skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Tandem Catalysis by Palladium Nanoclusters Encapsulated in Metal-Organic Frameworks

Journal Article · · ACS Catal.
DOI:https://doi.org/10.1021/cs5006635· OSTI ID:1163397

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
UNIVERSITY
OSTI ID:
1163397
Journal Information:
ACS Catal., Vol. 4, Issue (10) ; 10, 2014
Country of Publication:
United States
Language:
ENGLISH

References (68)

Methanol Reactions over Oxygen-Modified Re Surfaces:  Influence of Surface Structure and Oxidation journal September 2004
Au@ZIFs: Stabilization and Encapsulation of Cavity-Size Matching Gold Clusters inside Functionalized Zeolite Imidazolate Frameworks, ZIFs journal December 2010
Selective Oxidation of Methanol and Ethanol on Supported Ruthenium Oxide Clusters at Low Temperatures journal February 2005
Reaction of benzaldehyde with various aliphatic glycols in the presence of hydrophobic Al-MCM-41: A convenient synthesis of cyclic acetals journal July 2008
TiO2 nanotubes supported V2O5 for the selective oxidation of methanol to dimethoxymethane journal December 2008
Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory journal April 2011
Synergistic Catalysis of Au@Ag Core−Shell Nanoparticles Stabilized on Metal−Organic Framework journal February 2011
Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal–Organic Framework: A Double Solvents Approach journal August 2012
Organocatalytic cascade reactions as a new tool in total synthesis journal February 2010
Catalytically active palladium pyridylidene complexes: pyridinium ionic liquids as N-heterocyclic carbene precursors journal January 2005
Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks journal April 2012
Selective Formation of Acetal by Photooxidation of Ethanol over Silica-supported Niobium Oxide Catalysts journal April 1994
Ab initio theory and calculations of X-ray spectra journal July 2009
Green oxidation with aqueous hydrogen peroxide journal January 2003
One-Step Synthesis of Acetals from Phenol/Alcohols Mixtures Using a Pd/Aluminoborate Catalyst journal August 2012
Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks journal September 2011
Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions journal January 2014
Metal–Organic Frameworks in Biomedicine journal September 2011
A Multifunction Pd/Sc(OTf) 3 /Ionic Liquid Catalyst System for the Tandem One-Pot Conversion of Phenol to ε-Caprolactam journal February 2013
On the Stability and Recyclability of Supported Metal–Ligand Complex Catalysts: Myths, Misconceptions and Critical Research Needs journal May 2010
Palladium-catalyzed oxidation of primary alcohols: Highly selective direct synthesis of acetals journal October 2007
TPAP-Catalyzed Direct Oxidation of Primary Alcohols to Carboxylic Acids through Stabilized Aldehyde Hydrates journal August 2011
ZIF-8 immobilized nickel nanoparticles: highly effective catalysts for hydrogen generation from hydrolysis of ammonia borane journal January 2012
Effects of linker substitution on catalytic properties of porous zirconium terephthalate UiO-66 in acetalization of benzaldehyde with methanol journal February 2014
Metal–Organic Framework Materials as Chemical Sensors journal September 2011
Cascade Reactions in Total Synthesis journal November 2006
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals journal January 2013
Multiple-scattering calculations of x-ray-absorption spectra journal July 1995
EXAFS study of the influence of hydrogen desorption and oxygen adsorption on the structural properties of small iridium particles supported on Al2O3 journal January 1990
IFEFFIT  : interactive XAFS analysis and FEFF fitting journal March 2001
Coordination and Reactivity Study of Group 4 and 10 Transition Metal Complexes of N -Imidazol-2-ylidene- N ′- p -tolylureate and Thioureate Ligands journal March 2013
Multifunctional catalysis by Pd@MIL-101: one-step synthesis of methyl isobutyl ketone over palladium nanoparticles deposited on a metal–organic framework journal January 2010
Improved Low-Temperature CO Oxidation Performance of Pd Supported on La-Stabilized Alumina journal April 2013
Deposition of Gold Clusters on Porous Coordination Polymers by Solid Grinding and Their Catalytic Activity in Aerobic Oxidation of Alcohols journal September 2008
Palladium-Catalyzed Intramolecular Trapping of the Blaise Reaction Intermediate for Tandem One-Pot Synthesis of Indole Derivatives journal March 2011
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
Metal−Organic Framework Supported Gold Nanoparticles as a Highly Active Heterogeneous Catalyst for Aerobic Oxidation of Alcohols journal July 2010
From Alkyl Aromatics to Aromatic Esters: Efficient and Selective CH Activation Promoted by a Bimetallic Heterogeneous Catalyst journal September 2012
ATHENA and ARTEMIS Interactive Graphical Data Analysisusing IFEFFIT journal January 2005
An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation journal January 2011
Metal-Organic Frameworks: Opportunities for Catalysis journal September 2009
Introduction to Metal–Organic Frameworks journal September 2011
Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage journal August 2011
Mesoporous Silica with Site-Isolated Amine and Phosphotungstic Acid Groups: A Solid Catalyst with Tunable Antagonistic Functions for One-Pot Tandem Reactions journal September 2011
Highly productive iron molybdate mixed oxides and their relevant catalytic properties for direct synthesis of 1,1-dimethoxymethane from methanol journal February 2014
MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst journal January 2012
Catalysis by metal nanoparticles embedded on metal–organic frameworks journal January 2012
Metal–Organic Framework Thin Films: From Fundamentals to Applications. journal September 2011
Selective oxidation of methanol to dimethoxymethane under mild conditions over V2O5/TiO2 with enhanced surface acidity journal January 2007
Highly Efficient and Versatile Acetalization of Glycol Catalyzed by Cupricp-Toluenesulfonate journal January 2007
Mesoporous Organosilicas with Acidic Frameworks and Basic Sites in the Pores: An Approach to Cooperative Catalytic Reactions journal December 2009
Glycerol acetals as anti-freezing additives for biodiesel journal August 2010
Immobilizing Metal Nanoparticles to Metal–Organic Frameworks with Size and Location Control for Optimizing Catalytic Performance journal May 2013
Selective oxidation of methanol to dimethoxymethane over bifunctional VOx/TS-1 catalysts journal January 2011
Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation journal April 2014
Discovery, development, and functionalization of Zr( iv )-based metal–organic frameworks journal January 2012
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
The oxidation of ethanol by hydrogen peroxide. Part I. Catalysis by ferric ion journal January 1967
Significant promoting effects of Lewis acidity on Au–Pd systems in the selective oxidation of aromatic hydrocarbons journal January 2012
Catalytic chromium reduction using formic acid and metal nanoparticles immobilized in a metal–organic framework journal January 2013
Selective One-Step Synthesis of Dimethoxymethane via Methanol or Dimethyl Ether Oxidation on H 3+ n V n Mo 12- n PO 40 Keggin Structures journal October 2003
Sequential and tandem oxidation/acetalization procedures for the direct generation of acetals from alcohols journal July 2007
Efficient Iron-Catalyzed Acetal Formation from Styrene Derivatives journal May 2013
Supported oxorhenate catalysts prepared by thermal spreading of metal Re0 for methanol conversion to methylal journal October 2011
Reversible Structural Transformation of Palladium Catalyst Supported on La−Al 2 O 3 Probed with X-ray Absorption Fine Structure journal August 2000
Selective Palladium-Loaded MIL-101 Catalysts journal June 2011
Performance and Characterization of a New Crystalline SbRe2O6 Catalyst for Selective Oxidation of Methanol to Methylal journal October 2000
4.18 Photocatalytic Oxidation of Ethanol over Tantalum Oxide Supported on Silica book January 1994

Cited By (28)

Morphology inherence from hollow MOFs to hollow carbon polyhedrons in preparing carbon-based electrocatalysts journal January 2017
Palladium NPs supported on sulfonic acid functionalized metal–organic frameworks as catalysts for biomass cascade reactions journal January 2019
Unveiling the Effects of Linker Substitution in Suzuki Coupling with Palladium Nanoparticles in Metal–Organic Frameworks journal January 2018
Functionalization of Hollow Nanomaterials for Catalytic Applications: Nanoreactor Construction journal July 2018
Synthesis of imidazo[1,5-a]pyridines via oxidative amination of the C(sp 3 )–H bond under air using metal–organic framework Cu-MOF-74 as an efficient heterogeneous catalyst journal January 2016
Polydimethylsiloxane Coating for a Palladium/MOF Composite: Highly Improved Catalytic Performance by Surface Hydrophobization journal May 2016
An unprecedented anionic Ln-MOF with a cage-within-cage motif: spontaneous reduction and immobilization of ion-exchanged Pd( ii ) to Pd-NPs in the framework journal January 2015
Encapsulation of Metal Nanoparticles within Metal–Organic Frameworks for the Reduction of Nitro Compounds journal August 2019
Metal organic frameworks from extended, conjugated pentiptycene-based ligands journal January 2015
Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation journal January 2017
Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts: MOFs as Shape-Selective Hydrogenation Catalysts journal July 2015
Gold‐Palladium‐Alloy‐Catalyst Loaded UiO‐66‐NH 2 for Reductive Amination with Nitroarenes Exhibiting High Selectivity journal May 2018
Recent Advances of MOFs and MOF-Derived Materials in Thermally Driven Organic Transformations journal November 2018
Utilisation of gold nanoparticles on amine-functionalised UiO-66 (NH 2 -UiO-66) nanocrystals for selective tandem catalytic reactions journal January 2016
Fighting Deactivation: Classical and Emerging Strategies for Efficient Stabilization of Molecular Electrocatalysts journal January 2020
Size-confined growth of atom-precise nanoclusters in metal–organic frameworks and their catalytic applications journal January 2016
Polydimethylsiloxane Coating for a Palladium/MOF Composite: Highly Improved Catalytic Performance by Surface Hydrophobization journal May 2016
Ru/UiO-66 Catalyst for the Reduction of Nitroarenes and Tandem Reaction of Alcohol Oxidation/Knoevenagel Condensation journal April 2018
Engineering UiO-66 Metal Organic Framework for Heterogeneous Catalysis journal January 2019
Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster journal October 2018
Bimetallic Gold-Silver Nanoparticles Supported on Zeolitic Imidazolate Framework-8 as Highly Active Heterogenous Catalysts for Selective Oxidation of Benzyl Alcohol into Benzaldehyde journal October 2018
A ppm level Rh-based composite as an ecofriendly catalyst for transfer hydrogenation of nitriles: triple guarantee of selectivity for primary amines journal January 2019
A Bifunctional MOF Catalyst Containing Metal–Phosphine and Lewis Acidic Active Sites journal September 2018
Insight into the epitaxial encapsulation of Pd catalysts in an oriented metalloporphyrin network thin film for tandem catalysis journal January 2017
Titanium-Carboxylate Metal-Organic Framework Based on an Unprecedented Ti-Oxo Chain Cluster journal October 2018
Immobilized Pd-Ag bimetallic nanoparticles on polymeric nanofibers as an effective catalyst: effective loading of Ag with bimetallic functionality through Pd nucleated nanofibers journal April 2018
Exploitation of missing linker in Zr-based metal-organic framework as the catalyst support for selective oxidation of benzyl alcohol journal November 2019
Tandem Condensation‐Hydrogenation to Produce Alkylated Nitriles Using Bifunctional Catalysts: Platinum Nanoparticles Supported on MOF‐Derived Carbon journal November 2019

Similar Records

Related Subjects