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Title: Gaseous Chemistry and Aerosol Mechanism Developments for Version 3.5.1 of the Online Regional Model, WRF-Chem

Journal Article · · Geoscientific Model Development
 [1];  [1];  [2];  [1];  [3];  [3];  [4];  [1]
  1. Univ. of Manchester (United Kingdom)
  2. Univ. of Melbourne, Victoria (Australia)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  4. Univ. of Oslo (Norway)

We have made a number of developments in the regional coupled model WRF-Chem, with the aim of making the model more suitable for prediction of atmospheric composition and of interactions between air quality and weather. We have worked on the European domain, with a particular focus on making the model suitable for the study of night time chemistry and oxidation by the nitrate radical in the UK atmosphere. A reduced form of the Common Reactive Intermediates gas-phase chemical mechanism (CRIv2-R5) has been implemented to enable more explicit simulation of VOC degradation. N2O5 heterogeneous chemistry has been added to the existing sectional MOSAIC aerosol module, and coupled to both the CRIv2-R5 and existing CBM-Z gas phase scheme. Modifications have also been made to the sea-spray aerosol emission representation, allowing the inclusion of primary organic material in sea-spray aerosol. Driven by appropriate emissions, wind fields and chemical boundary conditions, implementation of the different developments is illustrated in order to demonstrate the impact that these changes have in the North-West European domain. These developments are now part of the freely available WRF-Chem distribution.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1166819
Report Number(s):
PNNL-SA-100202; KP1701000
Journal Information:
Geoscientific Model Development, Vol. 7, Issue 6; ISSN 1991-959X
Publisher:
European Geosciences Union
Country of Publication:
United States
Language:
English