Long life lithium batteries with stabilized electrodes

Amine, Khalil; Liu, Jun; Vissers, Donald R; Lu, Wenquan

Title: Long life lithium batteries with stabilized electrodes

Patent · Tue Apr 21 00:00:00 EDT 2015

OSTI ID:1178256

Amine, Khalil; Liu, Jun; Vissers, Donald R; Lu, Wenquan

The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In certain electrolytes, the alkali metal salt is a bis(chelato)borate and the additives include substituted or unsubstituted linear, branched or cyclic hydrocarbons comprising at least one oxygen atom and at least one aryl, alkenyl or alkynyl group. In other electrolytes, the additives include a substituted aryl compound or a substituted or unsubstituted heteroaryl compound wherein the additive comprises at least one oxygen atom. There are also provided methods of making the electrolytes and batteries employing the electrolytes. The invention also provides for electrode materials. Cathodes of the present invention may be further stabilized by surface coating the particles of the spinel or olivine with a material that can neutralize acid or otherwise lessen or prevent leaching of the manganese or iron ions. In some embodiments the coating is polymeric and in other embodiments the coating is a metal oxide such as ZrO.sub.2, TiO.sub.2, ZnO, WO.sub.3, Al.sub.2O.sub.3, MgO, SiO.sub.2, SnO.sub.2 AlPO.sub.4, Al(OH).sub.3, a mixture of any two or more thereof.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: W-31-109-ENG-38

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Number(s):: 9,012,096

Application Number:: 11/338,902

OSTI ID:: 1178256

Resource Relation:: Patent File Date: 2006 Jan 24

Country of Publication:: United States

Language:: English

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Long life lithium batteries with stabilized electrodes Amine, Khalil; Liu, Jun; Vissers, Donald R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060147809 US Patent Application 11/338902; 20060147809	patent-application	July 2006

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