Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries

Li, Hui; Yu, Xiqian; Bai, Ying; Wu, Feng; Wu, Chuan; Liu, Liang-Yu; Yang, Xiao-Qing

doi:10.1039/C5TA00277J

Title: Effects of Mg doping on the remarkably enhanced electrochemical performance of Na₃V₂(PO₄)₃ cathode materials for sodium ion batteries

Journal Article · Thu Jan 01 00:00:00 EST 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA00277J· OSTI ID:1177849

Li, Hui ^[1]; Yu, Xiqian ^[2]; Bai, Ying ^[1]; Wu, Feng ^[1]; Wu, Chuan ^[1]; Liu, Liang-Yu ^[1]; Yang, Xiao-Qing ^[2]

Beijing Inst. of Technology, Beijing (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and Environment
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.

Na₃V_2-xMg_x(PO₄)₃/C composites with different Mg²⁺ doping contents (x=0, 0.01, 0.03, 0.05, 0.07 and 0.1) were prepared by a facile sol-gel method. The doping effects on the crystal structure were investigated by XRD, XPS and EXAFS. The results show that low dose doping Mg²⁺ does not alter the structure of the material, and magnesium is successfully substituted for vanadium site. The Mg doped Na₃V_2-xMg_x(PO₄)₃/C composites exhibit significant improvements on the electrochemistry performances in terms of the rate capability and cycle performance, especially for the Na₃V_1.95Mg_0.05(PO₄)₃/C. For example, when the current density increased from 1 C to 30 C, the specific capacity only decreased from 112.5 mAh ^g-1 to 94.2 mAh g^-1 showing very good rate capability. Moreover, even cycling at a high rate of 20 C, an excellent capacity retention of 81% is maintained from the initial value of 106.4 mAh ^g-1 to 86.2 mAh ^g-1 at the 50th cycle. Enhanced rate capability and cycle performance can be attributed to the optimized particle size, structural stability and enhanced ionic and electronic conductivity induced by Mg doping.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-98CH10886; 2015CB251100; NCET-12-0047; NCET-13-0033

OSTI ID:: 1177849

Report Number(s):: BNL-107707-2015-JA; BNL-107707-2015-JAAM; JMCAET; R&D Project: MA453MAEA; VT0301010

Journal Information:: Journal of Materials Chemistry. A, Vol. 3, Issue 18; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 201 works

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Ultralong‐Life Chloride Ion Batteries Achieved by the Synergistic Contribution of Intralayer Metals in Layered Double Hydroxides Yin, Qing; Luo, Jianeng; Zhang, Jian Advanced Functional Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adfm.201907448	journal	November 2019
Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries Xiang, Xingde; Zhang, Kai; Chen, Jun Advanced Materials, Vol. 27, Issue 36 https://doi.org/10.1002/adma.201501527	journal	August 2015
Recent Advances in Sodium-Ion Battery Materials Fang, Yongjin; Xiao, Lifen; Chen, Zhongxue Electrochemical Energy Reviews, Vol. 1, Issue 3 https://doi.org/10.1007/s41918-018-0008-x	journal	June 2018
Prussian Blue@C Composite as an Ultrahigh-Rate and Long-Life Sodium-Ion Battery Cathode Jiang, Yinzhu; Yu, Shenglan; Wang, Baoqi Advanced Functional Materials, Vol. 26, Issue 29 https://doi.org/10.1002/adfm.201600747	journal	May 2016
Recent Research on Strategies to Improve Ion Conduction in Alkali Metal‐Ion Batteries Shao, TieLei; Liu, Chunyi; Deng, Wenjun Batteries & Supercaps, Vol. 2, Issue 5 https://doi.org/10.1002/batt.201800147	journal	April 2019
Boron Substituted Na ₃ V ₂ (P ₁ _−x B _x O ₄ ) ₃ Cathode Materials with Enhanced Performance for Sodium-Ion Batteries Hu, Pu; Wang, Xiaofang; Wang, Tianshi Advanced Science, Vol. 3, Issue 12 https://doi.org/10.1002/advs.201600112	journal	August 2016
A self-encapsulated porous Sb–C nanocomposite anode with excellent Na-ion storage performance Pham, Xuan-Manh; Ngo, Duc Tung; Le, Hang T. T. Nanoscale, Vol. 10, Issue 41 https://doi.org/10.1039/c8nr06182c	journal	January 2018
Strategies to Build High‐Rate Cathode Materials for Na‐Ion Batteries Lv, Wei‐Jun; Huang, Zhigao; Yin, Ya‐Xia ChemNanoMat, Vol. 5, Issue 10 https://doi.org/10.1002/cnma.201900254	journal	June 2019
Simultaneously tuning cationic and anionic redox in a P2-Na _0.67 Mn _0.75 Ni _0.25 O ₂ cathode material through synergic Cu/Mg co-doping Kong, Weijin; Gao, Rui; Li, Qingyuan Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/c9ta00968j	journal	January 2019
A Promising Carbon/g‐C ₃ N ₄ Composite Negative Electrode for a Long‐Life Sodium‐Ion Battery Weng, Guo‐Ming; Xie, Yu; Wang, Hang Angewandte Chemie International Edition, Vol. 58, Issue 39 https://doi.org/10.1002/anie.201905803	journal	September 2019
Synthesis and electrochemical performance of Na _{3− x} Li _x V ₂ (PO ₄ ) ₃ /C as cathode materials for Li‐ion batteries Jia, Maomao; Zhang, Yanhui; Tian, Hualing International Journal of Energy Research, Vol. 43, Issue 11 https://doi.org/10.1002/er.4713	journal	July 2019
Boron Substituted Na ₃ V ₂ (P _1−x B _x O ₄ ) ₃ Cathode Materials with Enhanced Performance for Sodium-Ion Batteries Hu, Pu; Wang, Xiaofang; Wang, Tianshi Advanced Science, Vol. 4, Issue 2 https://doi.org/10.1002/advs.201600525	journal	January 2017

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