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Title: On the dynamic and static manifestation of molecular absorption in thin films probed by a microcantilever

Journal Article · · Physical Review Applied
 [1];  [2];  [3];  [4]
  1. Univ. of Bourgogne, Dijon (France)
  2. Commission for Atomic Energy (France)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Univ. of Alberta, Edmonton, AB (Canada)

Mechanical resonators shaped like microcantilevers have been demonstrated as a platform for very sensitive detection of chemical and biological analytes. However, its use as an analytical tool will require fundamental understanding of the molecular absorption-induced effects in the static and dynamic sensor response. The effect of absorption-induced surface stress on the microcantilever response is here investigated using palladium hydride formation. It is shown that the resonance and deformation states of the cantilever monitored simultaneously exhibit excellent correlation with the phase of the hydride formation. However, the associated frequency shifts and quasistatic bending are observed to be independent during solid solution phase. Importantly, absorption-induced changes in the elastic parameters of the palladium film are found to play a dominant role in the static and dynamic response. The presented results help in discerning the parameters that control the cantilever response as well as the relationships between these parameters.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
OSTI ID:
1133557
Journal Information:
Physical Review Applied, Vol. 1, Issue 2; ISSN 2331-7019
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

References (12)

Pressure-composition isotherms for nanocrystalline palladium hydride journal July 1994
Effect of surface stress on the stiffness of thin elastic plates and beams journal February 2012
Effect of the adsorbate stiffness on the resonance response of microcantilever sensors journal November 2006
Detection of mercury vapor using resonating microcantilevers journal March 1995
Anomalous resonance in a nanomechanical biosensor journal August 2006
Adsorption‐induced surface stress and its effects on resonance frequency of microcantilevers journal April 1995
Stress-Induced Variations in the Stiffness of Micro- and Nanocantilever Beams journal June 2012
Size-dependent effective Young’s modulus of silicon nitride cantilevers journal June 2009
Elastic properties of Pd–hydrogen, Pd–deuterium, and Pd–tritium single crystals journal February 2005
Monitoring the chemical changes in Pd induced by hydrogen absorption using microcantilevers journal October 2003
Determination of adsorption-induced variation in the spring constant of a microcantilever journal March 2002
Nanomechanical hydrogen sensing journal April 2005

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