A mesoporous metal–organic framework based on a shape-persistent macrocycle

Chen, Teng -Hao; Popov, Ilya; Chuang, Yu -Chun; Chen, Yu -Sheng; Miljani, Ognjen S.

doi:10.1039/C5CC01635E

Title: A mesoporous metal–organic framework based on a shape-persistent macrocycle

Journal Article · Fri Jul 17 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC01635E· OSTI ID:1178849

Chen, Teng -Hao ^[1]; Popov, Ilya ^[1]; Chuang, Yu -Chun ^[2]; Chen, Yu -Sheng ^[3]; Miljani, Ognjen S. ^[1]

Univ. of Houston, Houston, TX (United States)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Univ. of Chicago, Argonne, IL (United States)

A mesoporous Zn-based metal–organic framework (MOF) was prepared from a shape-persistent phenylene ethynylene macrocycle functionalized with three –COOH groups. The rigid ligand has a ~ 9 Å wide central cavity which serves as a predesigned pore. The macrocycles [ππ] stack into pairs, with their carboxylate groups connected via three Zn₃O₁₄C₆H₂ clusters. The resulting MOF has a void volume of 86%.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: NSFOTHER

OSTI ID:: 1178849

Journal Information:: ChemComm, Vol. 51, Issue 29; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 29 works

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Mesoporous Fluorinated Metal-Organic Frameworks with Exceptional Adsorption of Fluorocarbons and CFCs Chen, Teng-Hao; Popov, Ilya; Kaveevivitchai, Watchareeya Angewandte Chemie, Vol. 127, Issue 47 https://doi.org/10.1002/ange.201505149	journal	October 2015
Cyclotetrabenzoin: Facile Synthesis of a Shape-Persistent Molecular Square and Its Assembly into Hydrogen-Bonded Nanotubes Ji, Qing; Le, Ha T. M.; Wang, Xiqu Chemistry - A European Journal, Vol. 21, Issue 48 https://doi.org/10.1002/chem.201503851	journal	October 2015
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Mesoporous Metal-Organic Frameworks: Synthetic Strategies and Emerging Applications Liu, Dingxin; Zou, Dianting; Zhu, Haolin Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201801454	journal	August 2018
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