Influence of interstitial Mn on magnetism in the room-temperature ferromagnet Mn1+δSb

Taylor, Alice E.; Berlijn, Tom; Hahn, Steven E.; May, Andrew F.; Williams, Travis J.; Poudel, Lekhanath N; Calder, Stuart A.; Fishman, Randy Scott; Stone, Matthew B.; Aczel, Adam A.; Cao, Huibo; Lumsden, Mark D.; Christianson, Andrew D.

doi:10.1103/PhysRevB.91.224418

Title: Influence of interstitial Mn on magnetism in the room-temperature ferromagnet ${Mn}_{1 + δ} Sb$

Journal Article · Mon Jun 15 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.91.224418· OSTI ID:1186000

Taylor, Alice E. ^[1]; Berlijn, Tom ^[2]; Hahn, Steven E. ^[3]; May, Andrew F. ^[4]; Williams, Travis J. ^[1]; Poudel, Lekhanath N ^[5]; Calder, Stuart A. ^[1]; Fishman, Randy Scott ^[4]; Stone, Matthew B. ^[1]; Aczel, Adam A. ^[1]; Cao, Huibo ^[1]; Lumsden, Mark D. ^[1]; Christianson, Andrew D. ^[5]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS) and Computer Science and Mathematics Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Data Analysis and Visualization Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy

We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet ${Mn}_{1 + δ} Sb$ . Measurements were performed on a large, T_C = 434 K, single crystal with interstitial Mn content of δ ≈ 0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (H K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. Finally, the results show that the influence of the interstitial Mn on the magnetic state in this system is more important than previously understood.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; AC02-05CH11231

OSTI ID:: 1186000

Alternate ID(s):: OSTI ID: 1184703

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 91, Issue 22; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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Title: Influence of interstitial Mn on magnetism in the room-temperature ferromagnet Mn 1 + δ Sb

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Title: Influence of interstitial Mn on magnetism in the room-temperature ferromagnet ${Mn}_{1 + δ} Sb$