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Title: Solid-state coexistence of {Zr 12 } and {Zr 6 } zirconium oxocarboxylate clusters

Ligand metathesis, Co(II) coordination, and partial condensation reactions of an archetypal {Zr6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.
Authors:
; ; ; ;
Publication Date:
OSTI Identifier:
1132292
Report Number(s):
IS-J 8196
Journal ID: ISSN 1466-8033
DOE Contract Number:
DE-AC02-07CH11358
Resource Type:
Journal Article
Resource Relation:
Journal Name: CrystEngComm; Journal Volume: 16; Journal Issue: 1
Publisher:
Royal Society of Chemistry
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE