skip to main content

Title: A Three-Dimensional Microporous Metal-Metalloporphyrin Framework

A new porphyrin-based microporous MOF, {Mn(II) 0.5[Mn(II) 4Cl(Mn(III)Cl-ttzpp) 2(H 2O) 4]}·(DEF) 20·(CH 3OH) 18·(H 2O) 12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C 2H 2/CH 4 separation at room temperature.
; ; ; ; ; ; ;  [1] ;  [2] ;  [2] ;  [2]
  1. Ames
  2. (
Publication Date:
OSTI Identifier:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorg. Chem.; Journal Volume: 54; Journal Issue: (1) ; 01, 2015
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org:
Country of Publication:
United States