Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal-Organic Frameworks

Yuan, S; Lu, WG; Chen, YP; Zhang, Q; Liu, TF; Feng, DW; Wang, X; Qin, JS; Zhou, HC

doi:10.1021/ja512762r

Title: Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal-Organic Frameworks

Journal Article · Wed Mar 11 00:00:00 EDT 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja512762r· OSTI ID:1211176

Yuan, S; Lu, WG; Chen, YP; Zhang, Q; Liu, TF; Feng, DW; Wang, X; Qin, JS; Zhou, HC

A unique strategy, sequential linker installation (SLI), has been developed to construct multivariate MOFs with functional groups precisely positioned. PCN-700, a Zr-MOF with eight-connected Zr6O4(OH)(8)(H2O)(4) clusters, has been judiciously designed; the Zr-6 clusters in this MOF are arranged in such a fashion that, by replacement of terminal OH-/H2O ligands, subsequent insertion of linear dicarboxylate linkers is achieved. We demonstrate that linkers with distinct lengths and functionalities can be sequentially installed into PCN-700. Single-crystal to single-crystal transformation is realized so that the positions of the subsequently installed linkers are pinpointed via single-crystal X-ray diffraction analyses. This methodology provides a powerful tool to construct multivariate MOFs with precisely positioned functionalities in the desired proximity, which would otherwise be difficult to achieve.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: DE-AR0000249

OSTI ID:: 1211176

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 9; ISSN 0002-7863

Country of Publication:: United States

Language:: English

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