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Title: Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of coper phase in redox reactions.

Abstract

A self-reduction of graphene oxide (GO) at room temperature after prolonged storage on a copper substrate is evidenced by decrease of oxygen content and a dramatic, 6 orders in magnitude, increase in dc conductivity. Experiments revealed that the stored GO film contains copper hydroxide phase embedded in the reduced GO structure.

Authors:
 [1];  [1];  [1];  [2];  [2]
  1. ORNL
  2. Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1128990
DOE Contract Number:  
DE-AC05-00OR22725
Resource Type:
Journal Article
Journal Name:
Carbon
Additional Journal Information:
Journal Volume: 69; Journal ID: ISSN 0008-6223
Country of Publication:
United States
Language:
English

Citation Formats

Voylov, Dmitry N, Agapov, Alexander L, Sokolov, Alexei P, Shulga, Y. M., and Arbuzov, Artem. Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of coper phase in redox reactions.. United States: N. p., 2014. Web. doi:10.1016/j.carbon.2013.12.067.
Voylov, Dmitry N, Agapov, Alexander L, Sokolov, Alexei P, Shulga, Y. M., & Arbuzov, Artem. Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of coper phase in redox reactions.. United States. https://doi.org/10.1016/j.carbon.2013.12.067
Voylov, Dmitry N, Agapov, Alexander L, Sokolov, Alexei P, Shulga, Y. M., and Arbuzov, Artem. 2014. "Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of coper phase in redox reactions.". United States. https://doi.org/10.1016/j.carbon.2013.12.067.
@article{osti_1128990,
title = {Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of coper phase in redox reactions.},
author = {Voylov, Dmitry N and Agapov, Alexander L and Sokolov, Alexei P and Shulga, Y. M. and Arbuzov, Artem},
abstractNote = {A self-reduction of graphene oxide (GO) at room temperature after prolonged storage on a copper substrate is evidenced by decrease of oxygen content and a dramatic, 6 orders in magnitude, increase in dc conductivity. Experiments revealed that the stored GO film contains copper hydroxide phase embedded in the reduced GO structure.},
doi = {10.1016/j.carbon.2013.12.067},
url = {https://www.osti.gov/biblio/1128990}, journal = {Carbon},
issn = {0008-6223},
number = ,
volume = 69,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 2014},
month = {Wed Jan 01 00:00:00 EST 2014}
}