Materials Data on OsCl2O by Materials Project
OsOCl2 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two OsOCl2 sheets oriented in the (0, 0, 1) direction. Os4+ is bonded to two equivalent O2- and four equivalent Cl1- atoms to form a mixture of edge and corner-sharing OsCl4O2 octahedra. The corner-sharing octahedral tilt angles are 0°. Both Os–O bond lengths are 1.86 Å. All Os–Cl bond lengths are 2.41 Å. O2- is bonded in a linear geometry to two equivalent Os4+ atoms. Cl1- is bonded in a water-like geometry to two equivalent Os4+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1203267
- Report Number(s):
- mp-29133
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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