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Title: Unconventional magnetism in ThCr2Si2-type phosphides, La1 xNdxCo2P2

Quaternary phases La1 xNdxCo2P2 (x = 0, 0.12, 0.25, 0.37, 0.50, 0.63, 0.75, 0.88, 1.0) have been synthesized from Sn flux to investigate the origins of drastic differences in properties between ferromagnetic LaCo2P2 and antiferromagnetic NdCo2P2. Powder and single-crystal X-ray diffraction indicate that all La1 xNdxCo2P2 samples are isostructural and crystallize in the ThCr2Si2 structure type. The unit cell parameters and volume change non-linearly with the Nd content (x), with the x < 0.50 10 samples being closer to LaCo2P2 and the ones with x > 0.50 being closer to NdCo2P2. These structural differences are also reflected in the magnetic behavior. The samples with lower Nd content are characterized by ferromagnetic ordering in the Co sublattice with the TC increasing from 132 K for x = 0 to 262 K for x = 0.50, while the samples with higher Nd content exhibit suppressed magnetization in the Co sublattice and canted antiferromagnetic ordering with TC ~ 270 K. Refinement of neutron powder 15 diffraction patterns for x = 0.50 and 0.75 reveals a gradual ordering of the Nd 4f moments under the influence of Co 3d moments below 100 K. At low temperatures and zero field, these samples exhibit antiferromagnetic orderingmore » of both Nd and Co magnetic moments, but under applied field they demonstrate the stabilization of a ferrimagnetic state with antiparallel alignment of the 4f and 3d moments, as indicated by isothermal magnetization measurements. The re-entrant ferrimagnetic transition 20 is also observed in samples with x > 0.50 if the temperature is lowered below 5 K. The occurrence of this low-temperature magnetic transition was confirmed by alternating-current susceptibility measurements.« less
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  1. Florida State University, Tallahassee
  2. ORNL
  3. National High Magnetic Field Laboratory (Magnet Lab), Florida
Publication Date:
OSTI Identifier:
DOE Contract Number:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Materials Chemistry C; Journal Volume: 2; Journal Issue: 36
Research Org:
Oak Ridge National Laboratory (ORNL); High Flux Isotope Reactor (HFIR)
Sponsoring Org:
SC USDOE - Office of Science (SC)
Country of Publication:
United States