Stable-isotope probe of nano-scale mineral-fluid redox interactions
The project examined how stable isotopes fractionate at an aqueous/solid interface during electrochemical reduction reactions. Measurements in a wide variety of metal deposition systems including Fe, Zn, Li, Mo, and Cu, have led to observations of large isotope fractionations which strongly vary as a function of rate and temperature. For the Fe, Zn, and Li systems, our electrochemical deposition methods provide the largest single-pass fractionation factors that are observed for these systems. Based on these and other experiments and theory showing and predicting significant and rate-dependent fractionations of isotopes at reacting interfaces, we have developed a simple statistical mechanics framework that predicts the kinetic isotope effect accompanying phase transformations in condensed systems. In addition, we have begun to extend our studies of mineral-fluid redox interactions to high pressures and temperatures in the diamond anvil cell. We performed a series of experiments to determine solubilities of Cu and Ni at elevated pressure and temperature conditions relevant to ore-formation.
- Publication Date:
- OSTI Identifier:
- Report Number(s):
- DOE Contract Number:
- Resource Type:
- Technical Report
- Research Org:
- Univ. of California, Los Angeles, CA (United States)
- Sponsoring Org:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Country of Publication:
- United States
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Stable isotope fractionation; electrochemistry; electrodeposition; metal-aqueous interfaces
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