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Title: Critical Review of the Global Chemical Kinetics of Cellulose Thermal Decomposition

Journal Article · · Energy and Fuels
 [1];  [2];  [2]
  1. American Shale Oil LLC, Rifle, Colorado 81650, United States
  2. Department of Chemical and Biological Engineering, Northwestern University, Evanston, Illinois 60208, United States

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Bioenergy Technologies Office (BETO)
Grant/Contract Number:
DEEE0003044
OSTI ID:
1179580
Journal Information:
Energy and Fuels, Journal Name: Energy and Fuels Vol. 29 Journal Issue: 5; ISSN 0887-0624
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 112 works
Citation information provided by
Web of Science

References (70)

A kinetic model for pyrolysis of cellulose journal June 1979
Cellulose pyrolysis kinetics: An historical review on the existence and role of intermediate active cellulose journal March 2012
Biomass pyrolysis kinetics: A comparative critical review with relevant agricultural residue case studies journal May 2011
Cellulose Pyrolysis Kinetics: The Current State of Knowledge journal March 1995
Numerical simulation of cellulose pyrolysis journal January 1994
Comparison of methods for measuring kerogen pyrolysis rates and fitting kinetic parameters journal November 1987
Isothermal and Nonisothermal Reaction Kinetics in Solids:  In Search of Ways toward Consensus journal October 1997
Kinetics of Chain Depolymerization journal June 1952
Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis journal January 2013
The Bitumen Intermediate in Isothermal and Nonisothermal Decomposition of Oil Shales book January 1995
Petroleum generation kinetics: Single versus multiple heating-ramp open-system pyrolysis journal April 2015
Model-free rate expression for thermal decomposition processes: The case of microcrystalline cellulose pyrolysis journal March 2015
Formation of Anhydro-sugars in the Primary Volatiles and Solid Residues from Cellulose Fast Pyrolysis in a Wire-Mesh Reactor journal July 2014
Oil-shale pyrolysis: Kinetics and mechanism of oil production journal April 1975
Kinetic parameters for thermal decomposition of microcrystalline, vegetal, and bacterial cellulose journal November 2010
Predicting oil and gas compositional yields via chemical structure–chemical yield modeling (CS–CYM): Part 2 – Application under laboratory and geologic conditions journal February 2007
A unified, global model for the pyrolysis of cellulose journal January 1994
What is active cellulose in pyrolysis? An approach based on reactivity of cellulose reducing end journal March 2014
Kinetic Analysis of Solid-State Reactions:  The Universality of Master Plots for Analyzing Isothermal and Nonisothermal Experiments journal November 2000
A Round-Robin Study of Cellulose Pyrolysis Kinetics by Thermogravimetry journal June 1999
An improved model for the kinetic description of the thermal degradation of cellulose journal October 2011
Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 °C journal August 2012
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data journal June 2011
Biological markers from Green River kerogen decomposition journal July 1982
The thermal decomposition of silver permanganate journal January 1946
Concerted Reactions and Mechanism of Glucose Pyrolysis and Implications for Cellulose Kinetics journal November 2012
Kinetics of Phase Change. I General Theory journal December 1939
Formation and Thermal Behavior of Polystyrene and Polystyrene/Clay Gels journal December 2008
Kinetics in Solids journal October 1997
Variation in Activation Energy of the Glass Transition for Polymers of Different Dynamic Fragility journal July 2006
Thermal dealkylation of dodecylbenzene and dodecylcyclohexane journal July 1998
Cooperative equilibrium transitions coupled with a slow annealing step explain the sharpness and hysteresis of collagen folding journal July 2000
Extrapolation of the kinetics of oil and gas formation from laboratory experiments to sedimentary basins journal May 1987
The Thermal Decomposition of Organic Compounds from the Standpoint of Free Radicals. VI. The Mechanism of Some Chain Reactions journal February 1934
Prediction of cellulose decomposition rates from thermogravimetric data journal January 1994
Kinetic Modelling With Multiresponse Data journal May 1980
Introduction to pyrolysis of biomass journal April 1982
Obtaining reliable phenomenological chemical kinetic models for real-world applications journal December 2014
An Appropriate Kinetic Model for Well-Preserved Algal Kerogens journal January 1996
A new model for the kinetic analysis of thermal degradation of polymers driven by random scission journal May 2010
Experimental and Mechanistic Modeling of Fast Pyrolysis of Neat Glucose-Based Carbohydrates. 2. Validation and Evaluation of the Mechanistic Model journal August 2014
A historical and current perspective on predicting thermal cookoff behavior journal July 2007
ICTAC Kinetics Committee recommendations for collecting experimental thermal analysis data for kinetic computations journal August 2014
Pyrolysis Decomposition Kinetics of Cellulose-Based Materials by Constant Heating Rate Micropyrolysis journal January 1997
Analysis of chemical reaction kinetics using a distribution of activation energies and simpler models journal March 1987
The Role of Sample Dimension and Temperature in Cellulose Pyrolysis journal March 2013
Cellulose Pyrolysis Kinetics:  Revisited journal April 1998
Development of a detailed model of petroleum formation, destruction, and expulsion from lacustrine and marine source rocks journal January 1990
Distinguishing primary and secondary reactions of cellulose pyrolysis journal April 2011
Study of the kinetics of the mechanism of solid-state reactions at increasing temperatures journal October 1971
Correlation between the shape of a TG/DTG curve and the form of the kinetic mechanism which is applying journal April 1992
Computational aspects of kinetic analysis journal July 2000
Characterization of Water-Soluble Intermediates from Slow Pyrolysis of Cellulose at Low Temperatures journal November 2012
Kinetics and Mechanism of Cellulose Pyrolysis journal October 2009
Thermokinetic model of sample response in nonisothermal analysis journal October 2012
Investigation of Primary Reactions and Secondary Effects from the Pyrolysis of Different Celluloses journal November 2014
Unraveling the Reactions that Unravel Cellulose journal June 2012
Thermal Lag, Fusion, and the Compensation Effect during Biomass Pyrolysis journal January 1996
The Kinetics of the Thermal Denaturation of Collagen in Unrestrained Rat Tail Tendon Determined by Differential Scanning Calorimetry journal January 1995
Assessment of various kinetic models for the pyrolysis of a microgranular cellulose journal July 2004
Modeling the physiochemistry of levoglucosan during cellulose pyrolysis journal January 2014
Response to Engel and Bachinger's critique of collagen denaturation as a rate process journal July 2001
Kinetics of Phase Change. II Transformation‐Time Relations for Random Distribution of Nuclei journal February 1940
Reaction Kinetics in Differential Thermal Analysis journal November 1957
The Prout-Tompkins rate equation in solid-state kinetics journal October 1997
Reaction-transport model for the pyrolysis of shrinking cellulose particles journal May 2012
Temperature and pressure dependence of n-hexadecane cracking journal October 1995
Experimental and Mechanistic Modeling of Fast Pyrolysis of Neat Glucose-Based Carbohydrates. 1. Experiments and Development of a Detailed Mechanistic Model journal August 2014
Estimation of kinetic triplet of cellulose pyrolysis reaction from isothermal kinetic results journal May 2006
Thermal decomposition mechanism of levoglucosan during cellulose pyrolysis journal July 2012

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