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Title: Chemical Degradation Studies on a Series of Dithiophosphinic Acids

A significant increase in the stability of a series of dithiophosphinic acids (DPAHs) under oxidizing acidic conditions was achieved. The degradation behavior of a series of DPAHs, designed for lanthanide/actinide separation, was examined. The stability of the DPAHs, when contacted with varying nitric acid concentrations, was tested and monitored using 31P {1H} NMR. Changes in the functional groups of the DPAHs resulted in substantial increases in the stability. However, when placed in contact with 2 M HNO3 all the DPAHs eventually showed signs of degradation. The addition of a radical scavenger, hydrazine, inhibited the degradation of the DPAHs. In the presence of a small concentration of hydrazine, five of the DPAHs remained stable for over a month in direct contact with 2 M HNO3.
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Publication Date:
OSTI Identifier:
Report Number(s):
Journal ID: ISSN 0888--5885
DOE Contract Number:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Industrial & Engineering Chemistry Research; Journal Volume: 53; Journal Issue: 9
Research Org:
Idaho National Laboratory (INL)
Sponsoring Org:
Country of Publication:
United States
99 GENERAL AND MISCELLANEOUS Dithiophosphinic Acids