Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

Park, Sarah S.; Hontz, Eric R.; Sun, Lei; Hendon, Christopher H.; Walsh, Aron; Van Voorhis, Troy; Dinca, Mircea

doi:10.1021/ja512437u

Title: Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks

Journal Article · Wed Feb 11 00:00:00 EST 2015 · J. Am. Chem. Soc.

DOI:https://doi.org/10.1021/ja512437u· OSTI ID:1210696

Park, Sarah S.; Hontz, Eric R.; Sun, Lei; Hendon, Christopher H.; Walsh, Aron; Van Voorhis, Troy; Dinca, Mircea

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001088

OSTI ID:: 1210696

Journal Information:: J. Am. Chem. Soc., Vol. 137; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University

Country of Publication:: United States

Language:: English

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Construction of three-dimensional anionic molecular frameworks based on hydrogen-bonded metal dithiolene complexes and the crystal solvent effect Yokomori, So; Ueda, Akira; Higashino, Toshiki CrystEngComm, Vol. 21, Issue 18 https://doi.org/10.1039/c9ce00364a	journal	January 2019
Novel semiconducting iron–quinizarin metal–organic framework for application in supercapacitors Agrawal, Surabhi; Clarke, Stuart M.; Vitorica-Yrezabal, Inigo J. Molecular Physics, Vol. 117, Issue 22 https://doi.org/10.1080/00268976.2019.1653502	journal	August 2019
Development of multi-metallic complexes using metal-salen complexes as building blocks Mondal, Ipsita; Chattopadhyay, Shouvik Journal of Coordination Chemistry, Vol. 72, Issue 19-21 https://doi.org/10.1080/00958972.2019.1695048	journal	November 2019
Novel Topology in Semiconducting Tetrathiafulvalene Lanthanide Metal-Organic Frameworks Xie, Lilia S.; Dincă, Mircea Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800068	journal	August 2018
From discrete complex to 1-D coordination polymer by subtle variation of ligand donor: structures and electrical conductivities Wu, Jun-Xi; Zhou, Dong-Dong; Zhang, Chi Journal of Coordination Chemistry, Vol. 69, Issue 11-13 https://doi.org/10.1080/00958972.2016.1190838	journal	June 2016
Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol Angewandte Chemie International Edition, Vol. 56, Issue 20 https://doi.org/10.1002/anie.201611824	journal	April 2017
Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction Fuku, Kentaro; Miyata, Momoka; Takaishi, Shinya Chemical Communications, Vol. 56, Issue 61 https://doi.org/10.1039/d0cc03062g	journal	January 2020
Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework Souto, Manuel; Calbo, Joaquín; Mañas-Valero, Samuel Beilstein Journal of Nanotechnology, Vol. 10 https://doi.org/10.3762/bjnano.10.183	journal	January 2019
Interdigitated conducting tetrathiafulvalene-based coordination networks Bechu, Damien; Xie, Lilia S.; Le Breton, Nolwenn Chemical Communications, Vol. 56, Issue 16 https://doi.org/10.1039/c9cc09960c	journal	January 2020
A Highly Conductive MOF of Graphene Analogue Ni ₃ (HITP) ₂ as a Sulfur Host for High‐Performance Lithium–Sulfur Batteries Cai, Dong; Lu, Mengjie; Li, La Small, Vol. 15, Issue 44 https://doi.org/10.1002/smll.201902605	journal	September 2019
Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks Su, Jian; Yuan, Shuai; Wang, Hai-Ying Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02256-y	journal	December 2017
Tetrathiopyridyl-tetrathiafulvalene-based Cd( ii ) coordination polymers: one ligand, one metal cation, many possibilities Bechu, Damien; Rogez, Guillaume; Hosseini, Mir Wais New Journal of Chemistry, Vol. 43, Issue 36 https://doi.org/10.1039/c9nj03572a	journal	January 2019
Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework Castaldelli, Evandro; Imalka Jayawardena, K. D. G.; Cox, David C. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02215-7	journal	December 2017
Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol Angewandte Chemie, Vol. 129, Issue 20 https://doi.org/10.1002/ange.201611824	journal	April 2017
Development of multi-metallic complexes using metal-salen complexes as building blocks Mondal, Ipsita; Chattopadhyay, Shouvik Taylor & Francis https://doi.org/10.6084/m9.figshare.11472246	text	January 2019
Development of multi-metallic complexes using metal-salen complexes as building blocks Mondal, Ipsita; Chattopadhyay, Shouvik Taylor & Francis https://doi.org/10.6084/m9.figshare.11472246.v1	text	January 2019
From discrete complex to 1-D coordination polymer by subtle variation of ligand donor: structures and electrical conductivities Wu, Jun-Xi; Zhou, Dong-Dong; Zhang, Chi Taylor & Francis https://doi.org/10.6084/m9.figshare.3394606.v2	text	January 2016
From discrete complex to 1-D coordination polymer by subtle variation of ligand donor: structures and electrical conductivities Wu, Jun-Xi; Zhou, Dong-Dong; Zhang, Chi Taylor & Francis https://doi.org/10.6084/m9.figshare.3394606	text	January 2016
Electroactive Nanoporous Metal Oxides and Chalcogenides by Chemical Design Hendon, Christopher H.; Butler, Keith T.; Ganose, Alex M. Chemistry of Materials, Vol. 29, Issue 8 https://doi.org/10.1021/acs.chemmater.7b00464	journal	April 2017
Absorbate-Induced Piezochromism in a Porous Molecular Crystal Hendon, Christopher H.; Wittering, Kate E.; Chen, Teng-Hao Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00144	journal	March 2015
Grand Challenges and Future Opportunities for Metal–Organic Frameworks Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00197	journal	June 2017
Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework Souto, Manuel; Romero, Jorge; Calbo, Joaquín Journal of the American Chemical Society, Vol. 140, Issue 33 https://doi.org/10.1021/jacs.8b05890	journal	July 2018

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CCDC 1053426: Experimental Crystal Structure Determination: ROYMEZ : catena-((μ8-4-(2-(4,5-bis(4-Carboxylatophenyl)-1,3-dithiol-2-ylidene)-5-(4-carboxylatophenyl)-1,3-dithiol-4-yl)benzoato)-diaqua-di-manganese dimethylformamide ethanol solvate) Park, Sarah S.; Hontz, Eric R.; Sun, Lei https://doi.org/10.5517/cc14c5h5 The current record is supplemented by this dataset	dataset	March 2015
CCDC 1053427: Experimental Crystal Structure Determination: ROYMID : catena-((μ8-4-(2-(4,5-bis(4-Carboxylatophenyl)-1,3-dithiol-2-ylidene)-5-(4-carboxylatophenyl)-1,3-dithiol-4-yl)benzoato)-diaqua-di-cobalt dimethylformamide ethanol solvate) Park, Sarah; Hontz, Eric; Sun, Lei https://doi.org/10.5517/cc14c5j6 The current record is supplemented by this dataset	dataset	March 2015
CCDC 1053428: Experimental Crystal Structure Determination: ROYMOJ : catena-((μ8-4-(2-(4,5-bis(4-Carboxylatophenyl)-1,3-dithiol-2-ylidene)-5-(4-carboxylatophenyl)-1,3-dithiol-4-yl)benzoato)-(μ2-aqua)-aqua-cadmium dimethylformamide ethanol solvate) Park, Sarah; Hontz, Eric; Sun, Lei https://doi.org/10.5517/cc14c5k7 The current record is supplemented by this dataset	dataset	March 2015