Low Temperature Propane Oxidation over Co3O4 based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability

Ren, Zheng; Wu, Zili; Gao, Puxian; Song, Wenqiao; Xiao, Wen; Guo, Yanbing; Ding, Jun; Suib, Steven L.; Gao, Pu-Xian

doi:10.1016/j.apcatb.2015.04.021

Title: Low Temperature Propane Oxidation over Co₃O₄ based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability

Abstract

Low temperature propane oxidation has been achieved by Co₃O₄-based nano-array catalysts featuring low catalytic materials loading. The Ni doping into the Co₃O₄ lattice has led to enhanced reaction kinetics at low temperature by promoting the surface lattice oxygen activity. In situ DRIFTS investigation in tandem with isotopic oxygen exchange reveals that the propane oxidation proceeds via Mars-van Krevelen mechanism where surface lattice oxygen acts as the active site whereas O₂ in the reaction feed does not directly participate in CO₂ formation. The Ni doping promotes the formation of less stable carbonates on the surface to facilitate the CO₂ desorption. The thermal stability of Ni doped Co₃O₄ decreases with increased Ni concentration while catalytic activity increases. A balance between enhanced activity and compromised thermal stability shall be considered in the Ni doped Co₃O₄ nano-array catalysts for low temperature hydrocarbon oxidation. This study provides useful and timely guidance for rational catalyst design toward low temperature catalytic oxidation.

Authors:

Ren, Zheng ^[1]; Wu, Zili ^[2]; Gao, Puxian ^[1]; Song, Wenqiao ^[1]; Xiao, Wen ^[3]; Guo, Yanbing ^[1]; Ding, Jun ^[3]; Suib, Steven L. ^[1]; Gao, Pu-Xian ^[1]

Univ. of Connecticut, Storrs, CT (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Univ. of Singapore (Singapore)

Publication Date:: Tue Jun 09 00:00:00 EDT 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1213987

Alternate Identifier(s):: OSTI ID: 1398071

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Applied Catalysis B: Environmental

Additional Journal Information:: Journal Volume: 180; Journal Issue: 1; Journal ID: ISSN 0926-3373

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Ren, Zheng, Wu, Zili, Gao, Puxian, Song, Wenqiao, Xiao, Wen, Guo, Yanbing, Ding, Jun, Suib, Steven L., and Gao, Pu-Xian. Low Temperature Propane Oxidation over Co3O4 based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability.  United States: N. p., 2015. 
        Web.  doi:10.1016/j.apcatb.2015.04.021.

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                    Ren, Zheng, Wu, Zili, Gao, Puxian, Song, Wenqiao, Xiao, Wen, Guo, Yanbing, Ding, Jun, Suib, Steven L., & Gao, Pu-Xian. Low Temperature Propane Oxidation over Co3O4 based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability.  United States.  https://doi.org/10.1016/j.apcatb.2015.04.021

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                    Ren, Zheng, Wu, Zili, Gao, Puxian, Song, Wenqiao, Xiao, Wen, Guo, Yanbing, Ding, Jun, Suib, Steven L., and Gao, Pu-Xian. 2015.  
        "Low Temperature Propane Oxidation over Co3O4 based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability".  United States.  https://doi.org/10.1016/j.apcatb.2015.04.021.  https://www.osti.gov/servlets/purl/1213987.

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@article{osti_1213987,

  title        = {Low Temperature Propane Oxidation over Co3O4 based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability},

  author       = {Ren, Zheng and Wu, Zili and Gao, Puxian and Song, Wenqiao and Xiao, Wen and Guo, Yanbing and Ding, Jun and Suib, Steven L. and Gao, Pu-Xian},

  abstractNote = {Low temperature propane oxidation has been achieved by Co3O4-based nano-array catalysts featuring low catalytic materials loading. The Ni doping into the Co3O4 lattice has led to enhanced reaction kinetics at low temperature by promoting the surface lattice oxygen activity. In situ DRIFTS investigation in tandem with isotopic oxygen exchange reveals that the propane oxidation proceeds via Mars-van Krevelen mechanism where surface lattice oxygen acts as the active site whereas O2 in the reaction feed does not directly participate in CO2 formation. The Ni doping promotes the formation of less stable carbonates on the surface to facilitate the CO2 desorption. The thermal stability of Ni doped Co3O4 decreases with increased Ni concentration while catalytic activity increases. A balance between enhanced activity and compromised thermal stability shall be considered in the Ni doped Co3O4 nano-array catalysts for low temperature hydrocarbon oxidation. This study provides useful and timely guidance for rational catalyst design toward low temperature catalytic oxidation.},

  doi          = {10.1016/j.apcatb.2015.04.021},

  url          = {https://www.osti.gov/biblio/1213987},
  journal      = {Applied Catalysis B: Environmental},

  issn         = {0926-3373},

  number       = 1,

  volume       = 180,

  place        = {United States},

  year         = {Tue Jun 09 00:00:00 EDT 2015},

  month        = {Tue Jun 09 00:00:00 EDT 2015}

}

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Title: Low Temperature Propane Oxidation over Co3O4 based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability

Abstract

Citation Formats

Emissions of unregulated pollutants from European gasoline and diesel passenger cars journal, October 2006

C2-C5 hydrocarbons in the Los Angeles atmosphere journal, December 1968

Measurement of Emissions from Air Pollution Sources. 5. C 1 −C 32 Organic Compounds from Gasoline-Powered Motor Vehicles journal, March 2002

Why Rhodium in Automotive Three-Way Catalysts? journal, August 1994

Modeling of Three-Way-Catalyst Monolith Converters with Microkinetics and Diffusion in the Washcoat journal, August 2004

Catalytic automotive exhaust aftertreatment journal, January 1997

Three-way catalyst emissions control technologies for spark-ignition engines—recent trends and future developments journal, May 2007

MnOx-CeO2 mixed oxides for the low-temperature oxidation of diesel soot journal, April 2006

Total Oxidation of Carbon Monoxide and Methane over Transition Metal Fluorite Oxide Composite Catalysts journal, May 1995

Low temperature oxidation of carbon monoxide: the influence of water and oxygen on the reactivity of a Co3O4 powder surface journal, April 2004

On the structure dependence of CO oxidation over CeO2 nanocrystals with well-defined surface planes journal, January 2012

Manganese Oxide Mesoporous Structures: Mixed-Valent Semiconducting Catalysts journal, May 1997

Interface-Confined Oxide Nanostructures for Catalytic Oxidation Reactions journal, March 2013

Highly Active and Stable Co 3 O 4 /ZSM-5 Catalyst for Propane Oxidation: Effect of the Preparation Method journal, April 2013

Characterization of manganese and iron oxides as combustion catalysts for propane and propene journal, July 1998

Total Oxidation of Hydrocarbons on Perovskite Oxides journal, December 1992

Catalytic combustion of methane over various perovskite-type oxides journal, January 1986

Strontium-Doped Perovskites Rival Platinum Catalysts for Treating NOx in Simulated Diesel Exhaust journal, March 2010

Methane combustion on Mg-doped LaMnO3 perovskite catalysts journal, April 1999

Perovskite catalysts for methane combustion journal, December 1990

Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis journal, August 2014

Mesoporous Co 3 O 4 with Controlled Porosity: Inverse Micelle Synthesis and High-Performance Catalytic CO Oxidation at −60 °C journal, July 2014

Low-temperature oxidation of CO catalysed by Co3O4 nanorods journal, April 2009

Robust 3-D configurated metal oxide nano-array based monolithic catalysts with ultrahigh materials usage efficiency and catalytic performance tunability journal, September 2013

Mechanical-Agitation-Assisted Growth of Large-Scale and Uniform ZnO Nanorod Arrays within 3D Multichannel Monolithic Substrates journal, July 2013

Single crystalline brookite titanium dioxide nanorod arrays rooted on ceramic monoliths: a hybrid nanocatalyst support with ultra-high surface area and thermal stability journal, January 2013

Nonprecious catalytic honeycombs structured with three dimensional hierarchical Co3O4 nano-arrays for high performance nitric oxide oxidation journal, January 2013

Monolithically Integrated Spinel M x Co 3− x O 4 (M=Co, Ni, Zn) Nanoarray Catalysts: Scalable Synthesis and Cation Manipulation for Tunable Low-Temperature CH 4 and CO Oxidation journal, May 2014

Mesoporous Co 3 O 4 and CoO@C Topotactically Transformed from Chrysanthemum-like Co(CO 3 ) 0.5 (OH)·0.11H 2 O and Their Lithium-Storage Properties journal, December 2011

Porous Co3O4 nanowires derived from long Co(CO3)0.5(OH)·0.11H2O nanowires with improved supercapacitive properties journal, January 2012

Hierarchical Nanoarchitectures: 3D Hierarchical Co 3 O 4 Twin-Spheres with an Urchin-Like Structure: Large-Scale Synthesis, Multistep-Splitting Growth, and Electrochemical Pseudocapacitors (Adv. Funct. Mater. 19/2012) journal, October 2012

Morphology-directed synthesis of Co 3 O 4 nanotubes based on modified Kirkendall effect and its application in CH 4 combustion journal, January 2012

In situ FT-IR and TPD-MS study of carbon monoxide oxidation over a CeO2/Co3O4 catalyst journal, March 2013

Identification of the Active Sites for CO and C 3 H 8 Total Oxidation over Nanostructured CuO−CeO 2 and Co 3 O 4 −CeO 2 Catalysts journal, May 2008

IR study of polycrystalline ceria properties in oxidised and reduced states journal, April 1999

Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part II: Oxidation states and surface species on Pd/CeO2 under reaction conditions, suggested reaction mechanism journal, January 2006

Structure Sensitivity of CO Oxidation on Co 3 O 4 : A DFT Study journal, November 2012

CO disproportionation at mild temperatures over partially reduced cerium oxide journal, January 1991

Mesoporous NiCo 2 O 4 Spinel: Influence of Calcination Temperature over Phase Purity and Thermal Stability journal, November 2009

The Raman spectra of Co 3 O 4 journal, March 1988

Facile hydrothermal synthesis of urchin-like NiCo2O4 spheres as efficient electrocatalysts for oxygen reduction reaction journal, May 2013

Highly stable Co3O4 nanoparticles-assembled microrods derived from MOF for efficient total propane oxidation journal, January 2020

Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis journal, November 2016

Monolithic LaBO 3 (B=Mn, Co or Ni)/Co 3 O 4 /cordierite Catalysts for o ‐Xylene Combustion journal, May 2019

Low temperature CO oxidation catalysed by flower-like Ni–Co–O: how physicochemical properties influence catalytic performance journal, January 2018

Facet‐Dependent Activity of Co 3 O 4 Catalyst for C 3 H 8 Combustion journal, October 2019

Nonprecious mixed oxide catalysts Co3AlO and Co2NiAlO derived from nanoflowerlike cobalt-based hydrotalcites for highly efficient oxidation of nitric oxide journal, January 2016

Decreasing Co3O4 Particle Sizes by Ammonia-Etching and Catalytic Oxidation of Propane journal, January 2017

Copper manganese oxide enhanced nanoarray-based monolithic catalysts for hydrocarbon oxidation journal, January 2018

Catalytic Glycolysis of Poly(ethylene terephthalate) Using Zinc and Cobalt Oxides Recycled from Spent Batteries journal, September 2019

Gaseous CO and toluene co-oxidation over monolithic core–shell Co 3 O 4 -based hetero-structured catalysts journal, January 2019

NaCl-induced nickel–cobalt inverse spinel structure for boosting hydrogen evolution from ethyl acetate and water journal, January 2019

Catalytic oxidation of propane over palladium alloyed with gold: an assessment of the chemical and intermediate species journal, January 2018

Oxidant free conversion of alcohols to nitriles over Ni-based catalysts journal, January 2019

Effect of Ce and La dopants in Co 3 O 4 nanorods on the catalytic activity of CO and C 3 H 6 oxidation journal, January 2019

Oxidant free conversion of alcohols to nitriles over Ni-based catalysts text, January 2019

Title: Low Temperature Propane Oxidation over Co₃O₄ based Nano-array Catalysts. Ni Dopant Effect, Reaction Mechanism and Structural Stability

Emissions of unregulated pollutants from European gasoline and diesel passenger cars
journal, October 2006

C2-C5 hydrocarbons in the Los Angeles atmosphere
journal, December 1968

Measurement of Emissions from Air Pollution Sources. 5. C ₁ −C ₃₂ Organic Compounds from Gasoline-Powered Motor Vehicles
journal, March 2002

Why Rhodium in Automotive Three-Way Catalysts?
journal, August 1994

Modeling of Three-Way-Catalyst Monolith Converters with Microkinetics and Diffusion in the Washcoat
journal, August 2004

Catalytic automotive exhaust aftertreatment
journal, January 1997

Three-way catalyst emissions control technologies for spark-ignition engines—recent trends and future developments
journal, May 2007

MnO_x-CeO₂ mixed oxides for the low-temperature oxidation of diesel soot
journal, April 2006

Total Oxidation of Carbon Monoxide and Methane over Transition Metal Fluorite Oxide Composite Catalysts
journal, May 1995

Low temperature oxidation of carbon monoxide: the influence of water and oxygen on the reactivity of a Co3O4 powder surface
journal, April 2004

On the structure dependence of CO oxidation over CeO2 nanocrystals with well-defined surface planes
journal, January 2012

Manganese Oxide Mesoporous Structures: Mixed-Valent Semiconducting Catalysts
journal, May 1997

Interface-Confined Oxide Nanostructures for Catalytic Oxidation Reactions
journal, March 2013

Highly Active and Stable Co ₃ O ₄ /ZSM-5 Catalyst for Propane Oxidation: Effect of the Preparation Method
journal, April 2013

Characterization of manganese and iron oxides as combustion catalysts for propane and propene
journal, July 1998

Total Oxidation of Hydrocarbons on Perovskite Oxides
journal, December 1992

Catalytic combustion of methane over various perovskite-type oxides
journal, January 1986

Strontium-Doped Perovskites Rival Platinum Catalysts for Treating NO_x in Simulated Diesel Exhaust
journal, March 2010

Methane combustion on Mg-doped LaMnO3 perovskite catalysts
journal, April 1999

Perovskite catalysts for methane combustion
journal, December 1990

Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis
journal, August 2014

Mesoporous Co ₃ O ₄ with Controlled Porosity: Inverse Micelle Synthesis and High-Performance Catalytic CO Oxidation at −60 °C
journal, July 2014

Low-temperature oxidation of CO catalysed by Co₃O₄ nanorods
journal, April 2009

Robust 3-D configurated metal oxide nano-array based monolithic catalysts with ultrahigh materials usage efficiency and catalytic performance tunability
journal, September 2013

Mechanical-Agitation-Assisted Growth of Large-Scale and Uniform ZnO Nanorod Arrays within 3D Multichannel Monolithic Substrates
journal, July 2013

Single crystalline brookite titanium dioxide nanorod arrays rooted on ceramic monoliths: a hybrid nanocatalyst support with ultra-high surface area and thermal stability
journal, January 2013

Nonprecious catalytic honeycombs structured with three dimensional hierarchical Co3O4 nano-arrays for high performance nitric oxide oxidation
journal, January 2013

Monolithically Integrated Spinel M _x Co _{3− x} O ₄ (M=Co, Ni, Zn) Nanoarray Catalysts: Scalable Synthesis and Cation Manipulation for Tunable Low-Temperature CH ₄ and CO Oxidation
journal, May 2014

Mesoporous Co ₃ O ₄ and CoO@C Topotactically Transformed from Chrysanthemum-like Co(CO ₃ ) _0.5 (OH)·0.11H ₂ O and Their Lithium-Storage Properties
journal, December 2011

Porous Co3O4 nanowires derived from long Co(CO3)0.5(OH)·0.11H2O nanowires with improved supercapacitive properties
journal, January 2012

Hierarchical Nanoarchitectures: 3D Hierarchical Co ₃ O ₄ Twin-Spheres with an Urchin-Like Structure: Large-Scale Synthesis, Multistep-Splitting Growth, and Electrochemical Pseudocapacitors (Adv. Funct. Mater. 19/2012)
journal, October 2012

Morphology-directed synthesis of Co ₃ O ₄ nanotubes based on modified Kirkendall effect and its application in CH ₄ combustion
journal, January 2012

In situ FT-IR and TPD-MS study of carbon monoxide oxidation over a CeO2/Co3O4 catalyst
journal, March 2013

Identification of the Active Sites for CO and C ₃ H ₈ Total Oxidation over Nanostructured CuO−CeO ₂ and Co ₃ O ₄ −CeO ₂ Catalysts
journal, May 2008

IR study of polycrystalline ceria properties in oxidised and reduced states
journal, April 1999

Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part II: Oxidation states and surface species on Pd/CeO2 under reaction conditions, suggested reaction mechanism
journal, January 2006

Structure Sensitivity of CO Oxidation on Co ₃ O ₄ : A DFT Study
journal, November 2012

CO disproportionation at mild temperatures over partially reduced cerium oxide
journal, January 1991

Mesoporous NiCo ₂ O ₄ Spinel: Influence of Calcination Temperature over Phase Purity and Thermal Stability
journal, November 2009

The Raman spectra of Co ₃ O ₄
journal, March 1988

Facile hydrothermal synthesis of urchin-like NiCo2O4 spheres as efficient electrocatalysts for oxygen reduction reaction
journal, May 2013

Highly stable Co3O4 nanoparticles-assembled microrods derived from MOF for efficient total propane oxidation
journal, January 2020

Nanostructured cerium oxide: preparation, characterization, and application in energy and environmental catalysis
journal, November 2016

Monolithic LaBO ₃ (B=Mn, Co or Ni)/Co ₃ O ₄ /cordierite Catalysts for o ‐Xylene Combustion
journal, May 2019

Low temperature CO oxidation catalysed by flower-like Ni–Co–O: how physicochemical properties influence catalytic performance
journal, January 2018

Facet‐Dependent Activity of Co ₃ O ₄ Catalyst for C ₃ H ₈ Combustion
journal, October 2019

Nonprecious mixed oxide catalysts Co3AlO and Co2NiAlO derived from nanoflowerlike cobalt-based hydrotalcites for highly efficient oxidation of nitric oxide
journal, January 2016

Decreasing Co3O4 Particle Sizes by Ammonia-Etching and Catalytic Oxidation of Propane
journal, January 2017

Copper manganese oxide enhanced nanoarray-based monolithic catalysts for hydrocarbon oxidation
journal, January 2018

Catalytic Glycolysis of Poly(ethylene terephthalate) Using Zinc and Cobalt Oxides Recycled from Spent Batteries
journal, September 2019

Gaseous CO and toluene co-oxidation over monolithic core–shell Co ₃ O ₄ -based hetero-structured catalysts
journal, January 2019

NaCl-induced nickel–cobalt inverse spinel structure for boosting hydrogen evolution from ethyl acetate and water
journal, January 2019

Catalytic oxidation of propane over palladium alloyed with gold: an assessment of the chemical and intermediate species
journal, January 2018

Oxidant free conversion of alcohols to nitriles over Ni-based catalysts
journal, January 2019

Effect of Ce and La dopants in Co ₃ O ₄ nanorods on the catalytic activity of CO and C ₃ H ₆ oxidation
journal, January 2019

Oxidant free conversion of alcohols to nitriles over Ni-based catalysts
text, January 2019