Dissecting graphene capacitance in electrochemical cell

Sun, Sheng; Qi, Yue; Zhang, Tong Yi

doi:10.1016/j.electacta.2015.02.049

Title: Dissecting graphene capacitance in electrochemical cell

Authors:: Sun, Sheng; Qi, Yue; Zhang, Tong Yi

Publication Date:: Fri May 01 00:00:00 EDT 2015

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1210477

DOE Contract Number:: SC0001160

Resource Type:: Journal Article

Journal Name:: Electrochimica Acta

Additional Journal Information:: Journal Volume: 163; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University

Country of Publication:: United States

Language:: English

Subject:: bio-inspired, energy storage (including batteries and capacitors), defects, charge transport, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats


                    Sun, Sheng, Qi, Yue, and Zhang, Tong Yi. Dissecting graphene capacitance in electrochemical cell.  United States: N. p., 2015. 
        Web.  doi:10.1016/j.electacta.2015.02.049.

Copy to clipboard


                    Sun, Sheng, Qi, Yue, & Zhang, Tong Yi. Dissecting graphene capacitance in electrochemical cell.  United States.  https://doi.org/10.1016/j.electacta.2015.02.049

Copy to clipboard


                    Sun, Sheng, Qi, Yue, and Zhang, Tong Yi. 2015.  
        "Dissecting graphene capacitance in electrochemical cell".  United States.  https://doi.org/10.1016/j.electacta.2015.02.049.

Copy to clipboard


                    
@article{osti_1210477,

  title        = {Dissecting graphene capacitance in electrochemical cell},

  author       = {Sun, Sheng and Qi, Yue and Zhang, Tong Yi},

  abstractNote = {},

  doi          = {10.1016/j.electacta.2015.02.049},

  url          = {https://www.osti.gov/biblio/1210477},
  journal      = {Electrochimica Acta},
number       = ,

  volume       = 163,

  place        = {United States},

  year         = {Fri May 01 00:00:00 EDT 2015},

  month        = {Fri May 01 00:00:00 EDT 2015}

}

Copy to clipboard

Journal Article:

https://doi.org/10.1016/j.electacta.2015.02.049

Other availability

Find in Google Scholar

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Band Structure of Graphite
journal, January 1958

Slonczewski, J. C.; Weiss, P. R.
Physical Review, Vol. 109, Issue 2
https://doi.org/10.1103/PhysRev.109.272

The Band Theory of Graphite
journal, May 1947

Wallace, P. R.
Physical Review, Vol. 71, Issue 9
https://doi.org/10.1103/PhysRev.71.622

Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
journal, March 2012

El-Kady, M. F.; Strong, V.; Dubin, S.
Science, Vol. 335, Issue 6074
https://doi.org/10.1126/science.1216744

Electrochemical Gate-Controlled Charge Transport in Graphene in Ionic Liquid and Aqueous Solution
journal, July 2009

Chen, Fang; Qing, Quan; Xia, Jilin
Journal of the American Chemical Society, Vol. 131, Issue 29
https://doi.org/10.1021/ja9041862

Accessing the transport properties of graphene and its multilayers at high carrier density
journal, July 2011

Ye, Jianting; Craciun, Monica F.; Koshino, Mikito
Proceedings of the National Academy of Sciences, Vol. 108, Issue 32
https://doi.org/10.1073/pnas.1018388108

Recent developments in models for the interface between a metal and an aqueous solution
journal, May 2000

Guidelli, Rolando; Schmickler, Wolfgang
Electrochimica Acta, Vol. 45, Issue 15-16
https://doi.org/10.1016/S0013-4686(00)00335-2

The electric double layer on graphite
journal, June 2012

Luque, N. B.; Schmickler, W.
Electrochimica Acta, Vol. 71
https://doi.org/10.1016/j.electacta.2012.03.083

Graphene: Status and Prospects
journal, June 2009

Geim, A. K.
Science, Vol. 324, Issue 5934, p. 1530-1534
https://doi.org/10.1126/science.1158877

The application of graphene as electrodes in electrical and optical devices
journal, February 2012

Jo, Gunho; Choe, Minhyeok; Lee, Sangchul
Nanotechnology, Vol. 23, Issue 11
https://doi.org/10.1088/0957-4484/23/11/112001

Tuning the Dirac Point in CVD-Grown Graphene through Solution Processed n-Type Doping with 2-(2-Methoxyphenyl)-1,3-dimethyl-2,3-dihydro-1 H -benzoimidazole
journal, April 2013

Wei, Peng; Liu, Nan; Lee, Hye Ryoung
Nano Letters, Vol. 13, Issue 5
https://doi.org/10.1021/nl303410g

Atomic Hole Doping of Graphene
journal, December 2008

Gierz, Isabella; Riedl, Christian; Starke, Ulrich
Nano Letters, Vol. 8, Issue 12
https://doi.org/10.1021/nl802996s

Charging the Quantum Capacitance of Graphene with a Single Biological Ion Channel
journal, April 2014

Wang, Yung Yu; Pham, Ted D.; Zand, Katayoun
ACS Nano, Vol. 8, Issue 5
https://doi.org/10.1021/nn501376z

pH sensing properties of graphene solution-gated field-effect transistors
journal, August 2013

Mailly-Giacchetti, Benjamin; Hsu, Allen; Wang, Han
Journal of Applied Physics, Vol. 114, Issue 8
https://doi.org/10.1063/1.4819219

Solution-Gated Epitaxial Graphene as pH Sensor
journal, November 2008

Ang, Priscilla Kailian; Chen, Wei; Wee, Andrew Thye Shen
Journal of the American Chemical Society, Vol. 130, Issue 44
https://doi.org/10.1021/ja805090z

Direct Measurement of Dirac Point Energy at the Graphene/Oxide Interface
journal, December 2012

Xu, Kun; Zeng, Caifu; Zhang, Qin
Nano Letters, Vol. 13, Issue 1
https://doi.org/10.1021/nl303669w

Quantum capacitance and density of states of graphene
journal, April 2010

Dröscher, S.; Roulleau, P.; Molitor, F.
Applied Physics Letters, Vol. 96, Issue 15
https://doi.org/10.1063/1.3391670

Measurements and microscopic model of quantum capacitance in graphene
journal, March 2011

Xu, Huilong; Zhang, Zhiyong; Peng, Lian-Mao
Applied Physics Letters, Vol. 98, Issue 13
https://doi.org/10.1063/1.3574011

Screening Length and Quantum Capacitance in Graphene by Scanning Probe Microscopy
journal, January 2009

Giannazzo, F.; Sonde, S.; Raineri, V.
Nano Letters, Vol. 9, Issue 1
https://doi.org/10.1021/nl801823n

Measurement of the quantum capacitance of graphene
journal, July 2009

Xia, Jilin; Chen, Fang; Li, Jinghong
Nature Nanotechnology, Vol. 4, Issue 8, p. 505-509
https://doi.org/10.1038/nnano.2009.177

Electric double-layer capacitance between an ionic liquid and few-layer graphene
journal, April 2013

Uesugi, Eri; Goto, Hidenori; Eguchi, Ritsuko
Scientific Reports, Vol. 3, Issue 1
https://doi.org/10.1038/srep01595

Density of States and Zero Landau Level Probed through Capacitance of Graphene
journal, September 2010

Ponomarenko, L. A.; Yang, R.; Gorbachev, R. V.
Physical Review Letters, Vol. 105, Issue 13
https://doi.org/10.1103/PhysRevLett.105.136801

Interaction phenomena in graphene seen through quantum capacitance
journal, February 2013

Yu, G. L.; Jalil, R.; Belle, Branson
Proceedings of the National Academy of Sciences, Vol. 110, Issue 9
https://doi.org/10.1073/pnas.1300599110

Quantum capacitance and density of states of graphene
journal, January 2012

Dröscher, S.; Roulleau, P.; Molitor, F.
Physica Scripta, Vol. T146
https://doi.org/10.1088/0031-8949/2012/T146/014009

Double-Layer in Ionic Liquids: Paradigm Change?
journal, May 2007

Kornyshev, Alexei A.
The Journal of Physical Chemistry B, Vol. 111, Issue 20
https://doi.org/10.1021/jp067857o

A Gouy–Chapman–Stern model of the double layer at a (metal)/(ionic liquid) interface
journal, February 2008

Oldham, Keith B.
Journal of Electroanalytical Chemistry, Vol. 613, Issue 2
https://doi.org/10.1016/j.jelechem.2007.10.017

Modeling Electrolytically Top-Gated Graphene
journal, January 2010

Mišković, Z. L.; Upadhyaya, Nitin
Nanoscale Research Letters, Vol. 5, Issue 3
https://doi.org/10.1007/s11671-009-9515-3

Static charging of graphene and graphite slabs
journal, March 2011

Topsakal, M.; Ciraci, S.
Applied Physics Letters, Vol. 98, Issue 13
https://doi.org/10.1063/1.3573806

Effects of static charging and exfoliation of layered crystals
journal, January 2012

Topsakal, M.; Ciraci, S.
Physical Review B, Vol. 85, Issue 4
https://doi.org/10.1103/PhysRevB.85.045121

Effects of Charging and Electric Field on Graphene Oxide
journal, March 2013

Topsakal, Mehmet; Gürel, Hikmet Hakan; Ciraci, Salim
The Journal of Physical Chemistry C, Vol. 117, Issue 11
https://doi.org/10.1021/jp310352u

First-principles calculations of charged surfaces and interfaces: A plane-wave nonrepeated slab approach
journal, March 2006

Otani, M.; Sugino, O.
Physical Review B, Vol. 73, Issue 11
https://doi.org/10.1103/PhysRevB.73.115407

First-Principles-Inspired Design Strategies for Graphene-Based Supercapacitor Electrodes
journal, December 2013

Wood, Brandon C.; Ogitsu, Tadashi; Otani, Minoru
The Journal of Physical Chemistry C, Vol. 118, Issue 1
https://doi.org/10.1021/jp4044013

Joint Density-Functional Theory: Ab Initio Study of Cr ₂ O ₃ Surface Chemistry in Solution
journal, August 2005

Petrosyan, S. A.; Rigos, A. A.; Arias, T. A.
The Journal of Physical Chemistry B, Vol. 109, Issue 32
https://doi.org/10.1021/jp044822k

Joint density functional theory of the electrode-electrolyte interface: Application to fixed electrode potentials, interfacial capacitances, and potentials of zero charge
journal, August 2012

Letchworth-Weaver, Kendra; Arias, T. A.
Physical Review B, Vol. 86, Issue 7
https://doi.org/10.1103/PhysRevB.86.075140

Workhorse Semilocal Density Functional for Condensed Matter Physics and Quantum Chemistry
journal, July 2009

Perdew, John P.; Ruzsinszky, Adrienn; Csonka, Gábor I.
Physical Review Letters, Vol. 103, Issue 2
https://doi.org/10.1103/PhysRevLett.103.026403

Improved lattice constants, surface energies, and CO desorption energies from a semilocal density functional
journal, March 2011

Sun, Jianwei; Marsman, Martijn; Ruzsinszky, Adrienn
Physical Review B, Vol. 83, Issue 12
https://doi.org/10.1103/PhysRevB.83.121410

Efficient pseudopotentials for plane-wave calculations
journal, January 1991

Troullier, N.; Martins, José Luriaas
Physical Review B, Vol. 43, Issue 3
https://doi.org/10.1103/PhysRevB.43.1993

Special points for Brillouin-zone integrations
journal, June 1976

Monkhorst, Hendrik J.; Pack, James D.
Physical Review B, Vol. 13, Issue 12, p. 5188-5192
https://doi.org/10.1103/PhysRevB.13.5188

Direct minimization technique for metals in density functional theory
journal, June 2009

Freysoldt, Christoph; Boeck, Sixten; Neugebauer, Jörg
Physical Review B, Vol. 79, Issue 24
https://doi.org/10.1103/PhysRevB.79.241103

The electronic properties of graphene
journal, January 2009

Castro Neto, A. H.; Guinea, F.; Peres, N. M. R.
Reviews of Modern Physics, Vol. 81, Issue 1, p. 109-162
https://doi.org/10.1103/RevModPhys.81.109

On the Numerical Calculation of the Density of States and Related Properties
journal, December 1972

Lehmann, G.; Taut, M.
Physica Status Solidi (b), Vol. 54, Issue 2
https://doi.org/10.1002/pssb.2220540211

Electronic doping and scattering by transition metals on graphene
journal, August 2009

Pi, K.; McCreary, K. M.; Bao, W.
Physical Review B, Vol. 80, Issue 7
https://doi.org/10.1103/PhysRevB.80.075406

Quantum capacitance devices
journal, February 1988

Luryi, Serge
Applied Physics Letters, Vol. 52, Issue 6
https://doi.org/10.1063/1.99649

Electronic structure of gated graphene and graphene ribbons
journal, May 2007

Fernández-Rossier, J.; Palacios, J. J.; Brey, L.
Physical Review B, Vol. 75, Issue 20
https://doi.org/10.1103/PhysRevB.75.205441

Carrier statistics and quantum capacitance of graphene sheets and ribbons
journal, August 2007

Fang, Tian; Konar, Aniruddha; Xing, Huili
Applied Physics Letters, Vol. 91, Issue 9
https://doi.org/10.1063/1.2776887

Similar records in OSTI.GOV collections:

Dissecting graphene capacitance in electrochemical cell

Journal Article Sun, Sheng; Qi, Yue; Zhang, Tong-Yi - Electrochimica Acta
Cited by 16
https://doi.org/10.1016/j.electacta.2015.02.049
Controlled synthesis of MnSn(OH){sub 6}/graphene nanocomposites and their electrochemical properties as capacitive materials

Journal Article Gongkai, Wang; Xiang, Sun; Fengyuan, Lu; ... - Journal of Solid State Chemistry

We report the synthesis of novel MnSn(OH){sub 6}/graphene nanocomposites produced by a co-precipitation method and their potential application for electrochemical energy storage. The hydroxide decorated graphene nanocomposites display better performance over pure MnSn(OH){sub 6} nanoparticles because the graphene sheets act as conductive bridges improving the ionic and electronic transport. The crystallinity of MnSn(OH){sub 6} nanoparticles deposited on the surface of graphene sheets also impacts the capacitive properties as electrodes. The maximum capacitance of 31.2 F/g (59.4 F/g based on the mass of MnSn(OH){sub 6} nanoparticles) was achieved for the sample with a low degree of crystallinity. No significant degradation ofmore »« less
https://doi.org/10.1016/j.jssc.2011.11.015
Electrochemical tuning of capacitive response of graphene oxide

Journal Article Gutić, Sanjin; Kozlica, Dževad; Korać, Fehim; ... - Physical Chemistry Chemical Physics. PCCP (Print)

The increasing energy demands of modern society require a deep understanding of the properties of energy storage materials, as well as the tuning of their performance. We show that the capacitance of graphene oxide (GO) can be precisely tuned using a simple electrochemical reduction route. In situ resistance measurements, in combination with cyclic voltammetry measurements and Raman spectroscopy, have shown that upon reduction GO is irreversibly deoxygenated, which is further accompanied by structural ordering and an increase in electrical conductivity. The capacitance is maximized when the concentration of oxygen functional groups is properly balanced with the conductivity. Any further reductionmore »« less
https://doi.org/10.1039/C8CP03631D
3D-Printed, Superelastic Polypyrrole–Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage

Journal Article Qi, Zhen; Ye, Jianchao; Chen, Wen; ... - Advanced Materials Technologies

Abstract Disruptive custom electronics require a transformation in energy storage systems from traditional thin‐film units to shape conformable 3D components. However, current thick electrodes suffer from uncontrollable geometries and architectures, which lead to ion diffusion limitations, and poor mechanical properties. Here, designed, superelastic polypyrrole (PPy)‐coated graphene aerogel (GA) electrodes are fabricated via 3D printing and polymer self‐assembly methods. This resilient GA template (up to 90% compression) can be printed into any desired shape including engineered 3D architectures with periodic macropores, which promote the uniform deposition and adhesion of PPy onto the support. The coated PPy thin film increases the specificmore »« less
Cited by 57
https://doi.org/10.1002/admt.201800053

Full Text Available
In situ transmission electron microscopy of electrochemical lithiation, delithiation and deformation of individual graphene nanoribbons

Journal Article Liu, X; Wang, J.; Liu, Yang; ...
https://doi.org/10.1016/j.carbon.2012.04.025

Similar Records

Title: Dissecting graphene capacitance in electrochemical cell

Citation Formats

Band Structure of Graphite journal, January 1958

The Band Theory of Graphite journal, May 1947

Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors journal, March 2012

Electrochemical Gate-Controlled Charge Transport in Graphene in Ionic Liquid and Aqueous Solution journal, July 2009

Accessing the transport properties of graphene and its multilayers at high carrier density journal, July 2011

Recent developments in models for the interface between a metal and an aqueous solution journal, May 2000

The electric double layer on graphite journal, June 2012

Graphene: Status and Prospects journal, June 2009

The application of graphene as electrodes in electrical and optical devices journal, February 2012

Tuning the Dirac Point in CVD-Grown Graphene through Solution Processed n-Type Doping with 2-(2-Methoxyphenyl)-1,3-dimethyl-2,3-dihydro-1 H -benzoimidazole journal, April 2013

Atomic Hole Doping of Graphene journal, December 2008

Charging the Quantum Capacitance of Graphene with a Single Biological Ion Channel journal, April 2014

pH sensing properties of graphene solution-gated field-effect transistors journal, August 2013

Solution-Gated Epitaxial Graphene as pH Sensor journal, November 2008

Direct Measurement of Dirac Point Energy at the Graphene/Oxide Interface journal, December 2012

Quantum capacitance and density of states of graphene journal, April 2010

Measurements and microscopic model of quantum capacitance in graphene journal, March 2011

Screening Length and Quantum Capacitance in Graphene by Scanning Probe Microscopy journal, January 2009

Measurement of the quantum capacitance of graphene journal, July 2009

Electric double-layer capacitance between an ionic liquid and few-layer graphene journal, April 2013

Density of States and Zero Landau Level Probed through Capacitance of Graphene journal, September 2010

Interaction phenomena in graphene seen through quantum capacitance journal, February 2013

Quantum capacitance and density of states of graphene journal, January 2012

Double-Layer in Ionic Liquids: Paradigm Change? journal, May 2007

A Gouy–Chapman–Stern model of the double layer at a (metal)/(ionic liquid) interface journal, February 2008

Modeling Electrolytically Top-Gated Graphene journal, January 2010

Static charging of graphene and graphite slabs journal, March 2011

Effects of static charging and exfoliation of layered crystals journal, January 2012

Effects of Charging and Electric Field on Graphene Oxide journal, March 2013

First-principles calculations of charged surfaces and interfaces: A plane-wave nonrepeated slab approach journal, March 2006

First-Principles-Inspired Design Strategies for Graphene-Based Supercapacitor Electrodes journal, December 2013

Joint Density-Functional Theory: Ab Initio Study of Cr 2 O 3 Surface Chemistry in Solution journal, August 2005

Joint density functional theory of the electrode-electrolyte interface: Application to fixed electrode potentials, interfacial capacitances, and potentials of zero charge journal, August 2012

Workhorse Semilocal Density Functional for Condensed Matter Physics and Quantum Chemistry journal, July 2009

Improved lattice constants, surface energies, and CO desorption energies from a semilocal density functional journal, March 2011

Efficient pseudopotentials for plane-wave calculations journal, January 1991

Special points for Brillouin-zone integrations journal, June 1976

Direct minimization technique for metals in density functional theory journal, June 2009

The electronic properties of graphene journal, January 2009

On the Numerical Calculation of the Density of States and Related Properties journal, December 1972

Electronic doping and scattering by transition metals on graphene journal, August 2009

Quantum capacitance devices journal, February 1988

Electronic structure of gated graphene and graphene ribbons journal, May 2007

Carrier statistics and quantum capacitance of graphene sheets and ribbons journal, August 2007

Band Structure of Graphite
journal, January 1958

The Band Theory of Graphite
journal, May 1947

Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
journal, March 2012

Electrochemical Gate-Controlled Charge Transport in Graphene in Ionic Liquid and Aqueous Solution
journal, July 2009

Accessing the transport properties of graphene and its multilayers at high carrier density
journal, July 2011

Recent developments in models for the interface between a metal and an aqueous solution
journal, May 2000

The electric double layer on graphite
journal, June 2012

Graphene: Status and Prospects
journal, June 2009

The application of graphene as electrodes in electrical and optical devices
journal, February 2012

Tuning the Dirac Point in CVD-Grown Graphene through Solution Processed n-Type Doping with 2-(2-Methoxyphenyl)-1,3-dimethyl-2,3-dihydro-1 H -benzoimidazole
journal, April 2013

Atomic Hole Doping of Graphene
journal, December 2008

Charging the Quantum Capacitance of Graphene with a Single Biological Ion Channel
journal, April 2014

pH sensing properties of graphene solution-gated field-effect transistors
journal, August 2013

Solution-Gated Epitaxial Graphene as pH Sensor
journal, November 2008

Direct Measurement of Dirac Point Energy at the Graphene/Oxide Interface
journal, December 2012

Quantum capacitance and density of states of graphene
journal, April 2010

Measurements and microscopic model of quantum capacitance in graphene
journal, March 2011

Screening Length and Quantum Capacitance in Graphene by Scanning Probe Microscopy
journal, January 2009

Measurement of the quantum capacitance of graphene
journal, July 2009

Electric double-layer capacitance between an ionic liquid and few-layer graphene
journal, April 2013

Density of States and Zero Landau Level Probed through Capacitance of Graphene
journal, September 2010

Interaction phenomena in graphene seen through quantum capacitance
journal, February 2013

Quantum capacitance and density of states of graphene
journal, January 2012

Double-Layer in Ionic Liquids: Paradigm Change?
journal, May 2007

A Gouy–Chapman–Stern model of the double layer at a (metal)/(ionic liquid) interface
journal, February 2008

Modeling Electrolytically Top-Gated Graphene
journal, January 2010

Static charging of graphene and graphite slabs
journal, March 2011

Effects of static charging and exfoliation of layered crystals
journal, January 2012

Effects of Charging and Electric Field on Graphene Oxide
journal, March 2013

First-principles calculations of charged surfaces and interfaces: A plane-wave nonrepeated slab approach
journal, March 2006

First-Principles-Inspired Design Strategies for Graphene-Based Supercapacitor Electrodes
journal, December 2013

Joint Density-Functional Theory: Ab Initio Study of Cr ₂ O ₃ Surface Chemistry in Solution
journal, August 2005

Joint density functional theory of the electrode-electrolyte interface: Application to fixed electrode potentials, interfacial capacitances, and potentials of zero charge
journal, August 2012

Workhorse Semilocal Density Functional for Condensed Matter Physics and Quantum Chemistry
journal, July 2009

Improved lattice constants, surface energies, and CO desorption energies from a semilocal density functional
journal, March 2011

Efficient pseudopotentials for plane-wave calculations
journal, January 1991

Special points for Brillouin-zone integrations
journal, June 1976

Direct minimization technique for metals in density functional theory
journal, June 2009

The electronic properties of graphene
journal, January 2009

On the Numerical Calculation of the Density of States and Related Properties
journal, December 1972

Electronic doping and scattering by transition metals on graphene
journal, August 2009

Quantum capacitance devices
journal, February 1988

Electronic structure of gated graphene and graphene ribbons
journal, May 2007

Carrier statistics and quantum capacitance of graphene sheets and ribbons
journal, August 2007