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Title: Examination of charge transfer in Au/YSZ for high-temperature optical gas sensing

Au-nanoparticle incorporated oxide thin film materials demonstrate significant promise as functionalsensor materials for high temperature optical gas sensing in severe environments relevant for fossil andnuclear based power generation. The Au/yttria-stabilized zirconia (YSZ) system has been extensivelystudied in the literature and serves as a model system for fundamental investigations that seek to betterunderstand the mechanistic origin of the plasmonic gas sensing response. In this work, X-ray photoelec-tron spectroscopy techniques are applied to Au/YSZ films in an attempt to provide further experimentalevidence for a proposed sensing mechanism involving a change in free carrier density of Au nanoparticles due to charge transfer.
 [1] ;  [1]
  1. U.S. DOE
Publication Date:
OSTI Identifier:
Report Number(s):
Journal ID: ISSN 0169-4332
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Surface Science; Journal Volume: 313
Elsevier B.V.
Research Org:
National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research; National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States)
Sponsoring Org:
USDOE Office of Fossil Energy (FE)
Country of Publication:
United States
Au/yttria-stabilized zirconia; Charge transfer; Optical gas sensing; Thin films; Surface plasmon resonance; X-ray photoelectron spectroscopy