Materials Data on K4P3 by Materials Project
K4P3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are three inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 6-coordinate geometry to six P+1.33- atoms. There are a spread of K–P bond distances ranging from 3.34–3.68 Å. In the second K1+ site, K1+ is bonded in a 7-coordinate geometry to seven P+1.33- atoms. There are a spread of K–P bond distances ranging from 3.32–3.50 Å. In the third K1+ site, K1+ is bonded in a square co-planar geometry to four equivalent P+1.33- atoms. All K–P bond lengths are 3.40 Å. There are two inequivalent P+1.33- sites. In the first P+1.33- site, P+1.33- is bonded in a 9-coordinate geometry to eight K1+ and one P+1.33- atom. The P–P bond length is 2.19 Å. In the second P+1.33- site, P+1.33- is bonded in a 9-coordinate geometry to seven K1+ and two equivalent P+1.33- atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1202537
- Report Number(s):
- mp-28424
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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