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Title: Following Solid-Acid-Catalyzed Reactions by MAS NMR Spectroscopy in Liquid Phase -Zeolite-Catalyzed Conversion of Cyclohexanol in Water

The catalytic conversion of cyclohexanol on zeolite HBEA in hot liquid water leads to dehydration as well as alkylation products. A novel micro autoclave suitable for application in MAS NMR at high temperatures and pressures is developed and successfully applied to obtain new insight into the mechanistic pathway leading to an understanding of the reactions under selected experimental conditions.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [2] ;  [3]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  2. TU Munchen, Garching (Germany)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States); TU Munchen, Garching (Germany)
Publication Date:
OSTI Identifier:
1118107
Report Number(s):
PNNL-SA--96916
Journal ID: ISSN 1433-7851; 47800; 47582; 47841; KC0302010
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 53; Journal Issue: 2
Publisher:
Wiley
Research Org:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY in operando high pressure MAS NMR spectroscopy; catalytic alcohol dehydration; enhanced activity by pores; catalysis; zeolites; Environmental Molecular Sciences Laboratory