Ni( ii ) and Fe( ii ) for CO ₂ hydrogenation in aqueous media. A DFT study Shiekh, Bilal Ahmad RSC Advances, Vol. 9, Issue 57 https://doi.org/10.1039/c9ra07139c	journal	January 2019
Rhenium‐Loaded TiO 2 : A Highly Versatile and Chemoselective Catalyst for the Hydrogenation of Carboxylic Acid Derivatives and the N‐Methylation of Amines Using H 2 and CO 2 Toyao, Takashi; Siddiki, S. M. A. H.; Morita, Yoshitsugu Chemistry – A European Journal, Vol. 23, Issue 59 https://doi.org/10.1002/chem.201702801	journal	September 2017
Oxygen vacancies confined in Co ₃ O ₄ quantum dots for promoting oxygen evolution electrocatalysis Tong, Yun; Mao, Hainiao; Xu, Yanglei Inorganic Chemistry Frontiers, Vol. 6, Issue 8 https://doi.org/10.1039/c9qi00325h	journal	January 2019
Direct Synthesis of Methyl Formate from CO ₂ With Phosphine‐Based Polymer‐Bound Ru Catalysts Sun, Ruiyan; Kann, Anna; Hartmann, Heinrich ChemSusChem, Vol. 12, Issue 14 https://doi.org/10.1002/cssc.201900808	journal	May 2019
Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand Lu, Sheng-Mei; Wang, Zhijun; Wang, Jijie Green Chemistry, Vol. 20, Issue 8 https://doi.org/10.1039/c8gc00495a	journal	January 2018
Artificial photosynthesis of methanol from carbon dioxide and water via a Nile red-embedded TiO ₂ photocathode Jia, Yongjian; Xu, Yanjie; Nie, Rong Journal of Materials Chemistry A, Vol. 5, Issue 11 https://doi.org/10.1039/c6ta10231j	journal	January 2017
Liquid phase hydrogenation of CO ₂ to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide Mitchell, Claire E.; Terranova, Umberto; Alshibane, Ihfaf New Journal of Chemistry, Vol. 43, Issue 35 https://doi.org/10.1039/c9nj02114k	journal	January 2019
The renaissance of the Sabatier reaction and its applications on Earth and in space Vogt, Charlotte; Monai, Matteo; Kramer, Gert Jan Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0244-4	journal	March 2019
Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO2 Hydrogenation: Integrated Reaction and Catalyst Separation for CO2-Scrubbing Solutions Scott, Martin; Blas Molinos, Beatriz; Westhues, Christian RWTH Aachen University https://doi.org/10.18154/rwth-2017-04273	text	January 2017
Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity Sánchez, Práxedes; Hernández-Juárez, Martín; Rendón, Nuria Dalton Transactions, Vol. 47, Issue 46 https://doi.org/10.1039/c8dt03951h	journal	January 2018
l -Cysteine electrooxidation in alkaline and acidic media: a combined spectroelectrochemical and computational study Dourado, André H. B.; de Lima Batista, Ana P.; Oliveira-Filho, Antonio G. S. RSC Advances, Vol. 7, Issue 13 https://doi.org/10.1039/c6ra26576f	journal	January 2017
Atomic origins of high electrochemical CO ₂ reduction efficiency on nanoporous gold Zhang, Weiqing; He, Jia; Liu, Siyu Nanoscale, Vol. 10, Issue 18 https://doi.org/10.1039/c8nr00642c	journal	January 2018
Half‐sandwich ruthenium complexes with S chiff base ligands bearing a hydroxyl group: Preparation, characterization and catalytic activities Jia, Wei‐Guo; Wang, Zhi‐Bao; Zhi, Xue‐Ting Applied Organometallic Chemistry, Vol. 34, Issue 1 https://doi.org/10.1002/aoc.5289	journal	November 2019
Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO ₂ Hydrogenation Processes Álvarez, Andrea; Bansode, Atul; Urakawa, Atsushi Chemical Reviews, Vol. 117, Issue 14 https://doi.org/10.1021/acs.chemrev.6b00816	journal	May 2017
CO2 Activation on Cobalt Surface in the Presence of H2O: An Ambient-Pressure X-ray Photoelectron Spectroscopy Study Liu, Qiang; Han, Yong; Cai, Jun Catalysis Letters, Vol. 148, Issue 6 https://doi.org/10.1007/s10562-018-2362-z	journal	March 2018
Current progress in electrocatalytic carbon dioxide reduction to fuels on heterogeneous catalysts Liu, Anmin; Gao, Mengfan; Ren, Xuefeng Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/c9ta11966c	journal	January 2020
Sequential hydrogen production system from formic acid and H ₂ /CO ₂ separation under high-pressure conditions Iguchi, Masayuki; Chatterjee, Maya; Onishi, Naoya Sustainable Energy & Fuels, Vol. 2, Issue 8 https://doi.org/10.1039/c8se00087e	journal	January 2018
Towards Sustainable Production of Formic Acid Bulushev, Dmitri A.; Ross, Julian R. H. ChemSusChem, Vol. 11, Issue 5 https://doi.org/10.1002/cssc.201702075	journal	February 2018
Hydrogenation of CO ₂ to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water Rohmann, Kai; Kothe, Jens; Haenel, Matthias W. Angewandte Chemie International Edition, Vol. 55, Issue 31 https://doi.org/10.1002/anie.201603878	journal	June 2016
Structural inhomogeneity as a factor promoting the homogenous catalysis of CO ₂ hydrogenation by (PMe ₃ ) ₄ RuH ₂ Xia, Guang-Jie; Liu, Jianwen; Liu, Zhi-Feng Physical Chemistry Chemical Physics, Vol. 21, Issue 35 https://doi.org/10.1039/c9cp03288f	journal	January 2019
Mesoporous Silica‐Encaged Ultrafine Bimetallic Nanocatalysts for CO ₂ Hydrogenation to Formates Sun, Qiming; Fu, Xinpu; Si, Rui ChemCatChem, Vol. 11, Issue 20 https://doi.org/10.1002/cctc.201901167	journal	September 2019
A copper-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide using molecular oxygen as the oxidant Xiong, Wenfang; Qi, Chaorong; Guo, Tianzuo Green Chemistry, Vol. 19, Issue 7 https://doi.org/10.1039/c6gc03465a	journal	January 2017
CO ₂ capture by amines in aqueous media and its subsequent conversion to formate with reusable ruthenium and iron catalysts Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos Green Chemistry, Vol. 18, Issue 21 https://doi.org/10.1039/c6gc01165a	journal	January 2016
Toward ideal carbon dioxide functionalization Yang, Yang; Lee, Ji-Woong Chemical Science, Vol. 10, Issue 14 https://doi.org/10.1039/c8sc05539d	journal	January 2019
Synthesis of Carboxylic Acids and Esters from CO2 Wu, Xiao-Feng; Zheng, Feng Topics in Current Chemistry, Vol. 375, Issue 1 https://doi.org/10.1007/s41061-016-0091-6	journal	December 2016
Bulk gold catalyzes hydride transfer in the Cannizzaro and related reactions Fecteau, Kristopher M.; Gould, Ian R.; Williams, Lynda B. New Journal of Chemistry, Vol. 43, Issue 48 https://doi.org/10.1039/c9nj04029c	journal	January 2019
Kinetic Studies on Formic Acid Dehydrogenation Catalyzed by an Iridium Complex towards Insights into the Catalytic Mechanism of High-Pressure Hydrogen Gas Production Iguchi, Masayuki; Zhong, Heng; Himeda, Yuichiro Chemistry - A European Journal, Vol. 23, Issue 67 https://doi.org/10.1002/chem.201702969	journal	September 2017
Reaction mechanism of the selective reduction of CO ₂ to CO by a tetraaza [Co ^II N ₄ H] ²⁺ complex in the presence of protons Garza, Alejandro J.; Pakhira, Srimanta; Bell, Alexis T. Physical Chemistry Chemical Physics, Vol. 20, Issue 37 https://doi.org/10.1039/c8cp01963k	journal	January 2018
Recent Advances in Catalysis with Transition-Metal Pincer Compounds Valdés, Hugo; García-Eleno, Marco A.; Canseco-Gonzalez, Daniel ChemCatChem, Vol. 10, Issue 15 https://doi.org/10.1002/cctc.201702019	journal	May 2018
Carbon nitrides and metal nanoparticles: from controlled synthesis to design principles for improved photocatalysis Teixeira, Ivo F.; Barbosa, Eduardo C. M.; Tsang, Shik Chi Edman Chemical Society Reviews, Vol. 47, Issue 20 https://doi.org/10.1039/c8cs00479j	journal	January 2018
Comparative Performance Evaluation of Self-Basifying Direct Formate Fuel Cells Sun, Xianda; Li, Yinshi; An, Liang Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0751912jes	journal	January 2019
Reduction of CO ₂ by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate Roy, Lisa; Al-Afyouni, Malik H.; DeRosha, Daniel E. Chemical Science, Vol. 10, Issue 3 https://doi.org/10.1039/c8sc02599a	journal	January 2019
Hydroboration of carbon dioxide enabled by molecular zinc dihydrides Wang, Xiaoming; Chang, Kejian; Xu, Xin Dalton Transactions, Vol. 49, Issue 22 https://doi.org/10.1039/d0dt01090a	journal	January 2020
Acceptorless dehydrogenative coupling reactions with alcohols over heterogeneous catalysts Hakim Siddiki, S. M. A.; Toyao, Takashi; Shimizu, Ken-ichi Green Chemistry, Vol. 20, Issue 13 https://doi.org/10.1039/c8gc00451j	journal	January 2018
A review on photocatalytic CO ₂ reduction using perovskite oxide nanomaterials Zeng, Sheng; Kar, Piyush; Thakur, Ujwal Kumar Nanotechnology, Vol. 29, Issue 5 https://doi.org/10.1088/1361-6528/aa9fb1	journal	January 2018
Hydrogen Production from Formic Acid over Au Catalysts Supported on Carbon: Comparison with Au Catalysts Supported on SiO2 and Al2O3 Bulushev, Dmitri A.; Sobolev, Vladimir I.; Pirutko, Larisa V. Catalysts, Vol. 9, Issue 4 https://doi.org/10.3390/catal9040376	journal	April 2019
1D/2D TiO ₂ /MoS ₂ Hybrid Nanostructures for Enhanced Photocatalytic CO ₂ Reduction Xu, Feiyan; Zhu, Bicheng; Cheng, Bei Advanced Optical Materials, Vol. 6, Issue 23 https://doi.org/10.1002/adom.201800911	journal	October 2018
Carbodiimides as catalysts for the reduction of CO ₂ with boranes Ramos, Alberto; Antiñolo, Antonio; Carrillo-Hermosilla, Fernando Chemical Communications, Vol. 54, Issue 37 https://doi.org/10.1039/c8cc02139b	journal	January 2018
Active Sites in Heterogeneous Catalytic Reaction on Metal and Metal Oxide: Theory and Practice Pan, Yanbo; Shen, Xiaochen; Yao, Libo Catalysts, Vol. 8, Issue 10 https://doi.org/10.3390/catal8100478	journal	October 2018
Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry Klankermayer, Jürgen; Wesselbaum, Sebastian; Beydoun, Kassem Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201507458	journal	May 2016
Deciphering key intermediates in the transformation of carbon dioxide into heterocyclic products Huang, Rui; Rintjema, Jeroen; González-Fabra, Joan Nature Catalysis, Vol. 2, Issue 1 https://doi.org/10.1038/s41929-018-0189-z	journal	December 2018
Pyrene-functionalized polymeric carbon nitride with promoted aqueous–organic biphasic photocatalytic CO ₂ reduction Gong, Xuezhong; Yu, Sijia; Guan, Meili Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c8ta09801h	journal	January 2019
Strategic Preparation of Efficient and Durable NiCo Alloy Supported N‐Doped Porous Graphene as an Oxygen Evolution Electrocatalyst: A Theoretical and Experimental Investigation Singh, Santosh K.; Kumar, Deepak; Dhavale, Vishal M. Advanced Materials Interfaces, Vol. 3, Issue 20 https://doi.org/10.1002/admi.201600532	journal	August 2016
Cu-Mo2C/MCM-41: An Efficient Catalyst for the Selective Synthesis of Methanol from CO2 Liu, Xiaoran; Song, Yingquan; Geng, Wenhao Catalysts, Vol. 6, Issue 5 https://doi.org/10.3390/catal6050075	journal	May 2016
Ligand Effect on the Stability of Water‐Soluble Iridium Catalysts for High‐Pressure Hydrogen Gas Production by Dehydrogenation of Formic Acid Iguchi, Masayuki; Onishi, Naoya; Himeda, Yuichiro ChemPhysChem, Vol. 20, Issue 10 https://doi.org/10.1002/cphc.201900137	journal	March 2019
Catalytic CO 2 Reduction with Boron‐ and Aluminum Hydrides Franz, Daniel; Jandl, Christian; Stark, Claire ChemCatChem, Vol. 11, Issue 21 https://doi.org/10.1002/cctc.201901255	journal	August 2019
Experimental parameters affecting the photocatalytic reduction performance of CO ₂ to methanol: A review Lais, Abul; Gondal, M. A.; Dastageer, M. A. International Journal of Energy Research, Vol. 42, Issue 6 https://doi.org/10.1002/er.3965	journal	January 2018
Mechanism of Cobalt-Catalyzed CO Hydrogenation: 2. Fischer–Tropsch Synthesis Chen, Wei; Filot, Ivo A. W.; Pestman, Robert ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02758	journal	October 2017
Techno-Economic Optimization of CO2-to-Methanol with Solid-Oxide Electrolyzer Zhang, Hanfei; Wang, Ligang; Van herle, Jan Energies, Vol. 12, Issue 19 https://doi.org/10.3390/en12193742	journal	September 2019

Similar Records

Sr- and Mn-doped LaAlO_3-δ for solar thermochemical H₂ and CO production

Journal Article · Tue Jan 01 00:00:00 EST 2013 · Energy & Environmental Science · OSTI ID:1214520

McDaniel, Anthony H.; Miller, Elizabeth C.; Arifin, Darwin; +5 more

Tandem and Hybrid Processes for Carbon Dioxide Utilization

Journal Article · Fri Jan 01 00:00:00 EST 2021 · Joule · OSTI ID:1214520

Overa, Sean; Feric, Tony G.; Park, Ah-Hyung Alissa; +1 more

Reduction of CO/sub 2/ to methanol and methane by photo and dark reactions on semiconductor electrodes. Annual report, February 15, 1984-February 15, 1985

Technical Report · Fri Mar 01 00:00:00 EST 1985 · OSTI ID:1214520

Frese, K W; Summers, D P

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

Citation Formats

References (285)

Cited By (221)

Similar Records

Related Subjects

Title: CO₂ hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO₂ reduction