Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver

El-Khoury, Patrick Z.; Ueltschi, Tyler W.; Mifflin, Amanda L.; Hu, Dehong; Hess, Wayne P.

doi:10.1021/jp509082c

Title: Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver

Journal Article · Wed Nov 12 00:00:00 EST 2014 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/jp509082c· OSTI ID:1164574

El-Khoury, Patrick Z. ^[1]; Ueltschi, Tyler W. ^[2]; Mifflin, Amanda L. ^[2]; Hu, Dehong ^[1]; Hess, Wayne P. ^[1]

Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, United States
Department of Chemistry, University of Puget Sound, Tacoma, Washington 98416, United States

Non-resonant tip-enhanced Raman images of 4,4'-dimercaptostilbene on silver reveal that different vibrational resonances of the reporter are selectively enhanced at different sites on the metal substrate. Sequentially recorded images track molecular diffusion within the diffraction-limited laser spot which illuminates the substrate. In effect, the recorded time resolved (Δt = 10 s) pixelated images (25 nm x 8 cm-1) broadcast molecule-local field interactions which take place on much finer scales.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1164574

Alternate ID(s):: OSTI ID: 1170070

Report Number(s):: PNNL-SA-100249

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Vol. 118 Journal Issue: 47; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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Title: Frequency-Resolved Nanoscale Chemical Imaging of 4,4′-Dimercaptostilbene on Silver

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