skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: MAPPING THE INHOMOGENEOUS ELECTROCHEMICAL REACTION THROUGH POROUS LIFEPO4 ELECTRODES IN A STANDARD COIN CELL BATTERY

Journal Article · · Chemistry of Materials
DOI:https://doi.org/10.1021/cm504317a· OSTI ID:1210547

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001294
OSTI ID:
1210547
Journal Information:
Chemistry of Materials, Vol. 27; Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University
Country of Publication:
United States
Language:
English

References (53)

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal April 1997
Thermal Stability of LiFePO[sub 4]-Based Cathodes journal January 1999
Electronically conductive phospho-olivines as lithium storage electrodes journal September 2002
Study of Antisite Defects in Hydrothermally Prepared LiFePO 4 by in Situ X-ray Diffraction journal May 2011
Comparative Kinetic Study of Olivine Li[sub x]MPO[sub 4] (M=Fe, Mn) journal January 2004
Particle Size Dependence of the Ionic Diffusivity journal October 2010
LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density journal June 1980
Approaching Theoretical Capacity of LiFePO[sub 4] at Room Temperature at High Rates journal January 2001
Battery materials for ultrafast charging and discharging journal March 2009
Solvothermal synthesis of hierarchical LiFePO4 microflowers as cathode materials for lithium ion batteries journal December 2011
Enhanced performance of LiFePO4 through hydrothermal synthesis coupled with carbon coating and cupric ion doping journal June 2011
Why Substitution Enhances the Reactivity of LiFePO 4 journal December 2012
Aliovalent Substitutions in Olivine Lithium Iron Phosphate and Impact on Structure and Properties journal April 2009
Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model journal July 2008
Kinetics of non-equilibrium lithium incorporation in LiFePO4 journal July 2011
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes journal June 2014
Rate-Induced Solubility and Suppression of the First-Order Phase Transition in Olivine LiFePO 4 journal April 2014
Visualization of Charge Distribution in a Lithium Battery Electrode journal June 2010
Multiscale Phase Mapping of LiFePO 4 -Based Electrodes by Transmission Electron Microscopy and Electron Forward Scattering Diffraction journal November 2013
Heterogeneous behaviour of the lithium battery composite electrode LiFePO4 journal May 2013
An Electrochemical Cell for Operando Study of Lithium Batteries Using Synchrotron Radiation journal January 2010
How the electrolyte limits fast discharge in nanostructured batteries and supercapacitors journal November 2009
Direct Observation of Active Material Concentration Gradients and Crystallinity Breakdown in LiFePO 4 Electrodes During Charge/Discharge Cycling of Lithium Batteries journal March 2014
Particle-Level Modeling of the Charge-Discharge Behavior of Nanoparticulate Phase-Separating Li-Ion Battery Electrodes journal January 2014
Effect of surface energies and nano-particle size distribution on open circuit voltage of Li-electrodes journal April 2009
Theory of Coherent Nucleation in Phase-Separating Nanoparticles journal May 2013
Architecture Dependence on the Dynamics of Nano-LiFePO4 Electrodes journal August 2014
Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance journal December 2012
Carbon nanofibers improve both the electronic and ionic contributions of the electrochemical performance of composite electrodes journal October 2011
Tortuosity Anisotropy in Lithium-Ion Battery Electrodes journal October 2013
Strain profiling of fatigue crack overload effects using energy dispersive X-ray diffraction journal October 2005
Stress Gradient Induced Strain Localization in Metals: High Resolution Strain Cross Sectioning via Synchrotron X-Ray Diffraction journal March 2008
In situ strain profiling of elastoplastic bending in Ti–6Al–4V alloy by synchrotron energy dispersive x-ray diffraction journal May 2009
Energy Dispersive X-ray Diffraction Profiling of Prototype LiMn 2 O 4 -Based Coin Cells journal January 2013
Rate-Dependent, Li-Ion Insertion/Deinsertion Behavior of LiFePO 4 Cathodes in Commercial 18650 LiFePO 4 Cells journal February 2014
Energy dispersive X-ray diffraction of lithium–silver vanadium phosphorous oxide cells: in situ cathode depth profiling of an electrochemical reduction–displacement reaction journal January 2013
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism journal January 2015
Isolation of Solid Solution Phases in Size-Controlled Li x FePO 4 at Room Temperature journal February 2009
A charge-flipping algorithm incorporating the tangent formula for solving difficult structures journal August 2007
Energy-dispersive diffraction studies of inert anodes journal May 2009
Intercalation Pathway in Many-Particle LiFePO 4 Electrode Revealed by Nanoscale State-of-Charge Mapping journal February 2013
Nonequilibrium Thermodynamics of Porous Electrodes journal January 2012
Porous-electrode theory with battery applications journal January 1975
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes journal September 2014
Modeling a Porous Intercalation Electrode with Two Characteristic Particle Sizes journal January 1997
Optimized solid-state synthesis of LiFePO4 cathode materials using ball-milling journal April 2008
Mechanism and kinetic studies on the synthesis of LiFePO4via solid-state reactions journal January 2013
The effects of moderate thermal treatments under air on LiFePO4-based nano powders journal January 2009
Synthesis of LiFePO4/C composite as a cathode material for lithium-ion battery by a novel two-step method journal November 2011
Solvation Structure of Li + in Concentrated LiPF 6 −Propylene Carbonate Solutions journal June 2007
Theoretical Analysis of Current Distribution in Porous Electrodes journal January 1962
Nondestructive Depth Profiling of the Solid Electrolyte Interphase on LiFePO 4 and Graphite Electrodes journal September 2009
Study on the stability of the LiFePO4 Li-ion battery via an electrochemical method journal March 2014

Cited By (10)

Review of Recent Development of In Situ/Operando Characterization Techniques for Lithium Battery Research journal May 2019
Improved electrochemical performances of carbon-coated LiFePO 4 microspheres for Li-ion battery cathode journal September 2019
Composition and Impedance Heterogeneity in Oxide Electrode Cross-Sections Detected by Raman Spectroscopy journal February 2018
Operando Neutron Depth Profiling to Determine the Spatial Distribution of Li in Li-ion Batteries journal July 2018
Synchrotron-Based X-ray Absorption Fine Structures, X-ray Diffraction, and X-ray Microscopy Techniques Applied in the Study of Lithium Secondary Batteries journal April 2018
Sustainability and in situ monitoring in battery development journal December 2016
In operando x-ray tomography for next-generation batteries: a systematic approach to monitor reaction product distribution and transport processes journal September 2016
Operando Study of LiV 3 O 8 Cathode: Coupling EDXRD Measurements to Simulations journal January 2018
Energy Dispersive X-ray Diffraction (EDXRD) of Li 1.1 V 3 O 8 Electrochemical Cell journal January 2017
Following lithiation fronts in paramagnetic electrodes with in situ magnetic resonance spectroscopic imaging journal November 2016