Direct measurement of polysulfide shuttle current: A window into understanding the performance of lithium-sulfur cells

Moy, Derek; Manivannan, A.; Narayanan, S. R.

doi:10.1149/2.0181501jes

Title: Direct measurement of polysulfide shuttle current: A window into understanding the performance of lithium-sulfur cells

Journal Article · Tue Nov 04 00:00:00 EST 2014 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0181501jes· OSTI ID:1185290

Moy, Derek ^[1]; Manivannan, A. ^[2]; Narayanan, S. R. ^[1]

Univ. of Southern California, Los Angeles, CA (United States)
National Energy Technology Lab. (NETL), Morgantown, WV (United States)

The shuttling of polysulfide ions between the electrodes in a lithium-sulfur battery is a major technical issue limiting the self-discharge and cycle life of this high-energy rechargeable battery. Although there have been attempts to suppress the shuttling process, there has not been a direct measurement of the rate of shuttling. We report here a simple and direct measurement of the rate of the shuttling (that we term “shuttle current”), applicable to the study of any type of lithium-sulfur cell. We demonstrate the effectiveness of this measurement technique using cells with and without lithium nitrate (a widely-used shuttle suppressor additive). We present a phenomenological analysis of the shuttling process and simulate the shuttle currents as a function of the state-of-charge of a cell. We also demonstrate how the rate of decay of the shuttle current can be used to predict the capacity fade in a lithium-sulfur cell due to the shuttle process. As a result, we expect that this new ability to directly measure shuttle currents will provide greater insight into the performance differences observed with various additives and electrode modifications that are aimed at suppressing the rate of shuttling of polysulfide ions and increasing the cycle life of lithium-sulfur cells.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Organization:: USDOE

OSTI ID:: 1185290

Report Number(s):: A-NETL-PUB-115

Journal Information:: Journal of the Electrochemical Society, Vol. 162, Issue 1; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 188 works

Citation information provided by
Web of Science

References (47)

Li/S fundamental chemistry and application to high-performance rechargeable batteries Akridge, J. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.07.070	journal	November 2004
Positive Electrode Materials for Li-Ion and Li-Batteries ^† Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902696j	journal	February 2010
Lithium batteries: Status, prospects and future Scrosati, Bruno; Garche, Jürgen Journal of Power Sources, Vol. 195, Issue 9 https://doi.org/10.1016/j.jpowsour.2009.11.048	journal	May 2010
Lithium/sulfur batteries with high specific energy: old challenges and new opportunities Song, Min-Kyu; Cairns, Elton J.; Zhang, Yuegang Nanoscale, Vol. 5, Issue 6 https://doi.org/10.1039/c2nr33044j	journal	January 2013
A Review on Li-S Batteries as a High Efficiency Rechargeable Lithium Battery Barghamadi, Marzieh; Kapoor, Ajay; Wen, Cuie Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.096308jes	journal	January 2013
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions Zhang, Sheng S. Journal of Power Sources, Vol. 231, p. 153-162 https://doi.org/10.1016/j.jpowsour.2012.12.102	journal	June 2013
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects Yin, Ya-Xia; Xin, Sen; Guo, Yu-Guo Angewandte Chemie International Edition, Vol. 52, Issue 50 https://doi.org/10.1002/anie.201304762	journal	November 2013
Lithium-sulfur batteries Nazar, Linda F.; Cuisinier, Marine; Pang, Quan MRS Bulletin, Vol. 39, Issue 5 https://doi.org/10.1557/mrs.2014.86	journal	May 2014
High Energy Rechargeable Li-S Cells for EV Application: Status, Remaining Problems and Solutions Mikhaylik, Yuriy V.; Kovalev, Igor; Schock, Riley 216th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3414001	conference	January 2010
Binder Based on Polyelectrolyte for High Capacity Density Lithium/Sulfur Battery Zhang, Sheng S. Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.039208jes	journal	January 2012
Improved Cyclability of Liquid Electrolyte Lithium/Sulfur Batteries by Optimizing Electrolyte/Sulfur Ratio Zhang, Sheng Energies, Vol. 5, Issue 12 https://doi.org/10.3390/en5125190	journal	December 2012
A simple approach for superior performance of lithium/sulphur batteries modified with a gel polymer electrolyte Zhang, Sheng S.; Tran, Dat T. J. Mater. Chem. A, Vol. 2, Issue 20 https://doi.org/10.1039/c4ta00597j	journal	January 2014
Sulphur–TiO₂ yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries Wei Seh, Zhi; Li, Weiyang; Cha, Judy J. Nature Communications, Vol. 4, Article No. 1331 https://doi.org/10.1038/ncomms2327	journal	January 2013
Ultrasound Assisted Design of Sulfur/Carbon Cathodes with Partially Fluorinated Ether Electrolytes for Highly Efficient Li/S Batteries Weng, Wei; Pol, Vilas G.; Amine, Khalil Advanced Materials, Vol. 25, Issue 11 https://doi.org/10.1002/adma.201204051	journal	January 2013
Role of Polysulfides in Self-Healing Lithium-Sulfur Batteries Xu, Rui; Belharouak, Ilias; Li, James C. M. Advanced Energy Materials, Vol. 3, Issue 7 https://doi.org/10.1002/aenm.201200990	journal	February 2013
Graphene-Based Three-Dimensional Hierarchical Sandwich-type Architecture for High-Performance Li/S Batteries Chen, Renjie; Zhao, Teng; Lu, Jun Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl4016683	journal	September 2013
Polysulfide Shuttle Study in the Li/S Battery System Mikhaylik, Yuriy V.; Akridge, James R. Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1969-A1976 https://doi.org/10.1149/1.1806394	journal	January 2004
Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries Lin, Zhan; Liu, Zengcai; Fu, Wujun Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200696	journal	June 2012
High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons He, Guang; Ji, Xiulei; Nazar, Linda Energy & Environmental Science, Vol. 4, Issue 8 https://doi.org/10.1039/c1ee01219c	journal	January 2011
Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability Wang, Hailiang; Yang, Yuan; Liang, Yongye Nano Letters, Vol. 11, Issue 7, p. 2644-2647 https://doi.org/10.1021/nl200658a	journal	July 2011
Sulfur-Impregnated Disordered Carbon Nanotubes Cathode for Lithium–Sulfur Batteries Guo, Juchen; Xu, Yunhua; Wang, Chunsheng Nano Letters, Vol. 11, Issue 10, p. 4288-4294 https://doi.org/10.1021/nl202297p	journal	October 2011
Influence of different electrode compositions and binder materials on the performance of lithium–sulfur batteries Schneider, Holger; Garsuch, Arnd; Panchenko, Alexander Journal of Power Sources, Vol. 205 https://doi.org/10.1016/j.jpowsour.2011.12.061	journal	May 2012
High-rate lithium–sulfur batteries promoted by reduced graphene oxide coating Li, Nianwu; Zheng, Mingbo; Lu, Hongling Chemical Communications, Vol. 48, Issue 34 https://doi.org/10.1039/c2cc17912a	journal	January 2012
A sulfur–carbon composite for lithium/sulfur battery based on activated vapor-grown carbon fiber Deng, Zhaofeng; Zhang, Zhian; Lai, Yanqing Solid State Ionics, Vol. 238 https://doi.org/10.1016/j.ssi.2013.03.018	journal	May 2013
A facile in situ sulfur deposition route to obtain carbon-wrapped sulfur composite cathodes for lithium–sulfur batteries Su, Yu-Sheng; Manthiram, Arumugam Electrochimica Acta, Vol. 77 https://doi.org/10.1016/j.electacta.2012.06.002	journal	August 2012
Chemically tailoring the nanostructure of graphenenanosheets to confine sulfur for high-performance lithium-sulfur batteries Ding, Bing; Yuan, Changzhou; Shen, Laifa J. Mater. Chem. A, Vol. 1, Issue 4 https://doi.org/10.1039/c2ta00396a	journal	January 2013
Lithium–Sulfur Battery Cathode Enabled by Lithium–Nitrile Interaction Guo, Juchen; Yang, Zichao; Yu, Yingchao Journal of the American Chemical Society, Vol. 135, Issue 2 https://doi.org/10.1021/ja309435f	journal	December 2012
Porous carbon nanotubes improved sulfur composite cathode for lithium-sulfur battery He, Min; Yuan, Li-Xia; Zhang, Wu-Xing Journal of Solid State Electrochemistry, Vol. 17, Issue 6 https://doi.org/10.1007/s10008-013-2023-5	journal	February 2013
Aligned sulfur-coated carbon nanotubes with a polyethylene glycol barrier at one end for use as a high efficiency sulfur cathode Huang, Jia-Qi; Zhang, Qiang; Zhang, Shu-Mao Carbon, Vol. 58 https://doi.org/10.1016/j.carbon.2013.02.037	journal	July 2013
Ultrafine Sulfur Nanoparticles in Conducting Polymer Shell as Cathode Materials for High Performance Lithium/Sulfur Batteries Chen, Hongwei; Dong, Weiling; Ge, Jun Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01910	journal	May 2013
Encapsulating sulfur into mesoporous TiO2 host as a high performance cathode for lithium–sulfur battery Ding, Bing; Shen, Laifa; Xu, Guiyin Electrochimica Acta, Vol. 107 https://doi.org/10.1016/j.electacta.2013.06.009	journal	September 2013
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide-based organic electrolyte for high performance lithium–sulfur batteries Wang, Lina; Byon, Hye Ryung Journal of Power Sources, Vol. 236 https://doi.org/10.1016/j.jpowsour.2013.02.068	journal	August 2013
Challenges and Prospects of Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar300179v	journal	June 2012
A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage Yang, Yuan; Zheng, Guangyuan; Cui, Yi Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee00072a	journal	January 2013
Exceptional electrochemical performance of rechargeable Li–S batteries with a polysulfide-containing electrolyte Chen, Shuru; Dai, Fang; Gordin, Mikhail L. RSC Advances, Vol. 3, Issue 11 https://doi.org/10.1039/c3ra23070h	journal	January 2013
Mechanistic modeling of polysulfide shuttle and capacity loss in lithium–sulfur batteries Hofmann, Andreas F.; Fronczek, David N.; Bessler, Wolfgang G. Journal of Power Sources, Vol. 259 https://doi.org/10.1016/j.jpowsour.2014.02.082	journal	August 2014
Systematical electrochemical study on the parasitic shuttle-effect in lithium-sulfur-cells at different temperatures and different rates Busche, Martin Rolf; Adelhelm, Philipp; Sommer, Heino Journal of Power Sources, Vol. 259 https://doi.org/10.1016/j.jpowsour.2014.02.075	journal	August 2014
Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer Su, Yu-Sheng; Manthiram, Arumugam Nature Communications, Vol. 3, Article No. 1166 https://doi.org/10.1038/ncomms2163	journal	January 2012
Low Temperature Performance of Li/S Batteries Mikhaylik, Yuriy V.; Akridge, James R. Journal of The Electrochemical Society, Vol. 150, Issue 3 https://doi.org/10.1149/1.1545452	journal	January 2003
Role of LiNO3 in rechargeable lithium/sulfur battery Zhang, Sheng S. Electrochimica Acta, Vol. 70 https://doi.org/10.1016/j.electacta.2012.03.081	journal	May 2012
New insight into liquid electrolyte of rechargeable lithium/sulfur battery Zhang, Sheng S. Electrochimica Acta, Vol. 97 https://doi.org/10.1016/j.electacta.2013.02.122	journal	May 2013
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries Aurbach, Doron; Pollak, Elad; Elazari, Ran Journal of The Electrochemical Society, Vol. 156, Issue 8, p. A694-A702 https://doi.org/10.1149/1.3148721	journal	January 2009
Lithium-sulfur batteries: Problems and solutions Kolosnitsyn, V. S.; Karaseva, E. V. Russian Journal of Electrochemistry, Vol. 44, Issue 5 https://doi.org/10.1134/S1023193508050029	journal	May 2008
A Mathematical Model for a Lithium–Sulfur Cell Kumaresan, Karthikeyan; Mikhaylik, Yuriy; White, Ralph E. Journal of The Electrochemical Society, Vol. 155, Issue 8 https://doi.org/10.1149/1.2937304	journal	January 2008
Construction of Electrocatalytic and Heat-Resistant Self-Supporting Electrodes for High-Performance Lithium–Sulfur Batteries Zhang, Xuemei; Wei, Yunhong; Wang, Boya Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0313-x	journal	September 2019
Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium-Sulfur-Battery Cathode Material with High Capacity and Cycling Stability Wang, Hailiang; Yang, Yuan; Liang, Yongye arXiv https://doi.org/10.48550/arxiv.1107.0109	text	January 2011

Cited By (43)

Manipulating Polysulfide Conversion with Strongly Coupled Fe ₃ O ₄ and Nitrogen Doped Carbon for Stable and High Capacity Lithium-Sulfur Batteries Lu, Ke; Zhang, Hong; Gao, Siyuan Advanced Functional Materials, Vol. 29, Issue 4 https://doi.org/10.1002/adfm.201807309	journal	November 2018
A Comprehensive Understanding of Lithium–Sulfur Battery Technology Li, Tao; Bai, Xue; Gulzar, Umair Advanced Functional Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adfm.201901730	journal	June 2019
A Cooperative Interface for Highly Efficient Lithium-Sulfur Batteries Peng, Hong-Jie; Zhang, Ze-Wen; Huang, Jia-Qi Advanced Materials, Vol. 28, Issue 43 https://doi.org/10.1002/adma.201603401	journal	September 2016
Atomic Interlamellar Ion Path in High Sulfur Content Lithium-Montmorillonite Host Enables High-Rate and Stable Lithium-Sulfur Battery Chen, Wei; Lei, Tianyu; Lv, Weiqiang Advanced Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adma.201804084	journal	August 2018
Sulfiphilic Few‐Layered MoSe ₂ Nanoflakes Decorated rGO as a Highly Efficient Sulfur Host for Lithium‐Sulfur Batteries Tian, Wenzhi; Xi, Baojuan; Feng, Zhenyu Advanced Energy Materials, Vol. 9, Issue 36 https://doi.org/10.1002/aenm.201901896	journal	August 2019
High Sulfur Content Material with Stable Cycling in Lithium-Sulfur Batteries Preefer, Molleigh B.; Oschmann, Bernd; Hawker, Craig J. Angewandte Chemie, Vol. 129, Issue 47 https://doi.org/10.1002/ange.201708746	journal	October 2017
Elektrolytadditive für Lithiummetallanoden und wiederaufladbare Lithiummetallbatterien: Fortschritte und Perspektiven Zhang, Heng; Eshetu, Gebrekidan Gebresilassie; Judez, Xabier Angewandte Chemie, Vol. 130, Issue 46 https://doi.org/10.1002/ange.201712702	journal	October 2018
Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives Zhang, Heng; Eshetu, Gebrekidan Gebresilassie; Judez, Xabier Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201712702	journal	October 2018
Uncovering the Shuttle Effect in Organic Batteries and Counter‐Strategies Thereof: A Case Study of the N , N′ ‐Dimethylphenazine Cathode Lau, Vincent Wing‐hei; Moudrakovski, Igor; Yang, Junghoon Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201912587	journal	January 2020
Electrochemical studies on composite gel polymer electrolytes for lithium sulfur-batteries Natarajan, Angulakshmi; Stephan, Arul Manuel; Chan, Chin Han Journal of Applied Polymer Science, Vol. 134, Issue 11 https://doi.org/10.1002/app.44594	journal	November 2016
Understanding the Role of Nano-Aluminum Oxide in All-Solid-State Lithium-Sulfur Batteries Judez, Xabier; Eshetu, Gebrekidan G.; Gracia, Ismael ChemElectroChem, Vol. 6, Issue 2 https://doi.org/10.1002/celc.201801390	journal	November 2018
Trapping of Polysulfides with Sulfur‐Rich Poly Ionic Liquid Cathode Materials for Ultralong‐Life Lithium–Sulfur Batteries Liu, Xu; Lu, Yu; Zeng, Qinghui ChemSusChem, Vol. 13, Issue 4 https://doi.org/10.1002/cssc.201903122	journal	January 2020
Ionic Liquids and their Polymers in Lithium‐Sulfur Batteries Josef, Elinor; Yan, Yajing; Stan, Marian Cristian Israel Journal of Chemistry, Vol. 59, Issue 9 https://doi.org/10.1002/ijch.201800159	journal	January 2019
Bio-Waste Derived Carbon as Interlayer and Scaffold for Li-S Batteries Balakumar, Kalimuthu; Packiyalakshmi, Parameswaran; Kalaiselvi, Nallathamby ChemistrySelect, Vol. 3, Issue 31 https://doi.org/10.1002/slct.201802051	journal	August 2018
Greatly Improved Conductivity of Double-Chain Polymer Network Binder for High Sulfur Loading Lithium-Sulfur Batteries with a Low Electrolyte/Sulfur Ratio Liu, Xuejun; Qian, Tao; Liu, Jie Small, Vol. 14, Issue 33 https://doi.org/10.1002/smll.201801536	journal	July 2018
A Toolbox for Lithium-Sulfur Battery Research: Methods and Protocols Zhang, Ge; Zhang, Ze-Wen; Peng, Hong-Jie Small Methods, Vol. 1, Issue 7 https://doi.org/10.1002/smtd.201700134	journal	June 2017
Sulfur Hosts against the Shuttle Effect Wang, Yazhou; Huang, Xiaoxiao; Zhang, Shanqing Small Methods, Vol. 2, Issue 6 https://doi.org/10.1002/smtd.201700345	journal	April 2018
Solvent-Engineered Scalable Production of Polysulfide-Blocking Shields to Enhance Practical Lithium-Sulfur Batteries Qin, Jin-Lei; Peng, Hong-Jie; Huang, Jia-Qi Small Methods, Vol. 2, Issue 8 https://doi.org/10.1002/smtd.201800100	journal	May 2018
Fe3O4-seated rGO–sulfur complex as a potential cathode material for lithium–sulfur batteries Suriyakumar, Shruti; Rani, G. Jenita; Stephan, A. Manuel Ionics, Vol. 26, Issue 5 https://doi.org/10.1007/s11581-019-03405-7	journal	January 2020
In situ wrapping of the cathode material in lithium-sulfur batteries Hu, Chenji; Chen, Hongwei; Shen, Yanbin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00656-8	journal	September 2017
Electrochemically primed functional redox mediator generator from the decomposition of solid state electrolyte Li, Matthew; Bai, Zhengyu; Li, Yejing Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09638-4	journal	April 2019
The Li–S battery: an investigation of redox shuttle and self-discharge behaviour with LiNO ₃ -containing electrolytes Lacey, Matthew J.; Yalamanchili, Anurag; Maibach, Julia RSC Advances, Vol. 6, Issue 5 https://doi.org/10.1039/c5ra23635e	journal	January 2016
Sisal-derived activated carbons for cost-effective lithium–sulfur batteries Raja, M.; Angulakshmi, N.; Stephan, A. Manuel RSC Advances, Vol. 6, Issue 17 https://doi.org/10.1039/c5ra25850b	journal	January 2016
Facile and scalable synthesis of nanosized core–shell Li ₂ S@C composite for high-performance lithium–sulfur batteries Yang, Tao; Wang, Xiuli; Wang, Donghuang Journal of Materials Chemistry A, Vol. 4, Issue 42 https://doi.org/10.1039/c6ta06361f	journal	January 2016
Inhibiting polysulfide shuttling using dual-functional nanowire/nanotube modified layers for highly stable lithium–sulfur batteries Wang, Yizhou; Liu, Wenhui; Liu, Ruiqing New Journal of Chemistry, Vol. 43, Issue 37 https://doi.org/10.1039/c9nj03320c	journal	January 2019
Promoting polysulfide conversion by catalytic ternary Fe ₃ O ₄ /carbon/graphene composites with ordered microchannels for ultrahigh-rate lithium–sulfur batteries Ding, Meng; Huang, Shaozhuan; Wang, Ye Journal of Materials Chemistry A, Vol. 7, Issue 43 https://doi.org/10.1039/c9ta06489c	journal	January 2019
A new cathode material synthesized by a thiol-modified metal–organic framework (MOF) covalently connecting sulfur for superior long-cycling stability in lithium–sulfur batteries Liu, Xu; Wang, Shi; Wang, Ailian Journal of Materials Chemistry A, Vol. 7, Issue 42 https://doi.org/10.1039/c9ta08043k	journal	January 2019
Enhancing the kinetics of lithium–sulfur batteries under solid-state conversion by using tellurium as a eutectic accelerator Li, Shuping; Ma, Jingqi; Zeng, Ziqi Journal of Materials Chemistry A, Vol. 8, Issue 6 https://doi.org/10.1039/c9ta13191d	journal	January 2020
Electric vehicle battery parameter identification and SOC observability analysis: NiMH and Li-S case studies Fotouhi, Abbas; Auger, Daniel J.; Propp, Karsten IET Power Electronics, Vol. 10, Issue 11 https://doi.org/10.1049/iet-pel.2016.0777	journal	September 2017
A Microstructurally Resolved Model for Li-S Batteries Assessing the Impact of the Cathode Design on the Discharge Performance Thangavel, Vigneshwaran; Xue, Kan-Hao; Mammeri, Youcef Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0051614jes	journal	January 2016
Reference Performance Test Methodology for Degradation Assessment of Lithium-Sulfur Batteries Knap, V.; Stroe, D-I.; Purkayastha, R. Journal of The Electrochemical Society, Vol. 165, Issue 9 https://doi.org/10.1149/2.0121809jes	journal	January 2018
Pitfalls in Li–S Rate-Capability Evaluation Poux, Tiphaine; Novák, Petr; Trabesinger, Sigita Journal of The Electrochemical Society, Vol. 163, Issue 7 https://doi.org/10.1149/2.0181607jes	journal	January 2016
Cellulose Separators With Integrated Carbon Nanotube Interlayers for Lithium-Sulfur Batteries: An Investigation into the Complex Interplay between Cell Components Chien, Yu-Chuan; Pan, Ruijun; Lee, Ming-Tao Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0301914jes	journal	January 2019
Investigation of the Self-Discharge Behavior of Lithium-Sulfur Batteries Knap, V.; Stroe, D. -I.; Swierczynski, M. Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0641606jes	journal	January 2016
Nontrivial Effects of “Trivial” Parameters on the Performance of Lithium–Sulfur Batteries Liao, Junbin; Ye, Zhibin Batteries, Vol. 4, Issue 2 https://doi.org/10.3390/batteries4020022	journal	May 2018
The Effects of Lithium Sulfur Battery Ageing on Second-Life Possibilities and Environmental Life Cycle Assessment Studies Wolff, Deidre; Canals Casals, Lluc; Benveniste, Gabriela Energies, Vol. 12, Issue 12 https://doi.org/10.3390/en12122440	journal	June 2019
Uncovering the Shuttle Effect in Organic Batteries and Counter‐Strategies Thereof: A Case Study of the N , N′ ‐Dimethylphenazine Cathode Lau, Vincent Wing‐hei; Moudrakovski, Igor; Yang, Junghoon Angewandte Chemie, Vol. 132, Issue 10 https://doi.org/10.1002/ange.201912587	journal	January 2020
Performance study of magnesium-sulfur battery using a graphene based sulfur composite cathode electrode and a non-nucleophilic Mg electrolyte Vinayan, B. P.; Zhao-Karger, Z.; Diemant, T. Karlsruhe https://doi.org/10.5445/ir/1000052570	text	January 2016
High Sulfur Content Material with Stable Cycling in Lithium-Sulfur Batteries Preefer, Molleigh B.; Oschmann, Bernd; Hawker, Craig J. Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201708746	journal	October 2017
Electric Vehicle Battery Parameter Identification and SOC Observability Analysis: NiMH and Li-S Case Studies Longo, S.; Auger, D. J.; Propp, K. 8th IET International Conference on Power Electronics, Machines and Drives (PEMD 2016) https://doi.org/10.1049/cp.2016.0142	conference	January 2016
The critical role of lithium nitrate in the gas evolution of lithium–sulfur batteries Jozwiuk, Anna; Berkes, Balázs B.; Weiß, Thomas Karlsruhe https://doi.org/10.5445/ir/1000058912	text	January 2016
Charge–Discharge and Interfacial Properties of Ionic Liquid-Added Hybrid Electrolytes for Lithium–Sulfur Batteries Suriyakumar, Shruti; Kathiresan, Murugavel; Stephan, A. Manuel ACS Omega, Vol. 4, Issue 2 https://doi.org/10.1021/acsomega.8b03544	journal	February 2019
Switchable encapsulation of polysulfides in the transition between sulfur and lithium sulfide Fu, Yongsheng; Wu, Zhen; Yuan, Yifei Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14686-2	journal	February 2020

Similar Records

The Role of Functionalized Conducting Polymer Binders in Improving Power Density and Cycle Life of Lithium-Sulfur Batteries

Journal Article · Wed Oct 12 00:00:00 EDT 2022 · Journal of the Electrochemical Society · OSTI ID:1185290

Zayat, Billal; Elizalde-Segovia, Rodrigo; Das, Pratyusha; +5 more

Beyond the Polysulfide Shuttle and Lithium Dendrite Formation: Addressing the Sluggish Sulfur Redox Kinetics for Practical High-Energy Li-S Batteries

Journal Article · Wed Aug 12 00:00:00 EDT 2020 · Angewandte Chemie (International Edition) · OSTI ID:1185290

Zhao, Chen; Xu, Gui‐Liang; Zhao, Tianshou; +1 more

Beyond the Polysulfide Shuttle and Lithium Dendrite Formation: Addressing the Sluggish Sulfur Redox Kinetics for Practical High‐Energy Li‐S Batteries

Journal Article · Wed Aug 12 00:00:00 EDT 2020 · Angewandte Chemie · OSTI ID:1185290

Zhao, Chen; Xu, Gui‐Liang; Zhao, Tianshou; +1 more

Related Subjects

25 ENERGY STORAGE

Title: Direct measurement of polysulfide shuttle current: A window into understanding the performance of lithium-sulfur cells

Citation Formats

References (47)

Cited By (43)

Similar Records

Related Subjects