Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Ordonez, Carlos; Kinnibrugh, Tiffany; Xu, Hongwu; Lindline, Jennifer; Timofeeva, Tatiana; Wei, Qiang

doi:10.3390/cryst5020193

Title: Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Journal Article · Thu Apr 02 00:00:00 EDT 2015 · Crystals

DOI:https://doi.org/10.3390/cryst5020193· OSTI ID:1426822

Ordonez, Carlos; Kinnibrugh, Tiffany; Xu, Hongwu; Lindline, Jennifer; Timofeeva, Tatiana; Wei, Qiang

The solvothermal synthesis of framework isomers was carried out using the hybrid carboxylate and tetrazolate functional ligand, 4-tetrazolyl benzenecarboxylic acid (H₂TBC, TBC = 4-tetrazolyl benzenecarboxylate) and zinc. H₂TBC was also synthesized with the solvothermal approach, and is referred herein as structure 1. Using single-crystal X-ray diffraction, we found that the tetrazolate groups of TBC show an unusual “opposite-on” coordination mode with zinc. Three previously characterized metal-organic frameworks (MOFs) were obtained by systematically changing the solvents of the H₂TBC-Zn reaction, (1) ZnTBC, 2, which has a non-porous structure; (2) Zn₂(TBC)₂(H2O), 3, which has an amphiphilic pore structure and (3) Zn₂(TBC)₂{guest}, 4, which is porous and has channels containing uncoordinated N heteroatoms. Fluorescence spectra of 4 reveal a strong blue emission mainly from the TBC ligands.

View Journal Article

Cite

Export

Save

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: LDRD-DR; DMR0934212; IIA1301346

OSTI ID:: 1426822

Alternate ID(s):: OSTI ID: 1208867

Journal Information:: Crystals, Journal Name: Crystals Vol. 5 Journal Issue: 2; ISSN 2073-4352

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (17)

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks Eddaoudi, Mohamed; Moler, David B.; Li, Hailian Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330 https://doi.org/10.1021/ar000034b	journal	April 2001
4-(1 H -Tetrazol-5-yl)benzoic acid monohydrate Li, Guo-Qing; Wu, A-Qing; Li, Yan Acta Crystallographica Section E Structure Reports Online, Vol. 64, Issue 7 https://doi.org/10.1107/S1600536808019053	journal	June 2008
Tuning the Framework Topologies of Co ^II -Doped Zn ^II −Tetrazole-benzoate Coordination Polymers by Ligand Modifications: Structures and Spectral Studies Song, Wei-Chao; Li, Jian-Rong; Song, Peng-Chao Inorganic Chemistry, Vol. 48, Issue 8 https://doi.org/10.1021/ic802438n	journal	April 2009
Isomerism in Metal–Organic Frameworks: “Framework Isomers” Makal, Trevor A.; Yakovenko, Andrey A.; Zhou, Hong-Cai The Journal of Physical Chemistry Letters, Vol. 2, Issue 14 https://doi.org/10.1021/jz200424h	journal	June 2011
Solvothermal in Situ Metal/Ligand Reactions: A New Bridge between Coordination Chemistry and Organic Synthetic Chemistry Chen, Xiao-Ming; Tong, Ming-Liang Accounts of Chemical Research, Vol. 40, Issue 2 https://doi.org/10.1021/ar068084p	journal	February 2007
Kinetic hysteresis in gas adsorption behavior for a rigid MOF arising from zig-zag channel structures Wei, Qiang; Yang, Dali; Larson, Toti Eric Journal of Materials Chemistry, Vol. 22, Issue 20 https://doi.org/10.1039/c2jm15860d	journal	January 2012
Metal-organic frameworks James, Stuart L. Chemical Society Reviews, Vol. 32, Issue 5 https://doi.org/10.1039/b200393g	journal	January 2003
A Novel Metal−Organic Network with High Thermal Stability: Nonlinear Optical and Photoluminescent Properties Li, Yan; Xu, Gang; Zou, Wen-Qiang Inorganic Chemistry, Vol. 47, Issue 18 https://doi.org/10.1021/ic800761h	journal	September 2008
Blue-green photoluminescent 5- and 10-connected metal 5-(4′-carboxy-phenyl)tetrazolate coordination polymers Jiang, Tao; Zhao, Yan-Fei; Zhang, Xian-Ming Inorganic Chemistry Communications, Vol. 10, Issue 10 https://doi.org/10.1016/j.inoche.2007.07.001	journal	October 2007
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel Science, Vol. 295, Issue 5554, p. 469-472 https://doi.org/10.1126/science.1067208	journal	January 2002
From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids Moulton, Brian; Zaworotko, Michael J. Chemical Reviews, Vol. 101, Issue 6 https://doi.org/10.1021/cr9900432	journal	June 2001
Design, Synthesis, Structure, and Gas (N₂, Ar, CO₂, CH₄, and H₂) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W. Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118 https://doi.org/10.1021/ja042802q	journal	May 2005
ℝPM-1: A Recyclable Nanoporous Material Suitable for Ship-In-Bottle Synthesis and Large Hydrocarbon Sorption Pan, Long; Liu, Haiming; Lei, Xuegong Angewandte Chemie International Edition, Vol. 42, Issue 5 https://doi.org/10.1002/anie.200390156	journal	February 2003
Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials Farha, Omar K.; Hupp, Joseph T. Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175 https://doi.org/10.1021/ar1000617	journal	August 2010
Syntheses, Crystal Structures, and Luminescent Properties of Three Novel Zinc Coordination Polymers with Tetrazolyl Ligands Wang, Xi-Sen; Tang, Yun-Zhi; Huang, Xue-Feng Inorganic Chemistry, Vol. 44, Issue 15 https://doi.org/10.1021/ic050354x	journal	July 2005
A novel metal–organic framework with bifunctional tetrazolate-5-carboxylate ligand: Crystal structure and luminescent properties Li, Yan; Zhong, Xin-Hua; Zheng, Fa-Kun Inorganic Chemistry Communications, Vol. 14, Issue 2 https://doi.org/10.1016/j.inoche.2010.12.013	journal	February 2011
A pcu-type metal–organic framework with spindle [Zn ₇ (OH) ₈ ] ⁶⁺ cluster as secondary building units Li, Jian-Rong; Tao, Ying; Yu, Qun Chem. Commun., Issue 15 https://doi.org/10.1039/b615675d	journal	January 2007

Cited By (3)

A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property Tai, Xi-Shi; You, Hai-Ying Crystals, Vol. 5, Issue 4 https://doi.org/10.3390/cryst5040608	journal	November 2015
Recent advances in controlled modification of the size and morphology of metal-organic frameworks Liu, Botao; Vellingiri, Kowsalya; Jo, Sang-Hee Nano Research, Vol. 11, Issue 9 https://doi.org/10.1007/s12274-018-2039-3	journal	April 2018
Tuning of Luminescent and Magnetic Properties via Metal Doping of Zn-BTC Systems Qu, Taoguang; Wei, Qiang; Ordonez, Carlos Crystals, Vol. 8, Issue 4 https://doi.org/10.3390/cryst8040162	journal	April 2018

Similar Records

A 3D porous zinc MOF constructed from a flexible tripodal ligand: Synthesis, structure, and photoluminescence property

Journal Article · Sun Mar 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry · OSTI ID:1426822

Lili, Wen; Dong'e, Wang; Chenggang, Wang; +1 more

An interpenetrated pillared-layer MOF: Synthesis, structure, sorption and magnetic properties

Journal Article · Sat Feb 15 00:00:00 EST 2014 · Journal of Solid State Chemistry · OSTI ID:1426822

Jia, Li-Na; Zhao, Yang; Hou, Lei; +3 more

Unique microporous NbO-type Co{sup II}/Zn{sup II} MOFs from double helical chains: Sorption and luminescent properties

Journal Article · Wed Jun 15 00:00:00 EDT 2016 · Journal of Solid State Chemistry · OSTI ID:1426822

Dong, Wen-Wen; Xia, Liang; Peng, Zhen; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
hybrid ligand
tetrazolate
opposite-on coordination
solvothermal technique

Title: Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Citation Formats

References (17)

Cited By (3)

Similar Records

Related Subjects