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Title: Real-Time Noise Reduction for Mossbauer Spectroscopy through Online Implementation of a Modified Kalman Filter

Spectrum-processing software that incorporates a gaussian smoothing kernel within the statistics of first-order Kalman filtration has been developed to provide cross-channel spectral noise reduction for increased real-time signal-to-noise ratios for Mossbauer spectroscopy. The filter was optimized for the breadth of the gaussian using the Mossbauer spectrum of natural iron foil, and comparisons between the peak broadening, signal-to-noise ratios, and shifts in the calculated hyperfine parameters are presented. The results of optimization give a maximum improvement in the signal-to-noise ratio of 51.1% over the unfiltered spectrum at a gaussian breadth of 27 channels, or 2.5% of the total spectrum width. The full-width half-maximum of the spectrum peaks showed an increase of 19.6% at this optimum point, indicating a relatively weak increase in the peak broadening relative to the signal enhancement, leading to an overall increase in the observable signal. Calculations of the hyperfine parameters showed no statistically significant deviations were introduced from the application of the filter, confirming the utility of this filter for spectroscopy applications.
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Publication Date:
OSTI Identifier:
Report Number(s):
Journal ID: ISSN 0168-9002; 48263
DOE Contract Number:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment; Journal Volume: 773
Research Org:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org:
Country of Publication:
United States
Mossbauer spectroscopy; software; spectrum filtering; signal-to-noise ratio; Environmental Molecular Sciences Laboratory