Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries
Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.
- Sponsoring Organization:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- DOE Contract Number:
- DE-AR0000062
- OSTI ID:
- 1211245
- Journal Information:
- ChemComm, Vol. 50, Issue 2; ISSN 1359-7345
- Country of Publication:
- United States
- Language:
- English
Similar Records
A Facile Approach Using MgCl2 to Formulate High Performance Mg2+ Electrolytes for Rechargeable Mg Batteries
MgCl 2 : The Key Ingredient to Improve Chloride Containing Electrolytes for Rechargeable Magnesium-Ion Batteries
Highly Active Electrolytes for Rechargeable Mg Batteries Based on [Mg2(μ-Cl)2]2+ Cation Complex in Dimethoxyethane
Journal Article
·
Wed Jan 01 00:00:00 EST 2014
· Journal of Materials Chemistry A, 2(10):3430 - 3438
·
OSTI ID:1211245
+7 more
MgCl 2 : The Key Ingredient to Improve Chloride Containing Electrolytes for Rechargeable Magnesium-Ion Batteries
Journal Article
·
Fri Jan 01 00:00:00 EST 2016
· Journal of the Electrochemical Society
·
OSTI ID:1211245
+6 more
Highly Active Electrolytes for Rechargeable Mg Batteries Based on [Mg2(μ-Cl)2]2+ Cation Complex in Dimethoxyethane
Journal Article
·
Thu Jan 01 00:00:00 EST 2015
· Physical Chemistry Chemical Physics. PCCP, 17(20):13307-13314
·
OSTI ID:1211245
+8 more