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Title: A new low-voltage plateau of Na3V2(PO4)(3) as an anode for Na-ion batteries

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c5cc00944h· OSTI ID:1211284

A low-voltage plateau at similar to 0.3 V is discovered for the deep sodiation of Na3V2(PO4)(3) by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na3V2(PO4)(3), thus turning it into a promising anode for Na-ion batteries.

Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DOE Contract Number:
DE-AR0000297TDD
OSTI ID:
1211284
Journal Information:
ChemComm, Vol. 51, Issue 29; ISSN 1359-7345
Country of Publication:
United States
Language:
English

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Cited By (33)

A High-Power Symmetric Na-Ion Pseudocapacitor journal August 2015
Prussian Blue@C Composite as an Ultrahigh-Rate and Long-Life Sodium-Ion Battery Cathode journal May 2016
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries journal January 2020
Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries journal August 2015
NASICON-Structured Materials for Energy Storage journal February 2017
Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries journal June 2017
Phosphate Framework Electrode Materials for Sodium Ion Batteries journal January 2017
Going Beyond Lithium Hybrid Capacitors: Proposing a New High-Performing Sodium Hybrid Capacitor System for Next-Generation Hybrid Vehicles Made with Bio-Inspired Activated Carbon journal January 2016
Commercial Prospects of Existing Cathode Materials for Sodium Ion Storage journal July 2017
Na-Ion Batteries for Large Scale Applications: A Review on Anode Materials and Solid Electrolyte Interphase Formation journal July 2017
Computational Studies of Electrode Materials in Sodium-Ion Batteries journal March 2018
Polyanionic Insertion Materials for Sodium-Ion Batteries journal April 2018
Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries journal July 2018
Highly Elastic Binders Incorporated with Helical Molecules to Improve the Electrochemical Stability of Black Phosphorous Anodes for Sodium‐Ion Batteries journal November 2019
Improvement in the Energy Density of Na 3 V 2 (PO 4 ) 3 by Mg Substitution journal August 2017
Boosting High‐Rate Sodium Storage Performance of N‐Doped Carbon‐Encapsulated Na 3 V 2 (PO 4 ) 3 Nanoparticles Anchoring on Carbon Cloth journal September 2019
Research Progress in Multielectron Reactions in Polyanionic Materials for Sodium‐Ion Batteries journal October 2018
Na3V2(PO4)3/C nanofiber bifunction as anode and cathode materials for sodium-ion batteries journal May 2017
Insertion compounds and composites made by ball milling for advanced sodium-ion batteries journal January 2016
Sodium vanadium titanium phosphate electrode for symmetric sodium-ion batteries with high power and long lifespan journal June 2017
Excellent energy–power characteristics from a hybrid sodium ion capacitor based on identical carbon nanosheets in both electrodes journal January 2016
Towards high potential and ultra long-life cathodes for sodium ion batteries: freestanding 3D hybrid foams of Na 7 V 4 (P 2 O 7 ) 4 (PO 4 ) and Na 7 V 3 (P 2 O 7 ) 4 @biomass-derived porous carbon journal January 2016
Design of fast ion conducting cathode materials for grid-scale sodium-ion batteries journal January 2017
Multi-heteroatom doped carbon coated Na 3 V 2 (PO 4 ) 3 derived from ionic liquids journal January 2018
A high rate capability and long lifespan symmetric sodium-ion battery system based on a bipolar material Na 2 LiV 2 (PO 4 ) 3 /C journal January 2018
In situ formation of NaTi 2 (PO 4 ) 3 cubes on Ti 3 C 2 MXene for dual-mode sodium storage journal January 2018
Crystalline iceplant-like nano-NaVPO 4 F@graphene as an intercalation-type anode material for sodium-ion batteries journal January 2020
Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca) journal January 2019
Delicate lattice modulation enables superior Na storage performance of Na 3 V 2 (PO 4 ) 3 as both an anode and cathode material for sodium-ion batteries: understanding the role of calcium substitution for vanadium journal January 2019
A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries journal January 2019
Building highly stable and industrial NaVPO 4 F/C as bipolar electrodes for high-rate symmetric rechargeable sodium-ion full batteries journal January 2019
Sodium vanadium titanium phosphate electrode for symmetric sodium-ion batteries with high power and long lifespan text January 2017
A High-Power Symmetric Na-Ion Pseudocapacitor journal June 2016

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