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Title: Hydrogen generation having CO2 removal with steam reforming

Patent ·
OSTI ID:1202313

A method for producing hydrogen using fuel cell off gases, the method feeding hydrocarbon fuel to a sulfur adsorbent to produce a desulfurized fuel and a spent sulfur adsorbent; feeding said desulfurized fuel and water to an adsorption enhanced reformer that comprises of a plurality of reforming chambers or compartments; reforming said desulfurized fuel in the presence of a one or more of a reforming catalyst and one or more of a CO2 adsorbent to produce hydrogen and a spent CO2 adsorbent; feeding said hydrogen to the anode side of the fuel cell; regenerating said spent CO2 adsorbents using the fuel cell cathode off-gases, producing a flow of hydrogen by cycling between said plurality of reforming chambers or compartments in a predetermined timing sequence; and, replacing the spent sulfur adsorbent with a fresh sulfur adsorbent at a predetermined time.

Research Organization:
Intelligent Energy Inc., San Jose, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG36-07GO17013
Assignee:
Intelligent Energy Inc. (San Jose, CA)
Patent Number(s):
9,093,681
Application Number:
13/324,828
OSTI ID:
1202313
Resource Relation:
Patent File Date: 2011 Dec 13
Country of Publication:
United States
Language:
English

References (6)

Catalytic reforming process patent January 1984
Steam reforming patent February 1986
Dual recycle pressure-step reformer with cyclic regeneration patent December 1986
Compact chemical reaction vessel patent August 1989
Systems and processes for providing hydrogen to fuel cells patent May 2006
Steam reforming unit patent October 2013

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