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Title: Pressure-induced isostructural phase transition of a metal-organic framework Co2(4,4'-bpy)3(NO3)4·xH2O

Based on the 4,4'-bipyridine organic linker, metal–organic frameworks of Co2(4,4'-bpy)3(NO3)4·xH2O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.
Authors:
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  1. Jilin
Publication Date:
OSTI Identifier:
1130105
Resource Type:
Journal Article
Resource Relation:
Journal Name: Cryst. Eng. Comm.; Journal Volume: 16; Journal Issue: 05, 2014
Research Org:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Org:
FOREIGNNSFDOE - BASIC ENERGY SCIENCESDOE-NNSA
Country of Publication:
United States
Language:
ENGLISH