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Title: Low temperature spin dynamics in Cr7Ni-Cu-Cr7Ni coupled molecular rings

Proton Nuclear Magnetic Resonance (NMR) relaxation measurements have been performed down to very low temperature (50 mK) to determine the effect of coupling two Cr7 Ni molecular rings via a Cu2+ ion. No difference in the spin dynamics was found from nuclear spin lattice relaxation down to 1.5 K. At lower temperature, the 1H-NMR line broadens dramatically indicating spin freezing. From the plot of the line width vs. magnetization, it is found that the freezing temperature is higher (260 mK) in the coupled ring with respect to the single Cr7 Ni ring (140 mK).
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Publication Date:
OSTI Identifier:
Report Number(s):
IS-J 8313
Journal ID: ISSN 0021-8979; JAPIAU
DOE Contract Number:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 115; Journal Issue: 17
American Institute of Physics (AIP)
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
36 MATERIALS SCIENCE Nickel, Nuclear magnetic resonance, Antiferromagnetism, Copper, Ground states