Emptying and filling a tunnel bronze

Marley, Peter M.; Abtew, Tesfaye A.; Farley, Katie E.; Horrocks, Gregory A.; Dennis, Robert V.; Zhang, Peihong; Banerjee, Sarbajit

doi:10.1039/C4SC03748K

Title: Emptying and filling a tunnel bronze

Journal Article · Tue Jan 13 00:00:00 EST 2015 · Chemical Science

DOI:https://doi.org/10.1039/C4SC03748K· OSTI ID:1170442

Marley, Peter M.; Abtew, Tesfaye A.; Farley, Katie E.; Horrocks, Gregory A.; Dennis, Robert V.; Zhang, Peihong; Banerjee, Sarbajit ^[1]

The classical orthorhombic layered phase of V₂O₅ has long been regarded as the thermodynamic sink for binary vanadium oxides and has found great practical utility as a result of its open framework and easily accessible redox states. Herein, we exploit a cation-exchange mechanism to synthesize a new stable tunnel-structured polymorph of V₂O₅ (ζ-V₂O₅) and demonstrate the subsequent ability of this framework to accommodate Li and Mg ions. The facile extraction and insertion of cations and stabilization of the novel tunnel framework is facilitated by the nanometer-sized dimensions of the materials, which leads to accommodation of strain without amorphization. The topotactic approach demonstrated here indicates not just novel intercalation chemistry accessible at nanoscale dimensions but also suggests a facile synthetic route to ternary vanadium oxide bronzes (MxV₂O₅) exhibiting intriguing physical properties that range from electronic phase transitions to charge ordering and superconductivity.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC02-98CH10886

OSTI ID:: 1170442

Journal Information:: Chemical Science, Vol. 6, Issue 3; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 38 works

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References (48)

From Grignard's reagents to well-defined Mg nanostructures: distinctive electrochemical and solution reduction routes Viyannalage, Lasantha; Lee, Vincent; Dennis, Robert V. Chemical Communications, Vol. 48, Issue 42 https://doi.org/10.1039/c2cc31405c	journal	January 2012
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Recent Developments in One-Dimensional Inorganic Nanostructures for Photodetectors Zhai, Tianyou; Li, Liang; Wang, Xi Advanced Functional Materials, Vol. 20, Issue 24 https://doi.org/10.1002/adfm.201001259	journal	November 2010
Crystal Structure and Shape of Colloidal Particles of Vanadium Pentoxide Ketelaar, J. A. A. Nature, Vol. 137, Issue 3460 https://doi.org/10.1038/137316a0	journal	February 1936
On the preparation and characterization of a new polymorph of V2O5 Cocciantelli, J. M.; Gravereau, P.; Doumerc, J. P. Journal of Solid State Chemistry, Vol. 93, Issue 2 https://doi.org/10.1016/0022-4596(91)90323-A	journal	August 1991
Insertion Electrode Materials for Rechargeable Lithium Batteries Winter, Martin; Besenhard, Jürgen O.; Spahr, Michael E. Advanced Materials, Vol. 10, Issue 10 https://doi.org/10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z	journal	July 1998
Chemical and mechanistic aspects of the selective catalytic reduction of NO by ammonia over oxide catalysts: A review Busca, Guido; Lietti, Luca; Ramis, Gianguido Applied Catalysis B: Environmental, Vol. 18, Issue 1-2 https://doi.org/10.1016/S0926-3373(98)00040-X	journal	September 1998
Layered vanadium and molybdenum oxides: batteries and electrochromics Chernova, Natasha A.; Roppolo, Megan; Dillon, Anne C. Journal of Materials Chemistry, Vol. 19, Issue 17 https://doi.org/10.1039/b819629j	journal	January 2009
Mott transition field effect transistor Newns, D. M.; Misewich, J. A.; Tsuei, C. C. Applied Physics Letters, Vol. 73, Issue 6 https://doi.org/10.1063/1.121999	journal	August 1998
Topochemical Manipulation of Perovskites: Low-Temperature Reaction Strategies for Directing Structure and Properties Sanjaya Ranmohotti, K. G.; Josepha, Elisha; Choi, Jonglak Advanced Materials, Vol. 23, Issue 4 https://doi.org/10.1002/adma.201002274	journal	January 2011
Electronic Phase Transitions of δ-Ag _x V ₂ O ₅ Nanowires: Interplay between Geometric and Electronic Structures Marley, Peter M.; Singh, Sujay; Abtew, Tesfaye A. The Journal of Physical Chemistry C, Vol. 118, Issue 36 https://doi.org/10.1021/jp506238s	journal	August 2014
Finite size effects on the structural progression induced by lithiation of V2O5: a combined diffraction and Raman spectroscopy study Horrocks, Gregory A.; Likely, Maliek F.; Velazquez, Jesus M. Journal of Materials Chemistry A, Vol. 1, Issue 48 https://doi.org/10.1039/c3ta13690f	journal	January 2013
The crystal structure of Na _{2− x} V ₆ O ₁₅ Wadsley, A. D. Acta Crystallographica, Vol. 8, Issue 11 https://doi.org/10.1107/S0365110X55002144	journal	November 1955
Electronic Structure of β-Na _x V ₂ O ₅ ( x ≈ 0.33) Polycrystalline Films: Growth, Spectroscopy, and Theory Chen, Bo; Laverock, Jude; Newby, Dave The Journal of Physical Chemistry C, Vol. 118, Issue 2 https://doi.org/10.1021/jp410277m	journal	December 2013
Prototype systems for rechargeable magnesium batteries Aurbach, D.; Lu, Z.; Schechter, A. Nature, Vol. 407, Issue 6805, p. 724-727 https://doi.org/10.1038/35037553	journal	October 2000
Structure and phase transitions of low-dimensional thallium vanadium bronze TlxV2O5 (0.44 ≤ x ≤ 0.48) Ganne, M.; Jouanneaux, A.; Tournoux, M. Journal of Solid State Chemistry, Vol. 97, Issue 1 https://doi.org/10.1016/0022-4596(92)90024-P	journal	March 1992
Charge Disproportionation and Voltage-Induced Metal-Insulator Transitions Evidenced in β-Pb _x V ₂ O ₅ Nanowires Marley, Peter M.; Stabile, Adam A.; Kwan, Chun Pui Advanced Functional Materials, Vol. 23, Issue 2 https://doi.org/10.1002/adfm.201201513	journal	August 2012
Reversible Interconversion of a Divalent Vanadium Bronze between δ and β Quasi-1D Structures Marley, Peter M.; Banerjee, Sarbajit Inorganic Chemistry, Vol. 51, Issue 9 https://doi.org/10.1021/ic300191y	journal	April 2012
Vanadium Pentoxide - a Compound with Five-Coordinated Vanadium Atoms. Byström, Anders; Wilhelmi, Karl-Axel; Brotzen, Otto Acta Chemica Scandinavica, Vol. 4 https://doi.org/10.3891/acta.chem.scand.04-1119	journal	January 1950
Oxidative dehydrogenation of lower alkanes on vanadium oxide-based catalysts. The present state of the art and outlooks Mamedov, E. A.; Cortés Corberán, V. Applied Catalysis A: General, Vol. 127, Issue 1-2 https://doi.org/10.1016/0926-860X(95)00056-9	journal	June 1995
Synthesis, Structural Characterization, and Electronic Structure of Single-Crystalline Cu _x V ₂ O ₅ Nanowires Patridge, Christopher J.; Jaye, Cherno; Zhang, Hengsong Inorganic Chemistry, Vol. 48, Issue 7 https://doi.org/10.1021/ic802408c	journal	April 2009
I. The Bakerian Lecture. - Researches on vanadium Roscoe, Henry Enfield Philosophical Transactions of the Royal Society of London, Vol. 158, p. 1-27 https://doi.org/10.1098/rstl.1868.0001	journal	January 1868
Electronic structure of $V_{2} O_{5}$ : Role of octahedral deformations Eyert, V.; Höck, K. -H. Physical Review B, Vol. 57, Issue 20 https://doi.org/10.1103/PhysRevB.57.12727	journal	May 1998
Doped Nanocrystals Norris, D. J.; Efros, A. L.; Erwin, S. C. Science, Vol. 319, Issue 5871 https://doi.org/10.1126/science.1143802	journal	March 2008
Real-time synchrotron powder X-ray diffraction study of the antisite defect formation during sub- and supercritical synthesis of LiFePO ₄ and LiFe _{1− x} Mn _x PO ₄ nanoparticles Jensen, Kirsten; Christensen, Mogens; Tyrsted, Christoffer Journal of Applied Crystallography, Vol. 44, Issue 2 https://doi.org/10.1107/S0021889811006522	journal	March 2011
Electrode materials for lithium secondary batteries prepared by sol–gel methods Fu, L.; Liu, H.; Li, C. Progress in Materials Science, Vol. 50, Issue 7 https://doi.org/10.1016/j.pmatsci.2005.04.002	journal	September 2005
Structure of a high-pressure phase of vanadium pentoxide, β-V ₂ O ₅ Filonenko, V. P.; Sundberg, M.; Werner, P. -E. Acta Crystallographica Section B Structural Science, Vol. 60, Issue 4 https://doi.org/10.1107/S0108768104012881	journal	July 2004
Pressure-Induced Superconductivity in $β - {N a}_{0.33} V_{2} O_{5}$ beyond Charge Ordering Yamauchi, T.; Ueda, Y.; Môri, N. Physical Review Letters, Vol. 89, Issue 5 https://doi.org/10.1103/PhysRevLett.89.057002	journal	July 2002
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Synthesis, Spectroscopic Characterization, and Observation of Massive Metal—Insulator Transitions in Nanowires of a Nonstoichiometric Vanadium Oxide Bronze Patridge, Christopher J.; Wu, Tai-Lung; Jaye, Cherno Nano Letters, Vol. 10, Issue 7 https://doi.org/10.1021/nl100642b	journal	July 2010
Superconducting $β (β^{'})$ -vanadium bronzes under pressure Yamauchi, Touru; Ueda, Yutaka Physical Review B, Vol. 77, Issue 10 https://doi.org/10.1103/PhysRevB.77.104529	journal	March 2008
On the crystal structure of CsxV2O5 (x approx. 0.3), a new hexagonal vanadium bronze structure type Waltersson, K.; Forslund, B. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 33, Issue 3 https://doi.org/10.1107/S0567740877004634	journal	March 1977
Structural chemistry of vanadium oxides with open frameworks Zavalij, Peter Y.; Whittingham, M. Stanley Acta Crystallographica Section B Structural Science, Vol. 55, Issue 5 https://doi.org/10.1107/S0108768199004000	journal	October 1999
Colossal above-room-temperature metal–insulator switching of a Wadsley-type tunnel bronze Patridge, Christopher J.; Wu, Tai-Lung; Sambandamurthy, G. Chemical Communications, Vol. 47, Issue 15 https://doi.org/10.1039/c0cc05709f	journal	January 2011
The structure of the lithium-inserted metal oxide δLiV2O5 Cava, R. J.; Santoro, A.; Murphy, D. W. Journal of Solid State Chemistry, Vol. 65, Issue 1 https://doi.org/10.1016/0022-4596(86)90089-7	journal	November 1986
Microscopic and Nanoscale Perspective of the Metal−Insulator Phase Transitions of VO ₂ : Some New Twists to an Old Tale Whittaker, Luisa; Patridge, Christopher J.; Banerjee, Sarbajit The Journal of Physical Chemistry Letters, Vol. 2, Issue 7 https://doi.org/10.1021/jz101640n	journal	March 2011
XXXVI.—Researches on vanadium Roscoe, Henry E. J. Chem. Soc., Vol. 21, Issue 0 https://doi.org/10.1039/JS8682100322	journal	January 1868
Fast, Completely Reversible Li Insertion in Vanadium Pentoxide Nanoribbons Chan, Candace K.; Peng, Hailin; Twesten, Ray D. Nano Letters, Vol. 7, Issue 2 https://doi.org/10.1021/nl062883j	journal	February 2007
Formation of the cerium orthovanadate $Ce V O_{4}$ : $DFT + U$ study Da Silva, Juarez L. F.; Ganduglia-Pirovano, M. Verónica; Sauer, Joachim Physical Review B, Vol. 76, Issue 12 https://doi.org/10.1103/PhysRevB.76.125117	journal	September 2007
Strongly Correlated Materials Morosan, Emilia; Natelson, Douglas; Nevidomskyy, Andriy H. Advanced Materials, Vol. 24, Issue 36 https://doi.org/10.1002/adma.201202018	journal	August 2012
Influence of stoichiometry on the metal‐semiconductor transition in vanadium dioxide Griffiths, C. H.; Eastwood, H. K. Journal of Applied Physics, Vol. 45, Issue 5 https://doi.org/10.1063/1.1663568	journal	May 1974
Perovskites by Design: A Toolbox of Solid-State Reactions Schaak, Raymond E.; Mallouk, Thomas E. Chemistry of Materials, Vol. 14, Issue 4, p. 1455-1471 https://doi.org/10.1021/cm010689m	journal	April 2002
Cation Exchange Reactions in Ionic Nanocrystals Son, Dong Hee; Hughes, Steven M.; Yin, Yadong Science, Vol. 306, Issue 5698, p. 1009-1012 https://doi.org/10.1126/science.1103755	journal	November 2004
Nanoscale Effects on Thermodynamics and Phase Equilibria in Oxide Systems Navrotsky, Alexandra ChemPhysChem, Vol. 12, Issue 12 https://doi.org/10.1002/cphc.201100129	journal	July 2011
Near Edge X-ray Absorption Fine Structure Spectroscopy Studies of Single-Crystalline V ₂ O ₅ Nanowire Arrays Velazquez, Jesus M.; Jaye, Cherno; Fischer, Daniel A. The Journal of Physical Chemistry C, Vol. 113, Issue 18 https://doi.org/10.1021/jp900809y	journal	April 2009
Charge order and superconductivity in vanadium oxides Yamauchi, Touru; Isobe, Masahiko; Ueda, Yutaka Solid State Sciences, Vol. 7, Issue 7 https://doi.org/10.1016/j.solidstatesciences.2005.01.024	journal	July 2005
V2O5 nanofibre sheet actuators Gu, Gang; Schmid, Michael; Chiu, Po-Wen Nature Materials, Vol. 2, Issue 5 https://doi.org/10.1038/nmat880	journal	April 2003
The inherent displacive structural flexibility of M _x V ₂ O ₅ framework structures Withers, Ray L.; Millet, P.; Tabira, Y. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 215, Issue 6 https://doi.org/10.1524/zkri.2000.215.6.357	journal	June 2000

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Type-II heterostructures of α -V ₂ O ₅ nanowires interfaced with cadmium chalcogenide quantum dots: Programmable energetic offsets, ultrafast charge transfer, and photocatalytic hydrogen evolution Chauhan, Saurabh; Sheng, Aaron; Cho, Junsang The Journal of Chemical Physics, Vol. 151, Issue 22 https://doi.org/10.1063/1.5128148	journal	December 2019
Reciprocal space imaging of ionic correlations in intercalation compounds Krogstad, Matthew J.; Rosenkranz, Stephan; Wozniak, Justin M. Nature Materials, Vol. 19, Issue 1 https://doi.org/10.1038/s41563-019-0500-7	journal	October 2019
Striping modulations and strain gradients within individual particles of a cathode material upon lithiation De Jesus, Luis R.; Stein, Peter; Andrews, Justin L. Materials Horizons, Vol. 5, Issue 3 https://doi.org/10.1039/c8mh00037a	journal	January 2018
Reciprocal Space Imaging of Ionic Correlations in Intercalation Compounds Krogstad, Matthew J.; Rosenkranz, Stephan; Wozniak, Justin M. arXiv https://doi.org/10.48550/arxiv.1902.03318	text	January 2019
Probing local electronic and geometric changes of hydrated calcium vanadium oxide (Ca _x V ₂ O ₅ ·yH ₂ O) upon Zn ion intercalation Patridge, Christopher Journal of Coordination Chemistry, Vol. 72, Issue 8 https://doi.org/10.1080/00958972.2019.1612054	journal	March 2019
A review of Raman spectroscopy of vanadium oxides Shvets, Petr; Dikaya, Olga; Maksimova, Ksenia Journal of Raman Spectroscopy, Vol. 50, Issue 8 https://doi.org/10.1002/jrs.5616	journal	May 2019

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